For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Synthesis and Characterization of the Microwave Dielectric Properties of a (1-x) Li3MgNbO5–(x) Sr3V2O8 Composite for Antenna Application
p.33
Influence of Sintering Temperature on Microstructure and Dielectric Properties of Strontium Calcium Titanate (Sr0.9Ca0.1TiO3) Ceramics
p.43
Physical and Upconversion Photoluminescence Properties in Nd3+-Yb3+ Doped Lead Borate Glasses at 980 nm Excitation
p.49
Studies on Synthesis, Physical and Optical Properties of Dysprosium Ion-Doped Transparent Heavy Metal Oxide Glasses
p.57
Structural and some Mechanical Properties of Parquetina Nigrescens Pod Nanoparticles Reinforced Mixed Matrix Membrane for Dental Applications
p.67
Ready-to-Use Flowable Hydraulic Tricalcium Silicate-Based Dental Cement Paste with Antibiotic Releasing Capacity
p.83
Effect of Composition on Physical, Mechanical, and Thermal Properties of Oil Palm Empty Fruit Bunch Epoxy Resin Biocomposite
p.99
The Influence of Palm Oil-Based Zinc Stearate Application on Vulcanized Rubber: Analyzing Hardness, Tensile Strength, and Elongation at Break for Hand Grip Formulation Development
p.111
Modification of Cellulose Isolated from Coconut Dregs Using Glycidyl Methacrylate (GMA)
p.119

Structural and some Mechanical Properties of Parquetina Nigrescens Pod Nanoparticles Reinforced Mixed Matrix Membrane for Dental Applications

Article Preview

Abstract:

Polylactic acid (PLA) is a biocompatible, and biodegradable thermoplastic. It is renewable being produced by bacterial fermentation of potatoes, sugarcane, or corn starch. PLA has been attempted in many applications to replace petroleum-based polymers because some of its mechanical properties are excellent and it can be processed easily but low toughness and thermal stability are setbacks from one application to another. To improve on mechanical properties of the PLA to be suitable as biomaterials for dental and other applications, this study focuses on synthesis of Parquetina nigrescens pod nanoparticles (PNPNP) as reinforcements in the PLA to engineer new nanocomposites for biomedical applications. Chemical, structural and some mechanical properties were investigated. TEM result indicates an average size of 14.14 nm of the PNPNP used for reinforcing the PLA. Fourier Transform Infrared Spectrograph establishes a reduction in the amount of light transmitted by the PLA. This is due to PNPNP additions with changes in the wavenumbers of the observed peaks affirming formation of new compounds due to interactions of the PLA molecules and PNPNP. X-ray diffractograms reaffirms new compound formations. Moreover, there are enhancements in mechanical properties up to 3% by weight of PNPNP addition to the PLA with about 92% improvement in the impact toughness.

You might also be interested in these eBooks
Waste Treatment and Materials for Advanced Application View Preview

Info:

Periodical:

Key Engineering Materials (Volume 1001)

Pages:

67-82

DOI:

https://doi.org/10.4028/p-lh2kYq

Citation:

Cite this paper

Online since:

December 2024

Authors:

Sefiu Adekunle Bello*, Boluwatife Olukunle, Raphael Gboyega Adeyemo, Funsho Olaitan Kolawole, Mohammed Kayode Adebayo, Abdul Ganiyu Funsho Alabi, Sikiru Ottan Abdulraman

Keywords:

Parquetina nigrescens, Pod Nanoparticles, Polylactic Acid (PLA), Structural Features

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] I.S. Sihama, K.O. Jawad, S.M. Arkan, Investigation of mechanical properties of PMMA composite reinforced with different types of natural powders, ARPN Journal of Engineering and Applied Sciences, 13 (2018) 8889-8900.

Google Scholar

[2] S. Bose, A. Bandyopadhyay,Chapter 1- Introduction to Biomaterials, in: A. BandyopadhyayS. Bose Characterization of Biomaterials, Academic Press, Oxford, 2013, 1-9.

Google Scholar

[3] M. Saraswathy, V. Krishnaswami, D.D. Ragini,Biomaterials for Hard Tissue Engineering: Concepts, Methods, and Applications, in: B. Bhaskar, et al. Biomaterials in Tissue Engineering and Regenerative Medicine: From Basic Concepts to State of the Art Approaches, Springer Singapore, Singapore, 2021, 347-380.

DOI: 10.1007/978-981-16-0002-9_10

Google Scholar

[4] X. Pang, X. Zhuang, Z. Tang, X. Chen, Polylactic acid (PLA): research, development and industrialization, Biotechnol J, 5 (2010) 1125-36.

DOI: 10.1002/biot.201000135

Google Scholar

[5] R.M. Rasal, D.E. Hirt, Toughness decrease of PLA-PHBHHx blend films upon surface-confined photopolymerization, J Biomed Mater Res A, 88 (2009) 1079-86.

