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HomeDefect and Diffusion ForumDefect and Diffusion Forum Vol. 406Thermo-Kinetic Study of Adsorption of Methylene...

Thermo-Kinetic Study of Adsorption of Methylene Blue in Aqueous Solutions Using Algerian Illite Natural and Activated Mineral Clay

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Abstract:

In this study, a local mineral clay was used as an adsorbent for the elimination of a cationic dye: methylene blue (MB), in an aqueous solution by adsorption technique. Early on, we performed mineralogical and textural analyses of a clay sample using various techniques, namely X-ray diffraction, Brunauer-Emmett-Teller analysis and Fourier-transform infrared spectroscopy. The experimental results showed that this adsorbent is a mesoporous and non-swelling clay with illite and kaolinite as the major components with a specific area of about 110m²/g. The study of MB adsorption on the clay was carried out by optimizing the conditions of adsorption, notably the initial concentration of pollutant C₀, the mass of clay m, the contact time t, the potential of hydrogen of the solution pH and the temperature T. Experimental results have shown that the equilibrium data are well adjusted by a Langmuir isotherm equation. Thermodynamic parameters such as the changes in Gibbs free energy, enthalpy, and entropy were determined from batch experiments. Results revealed that the adsorption of MB onto illitic clay was endothermic and spontaneous process. Kinetic modeling was also carried out. Experimental data adjusted the kinetic model of pseudo-second order with two stages of intraparticle diffusion.

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Periodical:

Defect and Diffusion Forum (Volume 406)

Pages:

348-363

DOI:

https://doi.org/10.4028/www.scientific.net/DDF.406.348

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Online since:

January 2021

Authors:

Larbi Haddad*, Abdelkader Hima, Belkhir Dadamoussa, Asma Messai Aoun

Keywords:

Adsorption, Environment, Illite, Methylene Blue, Mineral Clay, Water Treatment

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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[1] K. Bakker, M. Ritts, Global environmental change, Smart Earth: A meta-review and implications for environmental governance, 52 (2018) 201-211.

DOI: 10.1016/j.gloenvcha.2018.07.011

[2] S. Mnasri-Ghnimi, N. Frini-Srasra, Applied Clay Science, Removal of heavy metals from aqueous solutions by adsorption using single and mixed pillared clays, 179 (2019) 105151.

DOI: 10.1016/j.clay.2019.105151

[3] S.M. Ghnimi, N. Frini-Srasra, Applied Clay Science, A comparison of single and mixed pillared clays for zinc and chromium cations removal, 158 (2018) 150-157.

DOI: 10.1016/j.clay.2018.03.019

[4] M. Kummu, H. De Moel, M. Porkka, S. Siebert, O. Varis, P.J. Ward, Science of the total environment, Lost food, wasted resources: Global food supply chain losses and their impacts on freshwater, cropland, and fertiliser use, 438 (2012) 477-489.

DOI: 10.1016/j.scitotenv.2012.08.092

[5] M. Berradi, R. Hsissou, M. Khudhair, M. Assouag, O. Cherkaoui, A. El Bachiri, A. El Harfi, Heliyon, Textile finishing dyes and their impact on aquatic environs, 5 (2019) e02711.

DOI: 10.1016/j.heliyon.2019.e02711

[6] G. Crini, Bioresource technology, Non-conventional low-cost adsorbents for dye removal: a review, 97 (2006) 1061-1085.

DOI: 10.1016/j.biortech.2005.05.001

[7] T. Robinson, G. McMullan, R. Marchant, P. Nigam, Bioresource technology, Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative, 77 (2001) 247-255.

DOI: 10.1016/s0960-8524(00)00080-8

[8] C.A. Martínez-Huitle, E. Brillas, Applied Catalysis B: Environmental, Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: a general review, 87 (2009) 105-145.

DOI: 10.1016/j.apcatb.2008.09.017

[9] S. Azha, A. Ahmad, S. Ismail, Desalination and Water Treatment, Thin coated adsorbent layer: characteristics and performance study, 55 (2015) 956-969.

DOI: 10.1080/19443994.2014.922502

[10] D. Atia, A.A. Bebba, L. Haddad, A. Zobeidi, Elimination Of Organic Pollutants From Urban Wastewater By Illite-Kaolinite Local Clay From South-East Of Algeria, Ciencia e Tecnica Vitinicola, 33 (2018) 17-28.

DOI: 10.5958/0974-4150.2020.00018.8

[11] B. Zohra, K. Aicha, S. Fatima, B. Nourredine, D. Zoubir, Chemical Engineering Journal, Adsorption of Direct Red 2 on bentonite modified by cetyltrimethylammonium bromide, 136 (2008) 295-305.

