Preparation and Characterization of Carbon Nanotubes/Al2O3 Inorganic Hybrid Material - A Bio-Inspired Poly(Dopamine) Approach

Article Preview

Abstract:

Carbon nanotubes/alumina (CNTs/Al2O3) nanocomposites were prepared by the poly (dopamine) assisted chemical liquid phase deposition (CLPD). The poly (dopamine) layers were firstly coated on the CNTs surface uniformly by the self-oxidative polymerization of dopamine in mild aqueous solution and then the Al2O3 nanoparticles formed on the poly (dopamine) coated CNTs surface by the CLPD. The hydrophilic poly (dopamine) layers on the CNTs surface can improve the dispersion of CNTs in aqueous solution. Moreover, it can be used as a key linker between the CNTs and Al2O3 because of the nitrogen-containing group in poly (dopamine) could coordinate with Al3+ ions. The as-prepared poly (dopamine) coated CNTs and CNTs/Al2O3 nanohybrids were characterized by X-ray photoelectron spectroscopy (XPS), X-radial diffractometer (XRD) and high resolution transmission electron microscopy (HRTEM). These results showed that the poly (dopamine) layers were coated on the surface of CNTs uniformly, and the Al2O3 nanoparticles embellished with the poly (dopamine) coated CNTs surface. Compared with pristine NR composites, the thermal conductivity of the as-prepared NR/CNTs@Al2O3 composites increased 17%.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

127-135

Citation:

Online since:

August 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. D. Gardener, B. J. Queiser, Introduction to Tire Safety, Durability, and Failure Analysis in Pneumatic Tire. Administration U. S. Department of Transportation, (2005).

Google Scholar

[2] Z.X. Jia, B.C. Guo, and D.M. Jia, Advances in rubber/halloysite nanotubes nanocomposites. J Nanosci Nanotechnol. 14(2014) 1758-1771.

DOI: 10.1166/jnn.2014.9124

Google Scholar

[3] Z.Q. Shen, S. Bateman, D.Y. Wu, P. McMahon, M. Dell'Olio, J. Gotama, The effects of carbon nanotubes on mechanical and thermal properties of woven glass fibre reinforced polyamide-6 nanocomposites. Compos. Sci. Technol. 69(2009) 239-244.

DOI: 10.1016/j.compscitech.2008.10.017

Google Scholar

[4] C.W. Nan, G. Liu, Y.H. Lin, M. Li, Interface effect on thermal conductivity of carbon nanotube composites, Appl. Phys. Lett. 85(2004) 3549-3551.

DOI: 10.1063/1.1808874

Google Scholar

[5] A.Yu , P.Ramesh, X. Sun, E. Bekyarova, M.E. Itkis, R.C. Haddon, Enhanced thermal conductivity in a hybrid graphite nanoplatelet–carbon nanotube filler for epoxy composites, Adv. Mater. 20(2008) 4740-4744.

DOI: 10.1002/adma.200800401

Google Scholar

[6] J.A. King, B.A. Johnson, M.D. Via, C.J. Ciarkowski, Effects of carbon fillers in thermally conductive polypropylene based resins, Polym. Compos. 31(2010) 497-506.

DOI: 10.1002/pc.20830

Google Scholar

[7] J.A. King, D.L. Gaxiola, B.A. Johnson, J.M. Keith, Thermal conductivity of carbon-filled polypropylene-based resins, J. Compos. Mater. 44(2010) 839-855.

DOI: 10.1177/0021998309347578

Google Scholar

[8] S. Sihn, S. Ganguli, A.K. Roy, L. Qu, L.M. Dai, Enhancement of through-thickness thermal conductivity in adhesively bonded joints using aligned carbon nanotubes, Compos. Sci. Technol. 68(2008) 658-665.

DOI: 10.1016/j.compscitech.2007.09.016

Google Scholar

[9] Y.G. Zhang, P. Yan, Preparation and Application of Nano-alumina, Inorg. Chem. Indus. 33(2001) 19-22.

Google Scholar

[10] W. Zhao, L.J. Zhu, Y.L. Lu, L.Q. Zhang, R.H. Schuster, W.C. Wang, Magnetic nanoparticles decorated multi-walled carbon nanotubes by bio-inspired poly (dopamine) surface functionalization, Synth. Met. 169(2013) 59-63.

DOI: 10.1016/j.synthmet.2013.03.004

Google Scholar

[11] A. Postma, Y. Yan, Y.J. Wang, A.N. Zelikin, E. Tjipto, F. Caruso, Self-polymerization of dopamine as a versatile and robust technique to prepare polymer capsules, Chem. Mater. 21(2009) 3042-3044.

DOI: 10.1021/cm901293e

Google Scholar

[12] H. Lee, Y. Lee, A.R. Statz, J. Rho, T.G. Park, P.B. Messersmith, Substrate-independent layer-by-layer assembly by using mussel-adhesive-inspired polymers, Adv. Mater. 20(2008) 1619-1623.

DOI: 10.1002/adma.200702378

Google Scholar

[13] T.L. Wang, C.G. Tseng, Polymeric carbon nanocomposites from multiwalled carbon nanotubes functionalized with segmented polyurethane, J. Appl. Polym. Sci. 105(2007) 1642-1650.

DOI: 10.1002/app.26224

Google Scholar