Influence of Ag Content on the Microstructure, Mechanical, and Tribological Properties of ZrN-Ag Films

Article Preview

Abstract:

A series of ZrN-Ag nano-composite films were deposited using the RF magnetron sputtering system. The microstructure, mechanical properties and tribological performances were investigated. The results showed that ZrN-Ag films were composed of face-centered cubic (fcc)-ZrN and face-centered cubic (fcc)-Ag. With the increase of Ag content, the hardness of ZrN-Ag composite film increased rapidly and then decreased rapidly. The maximum hardness value was 22.8 GPa at 6.1at.% Ag. At room temperature, the coefficient of friction (Cof.) of ZrN-Ag films were lower than the ZrN film. During 25-500°C, the Cof. of ZrN-Ag films at 29.16 at.% Ag were lower than ZrN film, while the wear rate were higher than the ZrN film. In summary, the addition of Ag improved the hardness, and decreased the Cof. of the ZrN-Ag during 25-500°C.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

88-97

Citation:

Online since:

August 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Yu L, Luo H, Bian J G, et al. Research on Microstructure, Mechanical and Tribological Properties of Cr-Ti-B-N Films[J]. Coatings. 2017, 7(9), 137.

DOI: 10.3390/coatings7090137

Google Scholar

[2] L.H. Yu, Y. Li, H.B. Ju, and J.H. Xu, Microstructure, mechanical and tribological properties of magnetron sputtered VCN films, surf. Eng. (2017).

DOI: 10.1080/02670844.2016.1277630

Google Scholar

[3] Ju H, Yu D, Yu L, et al. The influence of Ag contents on the microstructure, mechanical and tribological properties of ZrN-Ag films[J]. Vacuum, 2017, 148.

DOI: 10.1016/j.vacuum.2017.10.029

Google Scholar

[4] J.H. Xu, H.B. Ju, and L.H. Yu, Microstructure, oxidation resistance, mechanical and tribological properties of Mo-Al-N films by reactive magnetron sputtering, Vacuum, 103(2014), pp.21-27.

DOI: 10.1016/j.vacuum.2013.11.013

Google Scholar

[5] I. MILOSEV, STREHBLOW H H, NAVINSEK B. Comparison of TiN, ZrN and CrN hard nitride coatings: Electrochemical and thermal oxidation[J]. Thin Solid Films, 1997, 303:246-254.

DOI: 10.1016/s0040-6090(97)00069-2

Google Scholar

[6] Huang J H, Ho C H, Yu G P. Effect of nitrogen flow rate on the structure and mechanical properties of ZrN thin films on Si(100) and stainless steel substrates[J]. Material Chemistry and Physics, 2007, 102:31-38.

DOI: 10.1016/j.matchemphys.2006.10.007

Google Scholar

[7] Pilloud D, Pierson J F, Cavaleiro A, Marco De Lucas M C. Effect of germanium addition on the properties of reactively sputtered ZrN films[J]. Thin Solid Films, 2005, 492:180-186.

DOI: 10.1016/j.tsf.2005.06.051

Google Scholar

[8] Lopez G, Staia M H. High-temperature tribological characterization of zirconium nitride coatings[J]. Surface and Coatings Technology, 2005, 200:2092-(2099).

DOI: 10.1016/j.surfcoat.2004.08.221

Google Scholar

[9] Deng J X, Liu J H, Zhao J L, Song W L, Niu M. Friction and wear behaviors of the PVD ZrN coated carbide in sliding wear tests and in machining processes[J]. Wear, 2008, 264:298-307.

DOI: 10.1016/j.wear.2007.03.014

Google Scholar

[10] I. Milošev, H. H. Strehblow, B. Navinšek. Comparison of TiN, ZrN and CrN hard nitride coatings: Electrochemical and thermal oxidation[J]. Thin Solid Films, 1997, 303(1–2):246-254.

DOI: 10.1016/s0040-6090(97)00069-2

Google Scholar

[11] H.B. Ju, L.H. Yu, D. Yu, I. Asempah, and J.H. Xu, Microstructure, mechanical and trobological properties of TiN-Ag films deposited by reactive magnetron sputtering, Vacuum, 141(2017), pp.82-88.

DOI: 10.1016/j.vacuum.2017.03.026

Google Scholar

[12] H.B. Ju and J.H. Xu, Microstructure and tribological properties of NbN-Ag composite films by reactive magnetron sputtering, Appl. Surf. Sci., 355(2015), pp.878-883.

DOI: 10.1016/j.apsusc.2015.07.114

Google Scholar

[13] C.P. Mulligan and D. Gall, CrN-Ag self-lubricating hard coatings, Surf. Coat. Technol., 200(2005), pp.1495-1500.

