Nanocrystalline Zirconium Oxide Thin Films Prepared by Filtered Cathodic Vacuum Arc

Article Preview

Abstract:

Zirconium oxide thin films were deposited at room temperature by using off-plane filtered cathodic vacuum arc (FCVA). Deposition rate, film structure, compositional analysis and optical properties are studied as a function of working pressure. Deposition rate as high as 53 nm/min could be achieved. As increasing working pressure, the film structure changes from Zr-O solid solution, to monoclinic structure with preferred orientation and finally to randomly oriented nanocrystalline structure. The averaged crystal size increases with working pressure and is less than 15 nm. The ratio of O/Zr increases with working pressure as well as transmittance and good stoichiometric film could be achieved with high transmittance of 91% at high working pressure.

You might also be interested in these eBooks

Info:

Pages:

63-66

Citation:

Online since:

January 2005

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2005 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] G.C. Hadjipanayis and R.W. Siegel: Nanophase Materials: Synthesis-Properties-Applications (Kluwer, Dordrecht, 1994).

Google Scholar

[2] Y.M. Chiang, E.B. Lavik, I. Kosacki, H.L. Tuller and J.Y. Ying: Appl. Phys. Lett. Vol. 69 (1996), p.185.

Google Scholar

[3] I. Kosacki and H.U. Anderson: Appl. Phys. Lett. Vol. 69 (1996), p.4171.

Google Scholar

[4] I. Kosacki, V. Petrovsky and H.U. Anderson: Appl. Phys. Lett. Vol. 74 (1999), p.341.

Google Scholar

[5] Z.W. Zhao, B.K. Tay, S.P. Lau and C.Y. Xiao, J. Vac. Sci. Technol. A Vol. 21 (2003), p.906.

Google Scholar

[6] Z.W. Zhao, B.K. Tay and G.Q. Yu, Applied optics (2003), accepted.

Google Scholar

[7] E. Ryshkewitz and D.W. Richardson: Oxide Ceramic, Physical Chemistry and Technology (General Ceramics, Haskell, NJ, 1985).

Google Scholar

[8] S. Meriani: Zriconia'88, Advances in Zirconia Science and Technology (Elsevier, New York, 1989).

Google Scholar

[9] X. Shi, B.K. Tay and H. S. Tan: US Patent No. 6031239 (29 February 2000).

Google Scholar

[10] X. Shi, B.K. Tay and S.P. Lau: Int. J. Mod. Phys. B Vol. 14 (2000), p.136.

Google Scholar

[11] G. P. Abriata, J. Garces and R. Versaci: Bull. Alloy Phase Diag. Vol. 7 (1986), p.116.

Google Scholar

[12] M.S. Wong, W.J. Chia, P. Yashar, J.M. Schneidere, W.D. Sproul and S.A. Barnett, Surf. Coat. Technol. Vol. 86-87 (1996), p.381.

Google Scholar

[13] K. Koski, J. Holsa and P. Juliet: Surf. Coat. Technol. Vol. 120-121 (1999), p.303.

Google Scholar

[14] B.D. Cullity: Elements of X-ray Diffraction (2 nd Edition) (Addison Wesley, 1978) p.102.

Google Scholar

[15] P. Gao, L.J. Meng, M.P. dos Santos, V. Teixeira and M. Andritschky: Vacuum Vol. 56 (2000), p.143.

Google Scholar