Reductive Transformation of p-Nitrophenol by the Effect of the Low Crystalline γ-FeOOH and Oxalic Acid

Peng Han; Ru Fen Chen; Hui Liu; Yu Wei

doi:10.4028/www.scientific.net/AMR.997.206

Paper Titles

An Improved Synthesis of Isonucleoside of Tubercidin
p.193

Synthesis and Crystal Structure of 1-(2R,3S,4R,5R)-3-fluoro-4-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-5-iodopyrimidine-2,4(1H,3H)-dione
p.196

An Improved Total Synthesis of 5'-Deoxytoyocamycin
p.200

An Efficient Synthesis of 5-Bromo-4-chloro-3-indoxyl Choline Phosphate
p.203

Reductive Transformation of p-Nitrophenol by the Effect of the Low Crystalline γ-FeOOH and Oxalic Acid
p.206

Expression and Identification on the MPB83-MPB70 Fusion Gene of Mycobacterium bovis in Escherichia coli
p.210

Isolation and Expression Analysis of a Putative CIPK Gene in Halophyte Sesuvium portulacastrumand L.
p.215

Synthesis of Methyl Methacrylate/Acrylic Acid/N, N’-4, 4’-Diphenylmethane-bismaleimide Copolymer and its Electricity Storage Characteristics
p.221

Inhibition of Tumor Cell Proliferation In Vitro by Benzamide Derivatives
p.225

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 997Reductive Transformation of p-Nitrophenol by the...

Reductive Transformation of p-Nitrophenol by the Effect of the Low Crystalline γ-FeOOH and Oxalic Acid

Abstract:

Low Lepidocrocite (γ-FeOOH) was synthesized with air oxidation method. In anaerobic conditions, the reductive transformation of p-nitrophenol (p-NP) was investigated with the low crystalline γ-FeOOH as catalyst in the presence of oxalic acid. Results showed that the oxalic acid could effectively promoted the reduction of p-NP, the optimal concentration for the oxalic acid was 2.0 mM. The surface bound Fe (II) concentration of γ-FeOOH was indirectly detected, which showed reductive transformation mainly referred to Fe (II) mechanism.

You might also be interested in these eBooks

Frontiers of Chemical Engineering, Metallurgical Engineering and Materials III

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 997)

Pages:

206-209

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.997.206

Citation:

Cite this paper

Online since:

August 2014

Authors:

Peng Han, Ru Fen Chen*, Hui Liu, Yu Wei

Keywords:

Fe (II), Oxalic Acid, p-Nitrophenol, Reductive, γ-FeOOH

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] Y.Y. Chu, Y. Qian, W.J. Wang, X.L. Deng, Adual-cathode electro-Fenton oxida- tion coupled with anodic oxidation system used for 4-nitrophenol degradeation. J. Hazard. Mater. 199–200 (199) (2012) 179–180.

DOI: 10.1016/j.jhazmat.2011.10.079

Google Scholar

[2] R.F. Chen, J.H. Cheng. Y. Wei, Photocatalytic Oxidation of Fe(OH)2 Suspension with Visible Light Irradiation. J Phys Chem (C). 111 (2007) 16453-16459.

DOI: 10.1021/jp074153l

Google Scholar

[3] C.A. Schultz, T.J. Grundl, pH dependence on reduction rate of 4-Cl-nitroben zen- e by Fe(II) /monmt orillonite systems. Environmental Science Technology, 34 (2000) 3641-3648.

DOI: 10.1021/es990931e

Google Scholar

[4] F.B. Li, X.Z. Li, X.M. Li, T.X. Liu, J. Dong, Heterogeneous photodegradation of bisphenol A with iron oxides and oxalate in aqueous solution, J. Colloid Interface Sci. 311 (2007) 481- 490.

DOI: 10.1016/j.jcis.2007.03.067

Google Scholar

[5] F.B. Li, G.W. Xu, S.L. Cheng, Enhancement of the reductive transformation of pentachlorophenol by polycarboxylic acids at the iron oxide–water interface. Journal of Colloid and Interface Science 321 (2008) 332–341.

DOI: 10.1016/j.jcis.2008.02.033

Google Scholar

[6] K. Pecher, S.B. Haderlein, R.P. Schwarzenbach, Reduction of polyhalogenated methanes by surface-bound Fe(II) in aqueous suspensions of iron oxides, Enviro-n. Sci. Technol. 36 (2002) 1734–1741.

DOI: 10.1021/es011191o

Google Scholar