CuZnSnSe Nanotubes and Nanowires by Template Electrosynthesis

Article Preview

Abstract:

In this work we present some results of an extensive investigation aimed to find suitable conditions to grow CuZnSnSe (CZTSe) nanostructures through single-step electrodeposition into the channels of polycarbonate membranes. After the optimization of several electrodeposition parameters, we have found that pulsed current deposition, between 0 and -1 mA cm-2, is the best way to obtain CZTSe nanostructures mechanically attached to the support. An interesting result concerns the effect of supporting electrolyte in the deposition bath. In fact, changing its concentration it is possible to vary morphology of nanostructures from nanotubes to nanowires. In both case uniform arrays of ordered nanostructures were obtained on a Ni current collector that are very stable also after thermal treatment at 550°C.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

241-246

Citation:

Online since:

October 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] G. Brammertz, M. Buffiere, S. Oueslati, H. ElAnzeery, K. Ben Messaound, S. Sahayaraj, C. Koble, M. Meuris, J. Poortmans, Characterization of defects in 9. 7% efficient Cu2ZnSnSe4-CdS-ZnO solar cells, Appl. Phys. Lett 103 (2013) 163904.

DOI: 10.1063/1.4826448

Google Scholar

[2] M Paire, L. Lombez, F. Donsanti, M. Jubault, S. Collin, J_L. Pelouard, J-F. Guillemoles, D. Lincot, Cu(In, Ga)Se2 microcells: High efficiency and low material consumption, J Renewable Sustainable Energy 5 (1023) 011202.

DOI: 10.1063/1.4791778

Google Scholar

[3] S. Bag, O. Gunawan, T. Gokmen, Y. Zhu, T. K. Todorov, D. B. Mitzi, Low band gap liquid-processed CZTSe solar cell with 10. 1% efficiency, Energy Environ. Sci. 5 (2012) 7060-7065.

DOI: 10.1039/c2ee00056c

Google Scholar

[4] W. Septina, S. Ikeda, T. Harada, M. Matsumura, Fabrication of Cu2ZnSnSe4 thin films from an electrodeposited Cu-Zn-Sn-Se/CuSn-Se bilayer. Phys. Status Solidi C 10 (2013) 1062-1066.

DOI: 10.1002/pssc.201200800

Google Scholar

[5] M. Meng, L. Wan, P. Zou, S. Miao, J. Xu, Cu2ZnSnSe4 thin films prepared by selenization of one-step electrochemically deposisted Cu-Zn-Sn-Se precursors, Applied Surface Science 273 (2013) 613-616.

DOI: 10.1016/j.apsusc.2013.02.088

Google Scholar

[6] L. Guo, Y. Zhu, O. Gunawan, T. Gokmen, V. R. DEline, S. Ahmed, L. T. Romankiw, H. Deligianni, Electrodeposited Cu2ZnSnSe4 thin film solar cell with 7% power conversion efficiency, Prog. Photovolt: Res. Appl. 222 (2014) 58—68.

DOI: 10.1002/pip.2332

Google Scholar

[7] P. Hiradal, H. E. Unalan, G. A. J. Amaratunga, Nanowires for energy conversion, Nanotechnology 23 (2013) 194002.

Google Scholar

[8] Z. Q. Li, J. H. Shi, Q. Q. Liu, Y. W. Chen, Z. Sun, Z. Yang, S. M. Huang, Large-scale growth of Cu2ZnSnSe4 and Cu2ZnSnSe4/Cu2ZnSnS4 core/shell nanowires, Nanotechnology 22 (2011) 265615.

Google Scholar

[9] W. Zhang, W. Yu, L. Zhang, H. Yang, W. Fu, M. Li, Y.: Li, Synthesis and characterization of Cu2ZnSnSe4 nanotube arrays on fluorine-doped tin oxide glass substrate, Superlattices and Microstructures 52 (2012) 653-661.

DOI: 10.1016/j.spmi.2012.07.013

Google Scholar

[10] R. Inguanta, P. Livreri, S. Piazza, C. Sunseri, Fabrication and photoelectrochemical behavior of ordered CIGS nanowire arrays for application in solar cells., Electrochem. Solid State Lett. 13 (2010) K22-K25.

DOI: 10.1149/1.3274126

Google Scholar

[11] R. Inguanta, T. Spanò, L. Oliveri, S. Piazza, C. Sunseri, Electrodeposition and photo-electrochemical behavior of CIGS thin films and nanowire arrays for solar cell, Chemical Engineering Transactions, 32 (2013) 343-348.

Google Scholar

[12] M. Farinella, R. Inguanta, T. Spanò, P. Livreri, S. Piazza, C. Sunseri, Electrochemical Deposition of CZTS Thin Films on Flexible Substrate, Energy Procedia, 44 (2014) 105-110.

DOI: 10.1016/j.egypro.2013.12.015

Google Scholar

[13] R. Inguanta, S. Piazza, C. Sunseri, A. Cino, V. Di Dio, D. La Cascia, R. Miceli, C. Rando, G. Zizzo, An electrochemical route towards the fabrication of nanostructured semiconductor solar cells, SPEEDAM 2010-International Symposium on Power Electronics, Electrical Drives, Automation and Motion. 2010; art. no. 5542264 , 1166-1171.

DOI: 10.1109/speedam.2010.5542264

Google Scholar

[14] E. I. sokol, I. I. Tyukhov, N. P. Klochko, G. S. Khrypunov, Y. O. Myagchenko, E. E. Meinychuk, V. R. Kopach, O. V. Momotenko, K. S. Klepikova, V. M. Lyubov, A. V. Kopach, Pulse plating of semiconductors for solar cells, Solar Energy 105 (2014).

DOI: 10.1016/j.solener.2014.03.003

Google Scholar