DOI: 10.1016/j.cej.2007.03.086

[12] M. Doğan, M. Alkan, Ö. Demirbaş, Y. Özdemir, C. Özmetin, Chemical Engineering Journal, Adsorption kinetics of maxilon blue GRL onto sepiolite from aqueous solutions, 124 (2006) 89-101.

DOI: 10.1016/j.cej.2006.08.016

[13] Z. Bouberka, A. Khenifi, N. Benderdouche, Z. Derriche, Journal of hazardous materials, Removal of Supranol Yellow 4GL by adsorption onto Cr-intercalated montmorillonite, 133 (2006) 154-161.

DOI: 10.1016/j.jhazmat.2005.10.003

[14] M.F.R. Pereira, S.F. Soares, J.J. Órfão, J.L. Figueiredo, Carbon, Adsorption of dyes on activated carbons: influence of surface chemical groups, 41 (2003) 811-821.

DOI: 10.1016/s0008-6223(02)00406-2

[15] S. Altenor, B. Carene, E. Emmanuel, J. Lambert, J.-J. Ehrhardt, S. Gaspard, Journal of hazardous materials, Adsorption studies of methylene blue and phenol onto vetiver roots activated carbon prepared by chemical activation, 165 (2009) 1029-1039.

DOI: 10.1016/j.jhazmat.2008.10.133

[16] Y. Zaker, M. Hossain, T. Islam, Research Journal of Chemical Sciences ISSN, Adsorption kinetics of methylene blue onto clay fractionated from Bijoypur soil, Bangladesh, 2231 (2013) 606X.

[17] I. Tan, A. Ahmad, B. Hameed, Desalination, Adsorption of basic dye using activated carbon prepared from oil palm shell: batch and fixed bed studies, 225 (2008) 13-28.

DOI: 10.1016/j.desal.2007.07.005

[18] A. Badruddoza, G.S.S. Hazel, K. Hidajat, M. Uddin, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Synthesis of carboxymethyl-β-cyclodextrin conjugated magnetic nano-adsorbent for removal of methylene blue, 367 (2010) 85-95.

DOI: 10.1016/j.colsurfa.2010.06.018

[19] S. Tahir, N. Rauf, Chemosphere, Removal of a cationic dye from aqueous solutions by adsorption onto bentonite clay, 63 (2006) 1842-1848.

DOI: 10.1016/j.chemosphere.2005.10.033

[20] C.-H. Weng, Y.-F. Pan, Journal of hazardous materials, Adsorption of a cationic dye (methylene blue) onto spent activated clay, 144 (2007) 355-362.

DOI: 10.1016/j.jhazmat.2006.09.097

[21] H. Yuh-Shan, Scientometrics, Citation review of Lagergren kinetic rate equation on adsorption reactions, 59 (2004) 171-177.

DOI: 10.1023/b:scie.0000013305.99473.cf

[22] L. Wang, A. Wang, Journal of hazardous materials, Adsorption properties of Congo Red from aqueous solution onto surfactant-modified montmorillonite, 160 (2008) 173-180.

DOI: 10.1016/j.jhazmat.2008.02.104

[23] A.S. Özcan, A. Özcan, Journal of colloid and interface science, Adsorption of acid dyes from aqueous solutions onto acid-activated bentonite, 276 (2004) 39-46.

DOI: 10.1016/j.jcis.2004.03.043

[24] V. Vimonses, S. Lei, B. Jin, C.W. Chow, C. Saint, Chemical Engineering Journal, Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials, 148 (2009) 354-364.

DOI: 10.1016/j.cej.2008.09.009

[25] H.B. Senturk, D. Ozdes, C. Duran, Desalination, Biosorption of Rhodamine 6G from aqueous solutions onto almond shell (Prunus dulcis) as a low cost biosorbent, 252 (2010) 81-87.

DOI: 10.1016/j.desal.2009.10.021

[26] R.K. Gautam, M.C. Chattopadhyaya, Nanomaterials for wastewater remediation, Butterworth-Heinemann, (2016).

[27] A.M. Din, B.H. Hameed, Journal of Applied Sciences in Environmental Sanitation, Adsorption of methyl violet dye on acid modified activated carbon: isotherms and thermodynamics, 5 (2010) 161-170.

[28] V.K. Gupta, A. Mittal, V. Gajbe, Journal of colloid and interface science, Adsorption and desorption studies of a water soluble dye, Quinoline Yellow, using waste materials, 284 (2005) 89-98.

DOI: 10.1016/j.jcis.2004.09.055

[29] A. Khenifi, Z. Bouberka, F. Sekrane, M. Kameche, Z. Derriche, Adsorption, Adsorption study of an industrial dye by an organic clay, 13 (2007) 149-158.

DOI: 10.1007/s10450-007-9016-6

[30] I. Chaari, E. Fakhfakh, S. Chakroun, J. Bouzid, N. Boujelben, M. Feki, F. Rocha, F. Jamoussi, Journal of hazardous materials, Lead removal from aqueous solutions by a Tunisian smectitic clay, 156 (2008) 545-551.

