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Microwave-Assisted FeCl3·6H2O-Catalyzed Regioselective Deprotection of Pyranose Anomeric O-Acetyl Group

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Abstract:

Treatment of peracetylated pyranoses with FeCl3·6H2O in acetonitrile under microwave conditions provides an efficient and mild method for regioselective deprotection of anomeric O-acetyl group. The experimental results indicated that the employment of microwave could notably improve the reaction efficacy compared with the conventional heating condition.

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Periodical:

Advanced Materials Research (Volume 830)

Pages:

155-158

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.830.155

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Online since:

October 2013

Authors:

Qiang Wang, Guo Dong Liu, Shan Shan Gong, Qi Sun*

Keywords:

Deprotection, FeCl3·6H2O, Microwave, Pyranose, Regioselective Deacetylation

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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