Promising Organic Inhibitor of Salak (Salacca zalacca) Peel Extract on AISI 1040

Article Preview

Abstract:

This study investigates the corrosion inhibition properties of Salak (Salacca zalacca) peel extract as a green inhibitor on AISI 1040 steel in a 1M HCl acidic environment and focusing on secondary metabolites such as flavonoids and tannins. The qualitative phytochemical analysis showed antioxidant activity of the inhibitor extract was categorized as moderate with an IC50 value of 105.219 ppm. Functional group analysis using FTIR indicated that the flavonoids and tannins in the extract acted as antioxidants and inhibited corrosion growth. The weight loss test revealed the highest inhibition efficiency 11.13% was achieved at a concentration of 200 ppm after 20 days of immersion. In the potentiodynamic polarization test, the corrosion rate was 0.025 mm/year at the same concentration and immersion time. These results suggest that Salak (Salacca zalacca) peel extract can effectively inhibit corrosion at spesific concentrations but its efficiency diminishes at higher concentrations.

You have full access to the following eBook
You might also be interested in these eBooks

Info:

* - Corresponding Author

[1] S. Prifiharni et al., "Extract sarampa wood (Xylocarpus Moluccensis) as an eco-friendly corrosion inhibitor for mild steel in HCl 1M," Journal of the Indian Chemical Society, vol. 99, no. 7, Jul. 2022.

DOI: 10.1016/j.jics.2022.100520

Google Scholar

[2] P. C. Okafor, X. Liu, and Y. G. Zheng, "Corrosion inhibition of mild steel by ethylamino imidazoline derivative in CO2-saturated solution," Corrosion Science, vol. 51, no. 4, p.761–768, Apr. 2009.

DOI: 10.1016/j.corsci.2009.01.017

Google Scholar

[3] R. Landolfo, L. Cascini, and F. Portioli, "Modeling of metal structure corrosion damage: A state of the art report," Sustainability, vol. 2, no. 7, p.2163–2175, 2010.

DOI: 10.3390/su2072163

Google Scholar

[4] M. G., & G. N. D. Fontana, Corrosion Engineering McGraw-Hill book Company. New York, 1987.

Google Scholar

[5] K. Hu, J. Zhuang, J. Ding, Z. Ma, F. Wang, and X. Zeng, "Influence of biomacromolecule DNA corrosion inhibitor on carbon steel," Corrosion Science, vol. 125, p.68–76, Aug. 2017.

DOI: 10.1016/j.corsci.2017.06.004

Google Scholar

[6] C.G. Soares, "SPECIAL ISSUE ON IMAM 2007." [Online]. Available: https://www.researchgate.net/publication/278353484

Google Scholar

[7] W. Xu et al., "Corrosion of rail tracks and their protection," Corrosion Reviews, vol. 39, no. 1. De Gruyter Open Ltd, p.1–13, Feb. 01, 2021.

DOI: 10.1515/corrrev-2020-0069

Google Scholar

[8] I. Radojčić, K. Berković, S. Kovač, and J. Vorkapić-Furač, "Natural honey and black radish juice as tin corrosion inhibitors," Corrosion Science, vol. 50, no. 5, p.1498–1504, May 2008.

DOI: 10.1016/j.corsci.2008.01.013

Google Scholar

[9] Z. D. I. Esih, "Technology of Corrosion Protection," 1990.

Google Scholar

[10] H. Ashassi-Sorkhabi and E. Asghari, "Effect of hydrodynamic conditions on the inhibition performance of l-methionine as a 'green' inhibitor," Electrochimica Acta, vol. 54, no. 2, p.162–167, Dec. 2008.

DOI: 10.1016/j.electacta.2008.08.024

Google Scholar

[11] X. Li, S. Deng, G. Mu, H. Fu, and F. Yang, "Inhibition effect of nonionic surfactant on the corrosion of cold rolled steel in hydrochloric acid," Corrosion Science, vol. 50, no. 2, p.420–430, Feb. 2008.

DOI: 10.1016/j.corsci.2007.08.014

Google Scholar

[12] J. Aljourani, M. A. Golozar, and K. Raeissi, "The inhibition of carbon steel corrosion in hydrochloric and sulfuric acid media using some benzimidazole derivatives," Materials Chemistry and Physics, vol. 121, no. 1–2, p.320–325, May 2010.

DOI: 10.1016/j.matchemphys.2010.01.040

Google Scholar

[13] M. Finšgar, S. Fassbender, F. Nicolini, and I. Milošev, "Polyethyleneimine as a corrosion inhibitor for ASTM 420 stainless steel in near-neutral saline media," Corrosion Science, vol. 51, no. 3, p.525–533, Mar. 2009.