DOI: 10.1016/j.jhazmat.2007.12.080

[31] W.-T. Tsai, H.-C. Hsu, T.-Y. Su, K.-Y. Lin, C.-M. Lin, T.-H. Dai, Journal of hazardous materials, The adsorption of cationic dye from aqueous solution onto acid-activated andesite, 147 (2007) 1056-1062.

DOI: 10.1016/j.jhazmat.2007.01.141

[32] C.-H. Weng, Y. Sharma, S.-H. Chu, Journal of hazardous materials, Adsorption of Cr (VI) from aqueous solutions by spent activated clay, 155 (2008) 65-75.

DOI: 10.1016/j.jhazmat.2007.11.029

[33] A.K.K. Mayeko, P.N. Vesituluta, J.N. Di Phanzu, D.M.W. Muanda, G.E. Bakambo, B.I. Lopaka, J.M. Mulangala, International Journal of Biological and Chemical Sciences, Adsorption de la quinine bichlorhydrate sur un charbon actif peu coûteux à base de la Bagasse de canne à sucre imprégnée de l'acide phosphorique, 6 (2012) 1337-1359.

DOI: 10.4314/ijbcs.v6i3.36

[34] C. Almeida, N. Debacher, A. Downs, L. Cottet, C. Mello, Sci, (2009).

[35] L. Zhang, H. Zhang, W. Guo, Y. Tian, Applied Clay Science, Removal of malachite green and crystal violet cationic dyes from aqueous solution using activated sintering process red mud, 93 (2014) 85-93.

DOI: 10.1016/j.clay.2014.03.004

[36] Z. Huang, Y. Li, W. Chen, J. Shi, N. Zhang, X. Wang, Z. Li, L. Gao, Y. Zhang, Materials Chemistry and Physics, Modified bentonite adsorption of organic pollutants of dye wastewater, 202 (2017) 266-276.

DOI: 10.1016/j.matchemphys.2017.09.028

[37] M. Doğan, Y. Özdemir, M. Alkan, Dyes and Pigments, Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite, 75 (2007) 701-713.

DOI: 10.1016/j.dyepig.2006.07.023

[38] A. Gürses, Ç. Doğar, M. Yalçın, M. Açıkyıldız, R. Bayrak, S. Karaca, Journal of hazardous materials, The adsorption kinetics of the cationic dye, methylene blue, onto clay, 131 (2006) 217-228.

DOI: 10.1016/j.jhazmat.2005.09.036

[39] G. Rytwo, R. Huterer-Harari, S. Dultz, Y. Gonen, Journal of thermal analysis and calorimetry, Adsorption of fast green and erythrosin-B to montmorillonite modified with crystal violet, 84 (2006) 225-231.

DOI: 10.1007/s10973-005-7187-5

[40] G. Rytwo, E. Ruiz-Hitzky, Journal of thermal analysis and calorimetry, Enthalpies of adsorption of methylene blue and crystal violet to montmorillonite, 71 (2003) 751-759.

[41] M. Kara, H. Yuzer, E. Sabah, M. Celik, Water research, Adsorption of cobalt from aqueous solutions onto sepiolite, 37 (2003) 224-232.

DOI: 10.1016/s0043-1354(02)00265-8

[42] L. Lian, L. Guo, C. Guo, Journal of hazardous materials, Adsorption of Congo red from aqueous solutions onto Ca-bentonite, 161 (2009) 126-131.

DOI: 10.1016/j.jhazmat.2008.03.063

[43] R. Mudzielwana, M.W. Gitari, P. Ndungu, Frontiers in chemistry, Enhanced As (III) and As (V) adsorption from aqueous solution by a clay based hybrid sorbent, 7 (2019).

DOI: 10.3389/fchem.2019.00913

[44] C. Almeida, N. Debacher, A. Downs, L. Cottet, C. Mello, Journal of colloid and interface science, Removal of methylene blue from colored effluents by adsorption on montmorillonite clay, 332 (2009) 46-53.

DOI: 10.1016/j.jcis.2008.12.012

[45] S. Hong, C. Wen, J. He, F. Gan, Y.-S. Ho, Journal of hazardous materials, Adsorption thermodynamics of methylene blue onto bentonite, 167 (2009) 630-633.

DOI: 10.1016/j.jhazmat.2009.01.014

[46] A. Rostami, M.A. Anbaz, H.R.E. Gahrooei, M. Arabloo, A. Bahadori, Egyptian Journal of Petroleum, Accurate estimation of CO2 adsorption on activated carbon with multi-layer feed-forward neural network (MLFNN) algorithm, 27 (2018) 65-73.

DOI: 10.1016/j.ejpe.2017.01.003