Defect and Diffusion Forum Vols. 326-328

Abstract: In submerged arc welding process, concept on temperature distribution is essential in order to control HAZ dimensions and get the required bead size and quality. In this paper, an analytical solution for moving heat source with Gaussian distribution of inside volume of central conicoidal shape is derived. Heat transfer in welded plates during welding is assumed to be conductive heat transfer of a semi infinite body. With the help of this analytical solution, transient temperature distribution, HAZ width, weld bead dimensions are estimated. Good agreements between predicted and experimental values are achieved.

Abstract: We determine thermal dispersion in metal foams using a pore scale numerical approach. Samples are contained in a channel crossed by a steady fully established fluid flow. The size of the foam sample is chosen according to a Representative Elementary Volume (REV).Two configurations are tested with several foam structures, pore size and pore shape. In the first configuration, heat and mass fluxes are in the same direction, in the second one, fluxes are perpendicular such as in heat exchanger. Results obtained on apparent fluid phase conductivity are discussed along with pressure drop data and compared to available literature data.

Abstract: The Reynolds Averaged Navier Stokes Equation (RANS) model was used to describe the turbulent flow in a coaxial jet mixer. The effects of turbulent models on the turbulent flow is investigated to help the engineers and researchers in deciding the selection of turbulent model need to be used in order to save the simulation time and to predict the best suitable model to be used. Good agreement of the CFD prediction with the experimental data in certain locations was obtained with species transport and velocity profiled, where dependence of turbulent models and grid sizes were discussed in detail. The results show that, the need of grid study is crucial to obtain reliable results with optimum consumption of computer power. SST and Launder Gibson RSTM models give results superior to the other models, each of which has its own area of capability. Launder Gibson RSTM is good in predicting the flow with recirculation and vortices, while SST is good for the flow with less recirculation and high velocity. The overall results show that RANS model is capable in predicting the area of mixing and the velocity profile correctly in certain locations but not in reproducing the vortices structure in the pipe and nozzle.

Abstract: Asymmetric polysulfone membranes were prepared by wet-phase inversion method from casting solutions consisting of PSf/NMP and water as non-solvent. The effects of polymer concentration and molar mass were investigated by rheological studies. Moreover, membranes were characterized by scanning electron microscope (SEM). It was found that polymer solutions containing between 22 and 25 wt% PSf/NMP originated microfiltration membranes. The use of a higher mass molar polysulfone has been shown to reduce diameter pore and to maintain morphology. All the results were interrelated into a discussion of the skin formation of asymmetric membranes.

Abstract: Hot dipping is a coating technique used in industry for galvanizing machine elements and steel profiles for construction or automotive applications. However, an alternative use of this process might be to improve specific properties. For instance, in order to improve the magnetic properties of electrical steels, it may be desirable to increase the Si and/or Al content. A possible and alternative route to realize this is by the application of an Al-Si-rich coating on the steel substrate using a hot dipping process, followed by a diffusion annealing treatment in order to distribute the Al/Si more evenly in the steel. The obtained distribution depends on the annealing parameters and can be both beneficial and detrimental for the magnetic properties. In the present work, Fe-Si substrates were hot dipped in different Al-Si baths. Subsequently, the samples were annealed at 1100°C during 20 minutes and concentration profiles were measured with scanning electron microscope energy dispersive spectroscopy line scans. The experimental results were analyzed using a specifically designed simulation model in order to determine the Al and Si diffusion coefficients. This model uses an inverse algorithm to determine interdiffusion coefficients that arise in a macro ternary diffusion system.

Abstract: A new model for solid skin formation on submicrocellular foams based on PMMA is presented. Structural foams has been produced by the solid state foaming technique using as precursor material a blend of poly (methyl methacrylate) PMMA and a triblock copolymer [poly (methyl methacrylate)-block poly (butyl acrylate)-block poly (methyl methacrylate), MA. An analysis on the skin thickness and densification has been carried based on x-ray high resolution radiography. The obtained results have been related to the fabrication parameters, i.e. MAM content of the blend and foaming pressure, and provide us a new vision about the processes that control the formation of a solid unfoamed, or partially unfoamed, skin in these materials.

Abstract: Mixed convection of Cu-water nanofluid in a lid-driven square cavity with a heat source embedded in the bottom wall is studied numerically. The governing equations together with the respective boundary conditions are solved numerically using the finite volume method and the SIMPLER algorithm. The computations are performed for various Richardson numbers (), heat source length () and volume fraction of the nanoparticles (). It is observed from the results that the average Nusselt number is increased by increasing the Richardson number and the volume fraction of the nanoparticles. Moreover, the maximum temperature at the heat source surface decreases by increasing the Richardson number and the volume fraction of the nanoparticles.

Abstract: Microstructural evolution in single crystal Ni-based superalloys is investigated by the phase field simulation. During creep, the morphology of the γ phase changed from the cuboidal shape to the rafted one, and the rafted structure was collapsed in the late stage of creep. The simulation on the microstructural evolution is based on thermodynamic information, diffusion equation, elastic anisotropy and a homogeneous lattice misfit. It is found that caused by external stress result in the morphological change of the γ phase to the rafted structure, and this rafted structure is collapsed by inhomogeneous lattice misfit. These morphological changes can be explained by the change in stable morphology of the γ phase.

Abstract: This paper reports the measurement of the binary mass diffusion coefficient for proteins with a wide range of molecular size. The diffusion coefficient is obtained by conducting diffusion experiments in the dilute region. Transient concentration profiles were measured by a phase shifting interferometer and subsequently compared with a numerical calculation based on Ficks law to determine the diffusion coefficient. Distilled water was used as solvent in free diffusion experiments conducted at T = (25 ± 1.0)°C. The method was validated by measuring the diffusion coefficient of aqueous NaCl, Sucrose, and BSA, which values have been extensively reported in the literature. The values of the diffusion coefficient for seven proteins: aprotinin (6.5 kDa), α-lactalbumin (14.2 kDa), lysozyme (14.3 kDa), trypsin inhibitor (20.1 kDa), ovalbumin (44.2 kDa), bovine serum albumin (66.7 kDa), and phosphorylase b (97.2 kDa), were determined in the dilute region of 0-3 mg/ml. The results are compared with the Stokes-Einstein equation. The influence of the molecular structure and pH on the diffusion coefficient is discussed.

Abstract: Hydrogen diffusivity in ZnO (0001) single crystal was investigated using electrical resistometry and nuclear reaction analysis (NRA). ZnO crystals were covered with a thin Pd over-layer and electrochemically charged with hydrogen. The net concentration of hydrogen determined by NRA was found to be in a reasonable agreement with the value estimated from the transported charge using the Faradays law. The hydrogen diffusion coefficient in ZnO was estimated from in-situ electrical resistivity measurements. Moreover, NRA investigations revealed existence of a subsurface layer with very high concentration of hydrogen (up to 40 at.%). Typical surface modification observed on hydrogen loaded crystal by light microscope indicates hydrogen-induced plastic deformation realized by a slip in the c-direction. Open-volume defects introduced by hydrogen-induced plastic deformation trap diffusing hydrogen and cause an enhancement of hydrogen concentration in the deformed subsurface layer.