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HomeDefect and Diffusion ForumDefect and Diffusion Forum Vol. 386Films of Reduced Graphene Oxide with Percolation...

Films of Reduced Graphene Oxide with Percolation Networks of Nanographenes

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Abstract:

Percolation networks of electrically connected nanographenes are the promising structures for solving the problem of the transfer of their peculiar quantum properties to the macroscopic level. In this work we report the results of investigations, conducted with using a set of complementary physical methods, on the origin, structural motifs and properties of such networks revealed in thermally reduced graphene oxide films. The presence of zero modes, which may be π-electronic states stabilized at the zigzag edges of network elements, has been established.

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Physics and Technology of Nanostructured Materials IV

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Periodical:

Defect and Diffusion Forum (Volume 386)

Pages:

388-393

DOI:

https://doi.org/10.4028/www.scientific.net/DDF.386.388

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Online since:

September 2018

Authors:

Albert M. Ziatdinov*, Peter G. Skrylnik

Keywords:

ESR, Graphene, Graphene Oxide, Magnetic Susceptibility, Nanographene, Nanographene Films, Percolation Network, Raman Spectroscopy, Reduced Graphene Oxide, XPS, XRD

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] K. Nakada, M. Fujita, G. Dresselhaus, M.S. Dresselhaus, Edge state in graphene ribbons: nanometer size effect and edge shape dependence, Phys. Rev. B. 54 (1996) 17954-17961.

DOI: 10.1103/physrevb.54.17954

[2] Y. Kobayashi, K. Fukui, T. Enoki, K. Kusakabe, Y. Kaburagi, Observation of zigzag and armchair edges of graphite using STM and STS, Phys. Rev. B. 71 (2005) 193406.

DOI: 10.1103/physrevb.71.193406

[3] A.M. Ziatdinov, Nanographites, their compounds, and film structures, Russ. Chem. Bull. 64 (2015) 1-14.

DOI: 10.1007/s11172-015-0812-y

[4] A.M. Ziatdinov, N.S. Saenko, P.G. Skrylnik, Molecular and electronic structure and magnetic properties of multilayer graphene nanoclusters and their changes under the influence of adsorbed molecules, Russ. Chem. Bull. 66 (2017) 837-848.

DOI: 10.1007/s11172-017-1816-6

[5] A.M. Ziatdinov, P.G. Skrylnik, N.S. Saenko, The influence of an adsorbate and edge covalent bonds on topological zero modes in few-layer nanographenes, Phys. Chem. Chem. Phys. 19 (2017) 26957-26968.

DOI: 10.1039/c7cp03423g

[6] Yu.M. Nikolenko, A.M. Ziatdinov, Synthesis and characterization of nanographites with chemically modified edges, Russ. J. Inorg. Chem. 57 (2012) 1436-1442.

DOI: 10.1134/s0036023612110101

[7] R. Taira, A. Yamanaka, S. Okada, Electronic structure and electric polarity of edge-functionalized graphene nanoribbons, Jpn. J. Appl. Phys. 56 (2017) 085103.

DOI: 10.7567/jjap.56.085103

[8] G. Magda, X. Jin, I. Hagymaґsi, P. Vancsoґ, Z. Osvaґth, P. Nemes-Incze, Room-temperature magnetic order on zigzag edges of narrow graphene nanoribbons, Nature. 514 (2014) 608-611.

DOI: 10.1038/nature13831

[9] K. Sasaki, J. Jiang, R. Saito, S. Onari, Y. Tanaka, Theory of superconductivity of carbon nanotubes and graphene, J. Phys. Soc. Jpn. 76 (2007) 033702.

DOI: 10.1143/jpsj.76.033702

[10] A. Kinikar, T.P. Sai, S. Bhattacharyya, A. Agarwala, T. Biswas, S.K. Sarker, Quantized edge modes in atomic-scale point contacts in graphene, Nature Nanotechnol. 12 (2017) 564-568.

DOI: 10.1038/nnano.2017.24

[11] W.S. Hummers Jr., R.E. Offeman, Preparation of graphitic oxide, J. Amer. Chem. Soc. 80 (1958) 1339-1339.

DOI: 10.1021/ja01539a017

[12] A.M. Ziatdinov, Y.V. Zelenskii, A.A. Uminskii, E.G. Ippolitov, Synthesis and investigation of intercalated oxygen-containing graphite compounds, Zhurnal Neorganicheskoi Khimii. 30 (1985) 1658-1664.

[13] N. Iwashita, C.R. Park, H. Fujimoto, M. Shiraishi, M. Inagaki, Specification for a standard procedure of X-ray diffraction measurements on carbon materials, Carbon. 42 (2004) 701-714.

DOI: 10.1016/j.carbon.2004.02.008

[14] L.G. Cancado, A. Jorio, M.A. Pimenta, Measuring the absolute Raman cross section of nanographites, Phys. Rev. B. 76 (2007) 064304.

DOI: 10.1103/physrevb.76.064304

[15] A.C. Ferrari, J. Robertson, Interpretation of Raman spectra of disordered and amorphous carbon, Phys. Rev. B. 61 (2000) 14095-14107.

DOI: 10.1103/physrevb.61.14095

[16] A.M. Ziatdinov, N.M. Mishchenko, Yu.M. Nikolenko, Phase transition and incommensurate states in GIC C5nHNO3, Synth. Met. 59 (1993) 253-258.

DOI: 10.1016/0379-6779(93)91034-y

[17] A.M. Ziatdinov, N.M. Mishchenko, Phase transitions and nonmetallic, temperature dependence of conduction electron spin resonance line width in quasi-two-dimensional synthetic metal C15HNO3, Solid State Commun. 97 (1996) 1085-1089.

DOI: 10.1016/0038-1098(95)00702-4

[18] M. Ziatdinov, S. Fujii, M. Kiguchi, T. Enoki, S. Jesse, S.V. Kalinin, Data mining graphene: correlative analysis of structure and electronic degrees of freedom in graphenic monolayers with defects, Nanotechnology. 27 (2016) 495703.

DOI: 10.1088/0957-4484/27/49/495703