Magnetic Properties of Cobalt and Manganese Oxide Spinel Ceramics

Abstract:

Magnetic susceptibility measurements, magnetization and neutron diffraction results at low temperature for cobalt and manganese oxide spinel ceramics are presented. The Curie temperature varies similarly with the sample composition in ceramics and powders. The experimental molar Curie constant variation is explained by the presence of Co2+, CoIII, Mn3+ and Mn4+, and possibly Co3+ in the octahedral sites for the cobalt rich phases. The magnetic moments of the cations in tetrahedral and octahedral sites are not collinear and the global magnetization is oriented in a third direction.

• Periodical: Advances in Science and Technology (Volume 67)
• Pages: 143-148
• DOI: https://doi.org/10.4028/www.scientific.net/AST.67.143
• Online since: October 2010
• Authors: Sophie Guillemet-Fritsch, Christophe Tenailleau, Helene Bordeneuve, Abel Rousset
• Keywords: Ceramic, Cobalt Oxide, Magnetism, Manganese Oxide, Neutron Diffraction, Spinel

References

[1] H. Bordeneuve, C. Tenailleau, S. Guillemet-Fritsch, R. Smith, E. Suard and A. Rousset: Solid State Sci. Vol. 12 (2010), p.379.

DOI: 10.1016/j.solidstatesciences.2009.11.018

[2] A. S. Borovik-Romanov, M. P. Orlova: Soviet Physics-JETP Vol. 5 (1957), p.1023.

[3] V. Baron, J. Gutzmer, H. Rundolf, R. Tellgren: Am. Mineral. Vol. 83 (1998), p.786.

[4] W. L. Roth: J. Phys. Chem. Solids Vol. 25 (1964), p.1.

[5] E. W. Gorter: Philips Research Reports Vol. 9 (1954), p.295.

[6] A. Navrotsky, O. J. Kleppa: J. Inorg. Nuclear Chem. Vol. 29 (1967), p.2701.

[7] J. S. Griffith: The theory of transition-metal ions. Cambridge University Press (1961).

[8] W. L. Roth : Journal de Physique Vol. 25 (1964), p.507.

[9] B. Boucher, R. Buhl, R. Di Bella, M. Perrin : Journal de Physique Vol. 31 (1970), p.113.

[10] S. Tamura : Physica B Vol. 190 (1993), p.150.

[11] H. Bordeneuve, S. Guillemet-Fritsch, A. Rousset, S. Schuurman, V. Poulain : J. Solid State Chem. Vol. 182 (2009), p.396.

DOI: 10.1016/j.jssc.2008.11.004

[12] H. Bordeneuve, A. Rousset, C. Tenailleau and S. Guillemet-Fritsch : J. Therm. Anal. Calorim., DOI: 10. 1007/s10973-009-0557-7.

[13] E. Rios, O. Pena, T. Guizouarn and J.L. Gautier: Phys. Stat. Sol. C DOI : 10. 1002/pssc. 200304888.

[14] H.T. Zhang and X.H. Chen : Nanotechnology Vol. 17 (2006), p.1384.

[15] C. Campos, G. Pecchi, Y. Moreno, C. Moure, V. Gil, P. Barahona and O. Pena: Bol. Soc. Esp. Ceram. Vol. 47 (2008), p.207.

[16] M. Marysko, Z. Jirak, K. Knizek and C. Autret-Lambert: J. Mag. Mag. Mater. Vol. 322 (2010), p.1392.

[17] D. G. Wickham and W. J. Croft: J. Phys. Chem. Solids Vol. 7 (1958), p.351.

[18] A. Michel : Phénomènes magnétiques et structure. Paris, Masson et Cie (1966).

[19] P. Poix : Annales de Chimie, Paris Vol. 9 (1964), p.261.

[20] J. L. Baudour, F. Bouree, M. A. Fremy, R. Legros, A. Rousset, B. Gillot: Physica B Vol. 180 (1992), p.97.

DOI: 10.1016/0921-4526(92)90672-f

[21] B. Boucher, R. Buhl, M. Perrin: J. Appl. Phys. Vol. 40 (1969), p.1126.

[22] M. Beley, L. Padel, J. C. Bernier: Annales de Chimie Vol. 3 (1978), p.429.