DOI: 10.1016/j.surfcoat.2005.08.063

Google Scholar

[14] C.P. Mulligan, T.A. Blanchet, and D. Gall, CrN-Ag nanocomposite coatings: High-temperature tribological response, Wear, 269(2010), pp.125-131.

DOI: 10.1016/j.wear.2010.03.015

Google Scholar

[15] C.P. Mulligan, T.A. Blanchet, and D. Gall, CrN-Ag nanocomposite coatings: Tribology at room temperature and during a temperature ramp, Surf. Coat. Technol., 204(2010), pp.1388-1394.

DOI: 10.1016/j.surfcoat.2009.09.018

Google Scholar

[16] S.M. Aouadi, D.P. Singh, D.S. Stone, K. Polychronopoulou, F. Nahif, C. Rebholz, C. Muratore, and A.A. Voevodin, Adaptive VN/Ag nanocomposite coatings with lubricious behavior from 25 to 1000 °C, Acta Mater., 58(2010), No. 16, pp.5326-5331.

DOI: 10.1016/j.actamat.2010.06.006

Google Scholar

[17] D.V. Shtansky, A.V. Bondarev, Ph.V. Kiryukhantsev-Korneev, T.C. Rojas, V. Godinho, and A. Fernández, Structure and tribological properties of MoCN-Ag coatings in the temperature range of 25-700°C, Appl. Surf. Sci.

DOI: 10.1016/j.apsusc.2013.02.055

Google Scholar

[18] Ali Erdemir. A crystal chemical approach to the formulation of self-lubricating composite coatings[J]. Surface & Coatings Technology, 2005, 200:1792 -1796.

DOI: 10.1016/j.surfcoat.2005.08.054

Google Scholar

[19] Z.W. Wu, F. Zhou, Q.W. Wang, Z.F. Zhou, and J.W. Yan, Influence of trimethylsilane flow on the microstructure, mechanical and tribological properties of CrSiCN coatings in water lubrication, Appl. Surf. Sci., 355(2015), pp.516-530.

DOI: 10.1016/j.apsusc.2015.07.146

Google Scholar

[20] L. Braginsky, A. Gusarov, V. Shklover, Surf. Coat. Technol. 2009, 204: 629.

Google Scholar

[21] J. Xu, H. Ju, L. Yu, Effects of Mo content on the microstructure and friction and wear properties of TiMoN films [J]. Acta Metallurgica Sinica. 2012, 48: 1132-1138.

DOI: 10.3724/sp.j.1037.2011.00751

Google Scholar

[22] Ziegele H, Rebholz C, Voevodin A A, et al. Studies of the tribological and mechanical properties of laminated CrC–SiC coatings produced by rf and dc sputtering[J]. Tribol. Int. 1997, 30:845-856.

DOI: 10.1016/s0301-679x(97)00059-5

Google Scholar

[23] K.E. Pappacena, D. Singh, O.O. Ajayi, J.L. Routbort, O.L. Erilymaz, N.G. Demas, and G. Chen, Residual stresses, interfacial adhesion and tribological properties of MoN/Cu composite coatings, Wear, 278(2012), pp.62-70.

DOI: 10.1016/j.wear.2012.01.007

Google Scholar

[24] Ming L T, Chang C M, Cheng B H, et al. Multi-level surface enhanced Raman scattering using AgOx thin film[J]. Optics Express, 2013, 21(21):24460-7.

DOI: 10.1364/oe.21.024460

Google Scholar

[25] Fujimaki M, Awazu K, Tominaga J, et al. Surface-enhanced Raman scattering from Ag nanoparticles formed by visible laser irradiation of thermally annealed AgOx thin films[J]. Journal of Applied Physics, 2006, 100(7):074303-074303-6.

DOI: 10.1063/1.2354329

Google Scholar

[26] Souissi A, Amlouk M, Khemakhem H, et al. Deep analysis of Raman spectra of ZnO:Mo and ZnO:In sprayed thin films along with LO and TA+LO bands investigation[J]. Superlattices & Microstructures, 2016, 92:294-302.

DOI: 10.1016/j.spmi.2016.02.024

Google Scholar

[27] Austin L A, Osseiran S, Evans C L. Raman technologies in cancer diagnostics[J]. Analyst, 2016, 141(2):476-503.

DOI: 10.1039/c5an01786f

Google Scholar

[28] Gilder S. Raman spectroscopy of the titanomagnetites: calibration of the intensity of Raman peaks as a sensitive indicator of the Ti content[J].

DOI: 10.2138/am.2011.3745

Google Scholar

[29] Muraoka K. Reaction steps of silicidation in ZrO2/SiO2/Si layered structure[J]. Applied Physics Letters, 2002, 80(24):4516-4518.

DOI: 10.1063/1.1486046

Google Scholar