DOI: 10.1016/j.corsci.2008.12.006

Google Scholar

[14] Q. B. Zhang and Y. X. Hua, "Corrosion inhibition of mild steel by alkylimidazolium ionic liquids in hydrochloric acid," Electrochimica Acta, vol. 54, no. 6, p.1881–1887, Feb. 2009.

DOI: 10.1016/j.electacta.2008.10.025

Google Scholar

[15] M. Seter, M. J. Thomson, J. Stoimenovski, D. R. MacFarlane, and M. Forsyth, "Dual active ionic liquids and organic salts for inhibition of microbially influenced corrosion," Chemical Communications, vol. 48, no. 48, p.5983–5985, May 2012.

DOI: 10.1039/c2cc32375c

Google Scholar

[16] D. Gopi, K. M. Govindaraju, and L. Kavitha, "Investigation of triazole derived Schiff bases as corrosion inhibitors for mild steel in hydrochloric acid medium," Journal of Applied Electrochemistry, vol. 40, no. 7, p.1349–1356, Jul. 2010.

DOI: 10.1007/s10800-010-0092-z

Google Scholar

[17] E. Kowsari, M. Payami, R. Amini, B. Ramezanzadeh, and M. Javanbakht, "Task-specific ionic liquid as a new green inhibitor of mild steel corrosion," Applied Surface Science, vol. 289, p.478–486, Jan. 2014.

DOI: 10.1016/j.apsusc.2013.11.017

Google Scholar

[18] D. Bizuayehu, M. Atlabachew, and M. T. Ali, "Determination of some selected secondary metabolites and their invitro antioxidant activity in commercially available Ethiopian tea (Camellia sinensis)," SpringerPlus, vol. 5, no. 1, Dec. 2016.

DOI: 10.1186/s40064-016-2056-1

Google Scholar

[19] N. Moonrungsee, N. Peamaroon, A. Boonmee, S. Suwancharoen, and J. Jakmunee, "Evaluation of tyrosinase inhibitory activity in Salak (Salacca zalacca) extracts using the digital image-based colorimetric method," Chemical Papers, vol. 72, no. 11, p.2729–2736, Nov. 2018.

DOI: 10.1007/s11696-018-0528-1

Google Scholar

[20] M. S. M. Saleh, M. J. Siddiqui, S. Z. M. Soad, S. Murugesu, A. Khatib, and M. M. Rahman, "Antioxidant and α-glucosidase inhibitory activities and gas chromatography-mass spectrometry profile of salak (Salacca zalacca) fruit peel extracts," Pharmacognosy Research, vol. 10, no. 4, p.385–390, Oct. 2018.

DOI: 10.4103/pr.pr_7_18

Google Scholar

[21] H. Hassannejad and A. Nouri, "Sunflower seed hull extract as a novel green corrosion inhibitor for mild steel in HCl solution," Journal of Molecular Liquids, vol. 254, p.377–382, Mar. 2018.

DOI: 10.1016/j.molliq.2018.01.142

Google Scholar

[22] M. J. B. Kabeyi and O. A. Olanrewaju, "Biogas Production and Applications in the Sustainable Energy Transition," Journal of Energy, vol. 2022, p.1–43, Jul. 2022.

DOI: 10.1155/2022/8750221

Google Scholar

[23] M. M. Kamel, A. A. S. Fouda, S. M. Rashwan, and O. Abdelkader, "Paprika extract: a green inhibitor for mitigating carbon steel disintegration in 1 M HCl pickling solution," Green Chemistry Letters and Reviews, vol. 14, no. 4. Taylor and Francis Ltd., p.598–609, 2021.

DOI: 10.1080/17518253.2021.1985173

Google Scholar

[24] G. Ji, S. Anjum, S. Sundaram, and R. Prakash, "Musa paradisica peel extract as green corrosion inhibitor for mild steel in HCl solution," Corrosion Science, vol. 90, p.107–117, Jan. 2015.

DOI: 10.1016/j.corsci.2014.10.002

Google Scholar

[25] J. C. da Rocha, J. A. da Cunha Ponciano Gomes, and E. D'Elia, "Aqueous extracts of mango and orange peel as green inhibitors for carbon steel in hydrochloric acid solution," Materials Research, vol. 17, no. 6, p.1581–1587, Nov. 2014.

DOI: 10.1590/1516-1439.285014

Google Scholar

[26] Q. Liu et al., "A novel green reinforcement corrosion inhibitor extracted from waste Platanus acerifolia leaves," Construction and Building Materials, vol. 260, Nov. 2020.

DOI: 10.1016/j.conbuildmat.2020.119695

Google Scholar

[27] A. Berrissoul et al., "Evaluation of Lavandula mairei extract as green inhibitor for mild steel corrosion in 1 M HCl solution. Experimental and theoretical approach," Journal of Molecular Liquids, vol. 313, Sep. 2020.

DOI: 10.1016/j.molliq.2020.113493

Google Scholar

[28] "ASTM-G31-72-1999-".

Google Scholar