L3xLa2/3-XTiO3 Nanoparticles Obtained from a Low Temperature Synthesis Route

Article Preview

Abstract:

In this work, the synthesis of Li3xLa2/3-xTiO3 oxide is studied by thermal decomposition of citrate precursor at very low temperature which has not been yet reported in the literature for these compounds. The characterization of oxides and its precursor was realized by DRX, IR, ATD and TEM techniques. The results show the formation of a new chemical compound (precursor) as well as several advantages of the citrate method in relation to reported ones in the literature: the ostensible decreasing of temperature Li3xLa2/3-xTiO3 formation and the decreasing of particle size on the nanometric scale which is very desirable for the electrochemical application.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

105-111

Citation:

Online since:

April 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. K. Shukla, T. P. Kumarl, Materials for next-generation lithium batteries, Current Science. 94 (2008) 314-334.

Google Scholar

[2] S. Chandra, Superionics Solids: Principles and Applications, North-Holland Publishing Company, Amsterdam, (1981).

Google Scholar

[3] C. Richard, A. Catlow, Atomistic mechanisms of ionic transport in fast-ion conductors, J. Chem. Soc. Faraday Trans. 86 (1990) 1167-1176.

DOI: 10.1039/ft9908601167

Google Scholar

[4] C. R. Milian, Síntesis y caracterización del compósito Li0. 5La0. 5TiO3/PANY, Master of Science Thesis. Havana University. Havana, (2009).

Google Scholar

[5] E. Perez Cappe, Y. Mosqueda, R. Martinez, C.R. Milian, O. Sanchez, J.A. Varela, A.H. Miranda, E. Souza, P. Aranda, E. Ruiz-Hitzky, Preparation and properties as positive electrodes of PANI-LiNi0. 8Co0. 2O2 nanocomposites, J. Mater. Chem. 18 (2008).

DOI: 10.1039/b803874k

Google Scholar

[6] A.G. Belous, V.I. Butko, G.N. Novitskaya, S.V. Polianetskaya, B.S. Khomenko, Y.M. Poplavko, Conductivity of La sub(2/3-x)M sub(3x)TiO sub(3) perovskites, J. UKR. PHYS. 31 (1986) 576-581.

Google Scholar

[7] Y. Inaguma, C. Liquan, M. Itoh, T, Nakamura, T, Uchida, H. Ikuta, M. Wakihara, High ionic conductivity in lithium lanthanum titanate, Solid State Commun . 86 (1993) 689-693.

DOI: 10.1016/0038-1098(93)90841-a

Google Scholar

[8] T. Ishihara., Perovskite Oxide for Solid Oxide Fuel Cells (Fuel Cells and Hydrogen Energy), Firth ed., Springer Dordrecht Heidelberg, London, (2009).

DOI: 10.1007/978-0-387-77708-5

Google Scholar

[9] P. V. Patil, V. S. Chincholkar, Solubility limit of Li0. 5La0. 5TiO3 in BaTiO3, Current. Science. 39 (1970) 348-348.

Google Scholar

[10] P. V. Patil,V. S Chincholkar, Structural studies in the system(Li0. 5Ln0. 5)TiO3. Indian. J. Chem. 16A (1978) 161–162.

Google Scholar

[11] Y. Harada, Y. Hirakoso, H. Kawai, J. Kuwano, Order-disorder of the A-site ions and lithium ion conductivity in the perovskite solid solution La0. 67-xLi3xTiO3 (x=0. 11), Solid State Ionics. 121 (1999) 245-251.

DOI: 10.1016/s0167-2738(99)00043-0

Google Scholar

[12] M. Nakayama, T. Usui, Y. Uchimoto, M. Wakihara, M. Yamamoto, Changes in Electronic Structure upon Lithium Insertion into the A-Site Deficient Perovskite Type Oxides (Li, La)TiO3. The Journal of Physical Chemistry. 109, (2005) 4135-4143.

DOI: 10.1021/jp046062j

Google Scholar

[13] O. Bohnke, Cl. Bohnke, J.L. Fourquet, Mechanism of ionic conduction and electrochemical intercalation of lithium into the perovskite lanthanum lithium titanate, Solid State Ionics. 91 (1996) 21-31.

DOI: 10.1016/s0167-2738(96)00434-1

Google Scholar

[14] T. Wöhrle, P. Gomez-Romero, T. Fries, K. West, M.R. Palacin, N. Casan-Pastor, Sol-gel synthesis of the lithium-ion conducting perovskita, Ionics. 2 (1996) 442-445.

DOI: 10.1007/bf02375824

Google Scholar

[15] K. Kitaoka, H. Kozuka, T. Hashimoto, T. Yoko, Preparation of La0. 5Li0. 5TiO3 perovskite thin films by the sol–gel method, J. Mater. Science. 32 (1997) 2063-(2070).

DOI: 10.1023/a:1018566620564

Google Scholar

[16] M. Vijayakumar, Y. Inaguma, W. Mashiko, M.P. Crosnier-López, C. Bhonke, Synthesis of Fine Powders of Li3xLa2/3-xTiO3 Perovskite by a Polymerizable Precursor Method. J. Mater. Chem. 16 (2004) 2719-2724.

DOI: 10.1021/cm049869x

Google Scholar

[17] J. -H. Choy, Y. -S. Han, J. -T. Kim,Y. -H. Kim, Citrate route to ultra-fine barium polytitanates with microwave dielectric properties J. Mater. Chem. 5 (1995) 57-63.

DOI: 10.1039/jm9950500057

Google Scholar

[18] E. Zhecheva, R. Stoyanova, M. Gorova, R. Alcántara, J. Morales, J.L. Tirado, Lithium-Cobalt Citrate Precursors in the Preparation of Intercalation Electrode Materials, J. Mater. Chem. 8 (1996) 1429-1440.

DOI: 10.1021/cm960009t

Google Scholar

[19] K. Nakamoto., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Fourth ed., John Wiley & Sons, New York, (1986).

Google Scholar

[20] Cl. Bohnke, B. Regrag, F.L. Berre, J. Fourquet, N. Randrianantoandro, Comparison of pH sensitivity of lithium lanthanum titanate obtained by sol-gel synthesis and solid state chemistry, Solid State Ionics. 176 (2005) 73-80.

DOI: 10.1016/j.ssi.2004.06.010

Google Scholar

[21] J. Ibarra, A. Várez, C. León, J. Santamaría, L. M. Torres-Martínez, J. Sanz, Influence of composition on the structure and conductivity of the fast ionic conductors La2/3-xLi3xTiO3 (0. 03<=x<=0. 167), Solid State Ionics. 134 (2000) 219-228.

DOI: 10.1016/s0167-2738(00)00761-x

Google Scholar

[22] Y. Harada, T. Ishigaki, H. Kawai, J. Kuwano, Lithium ion conductivity of polycrystalline perovskite La0. 67-xLi3xTiO3 with ordered and disordered arrangements of the A-site ions, Solid State Ionics. 108 (1998) 407-413.

DOI: 10.1016/s0167-2738(98)00070-8

Google Scholar

[23] O. Bohnke, The fast lithium-ion conducting oxides Li3xLa2/3 - xTiO3 from fundamentals to application, Solid State Ionics. 179 (2008) 9-15.

DOI: 10.1016/j.ssi.2007.12.022

Google Scholar

[24] O. Bohnke, C. Bohnke, J. L. Fourquet, Mechanism of ionic conduction and electrochemical intercalation of lithium into the perovskite lanthanum lithium titanate, Solid State Ionics. 91 (1996) 21-31.

DOI: 10.1016/s0167-2738(96)00434-1

Google Scholar