DOI: 10.1002/jbm.a.32009

Google Scholar

[6] E. Adase, P. Ankutse, D. Kumadoh, M.A. Archer, M.O. Kyene, G.N. Yeboah, D.O. Asamoah Agyare, "A Review of Parquetina nigrescens (Afzel.) Bullock, A Plant for Traditional Medicine: Phytochemical and Pharmacological Properties", Evid Based Complement Alternat Med, 2022 (2022) 6076707.

DOI: 10.1155/2022/6076707

Google Scholar

[7] A.T. Kola-Mustapha, Y.O. Ghazali, H.T. Ayotunde, S.A. Atunwa, S.O. Usman, Evaluation of the antidiarrheal activity of the leaf extract of Parquetina nigrescens and formulation into oral suspensions, J Exp Pharmacol, 11 (2019) 65-72.

DOI: 10.2147/jep.s214417

Google Scholar

[8] S.O. Adoga, D.E. Ekle, B.A. Kyenge, T.O.-O. Aondo, C.O. Ikese, Phytochemical screening, thin-layer chromatography and antimicrobial activity study of leaf extracts, Ovidius University Annals of Chemistry, 30 (2019) 88-94.

DOI: 10.2478/auoc-2019-0016

Google Scholar

[9] M.S. Zafar, Prosthodontic Applications of Polymethyl Methacrylate (PMMA): An Update, Polymers (Basel), 12 (2020)

DOI: 10.3390/polym12102299

Google Scholar

[10] Y. Wang, M.A. Hillmyer, Polyethylene-poly(L-lactide) diblock copolymers: synthesis and compatibilization of poly(L-lactide)/polyethylene blends, Journal of Polymer Science Part A, 39 (2001) 2755-2766.

DOI: 10.1002/pola.1254

Google Scholar

[11] P. Saini, M. Arora, M.N.V.R. Kumar, Poly(lactic acid) blends in biomedical applications, Advanced Drug Delivery Reviews, 107 (2016) 47-59.

DOI: 10.1016/j.addr.2016.06.014

Google Scholar

[12] K.S. Sanjay, A. Prashant, C. Abhishek, High Molecular Weight Poly(Lactic Acid) Synthesized With Apposite Catalytic Combination and Longer Time, Oriental Journal of Chemistry, 34 (2018) 1984-1990.

DOI: 10.13005/ojc/3404036

Google Scholar

[13] F.J. Akinrinmade, A.S. Akinrinde, O.O. Soyemi, A.A. Oyagbemi, Antioxidant Potential of the Methanol Extract of Parquetina nigrescens Mediates Protection Against Intestinal Ischemia-Reperfusion Injury in Rats, J Diet Suppl, 13 (2016) 420-32.

DOI: 10.3109/19390211.2015.1103828

Google Scholar

[14] J.Y. Datté, A. Ziegler, Pharmacological investigation on nigrescigenin-a cardenolide from Parquetina nigrescens (Afzel.) Bullock: comparative studies on cardiotonic effects of Parquetina nigrescens, g-strophanthin and noradrenaline in guinea-pig isolated atria, Journal of Pharmacy and Pharmacology, 53 (2001) 859-866.

DOI: 10.1211/0022357011776018

Google Scholar

[15] A.O. Ayoola, O. Akinloye, O.O. Oguntibeju, J.M. Oke, A.A. Odetola, Antioxidant activities of Parquetina nigrescens, 10 (2011) 4921-4925.

Google Scholar

[16] Z. Raszewski, A. Nowakowska-Toporowska, J. Weżgowiec, D. Nowakowska, W. Więckiewicz, Influence of silanized silica and silanized feldspar addition on the mechanical behavior of polymethyl methacrylate resin denture teeth, J Prosthet Dent, 123 (2020) 647.e1-647.e7.

DOI: 10.1016/j.prosdent.2019.12.007

Google Scholar

[17] M. Vojdani, R. Giti, Polyamide as a Denture Base Material: A Literature Review, J Dent (Shiraz), 16 (2015) 1-9.

Google Scholar

[18] S.A. Bello, Hybrid Polymeric Nanocomposites from Agricultural Waste,1st, Published by Taylor & Francis, Boca Raton, Florida, United States, 2022.

Google Scholar

[19] H.S. Barbara, Infrared Spectroscopy: Fundamentals and Applications, John Wiley &Son, University of Technology, Sydney, Australia, 2004.

Google Scholar

[20] S.A. Bello, J.O. Agunsoye, S.B. Hassan, Synthesis of Coconut Shell Nanoparticles Via A Top Down Approach: Assessment of Milling Duration on The Particle Sizes and Morphologies of Coconut Shell Nanoparticles, Materials Letters, 159 (2015) 514-519.

DOI: 10.1016/j.matlet.2015.07.063

Google Scholar

[21] ASTM D638-14 Standard Test Method for Tensile Properties of Plastics, ASTM International, West Conshohocken, PA,, 2014.

Google Scholar

[22] S.A. Bello, M.Y. Kolawole,Recycled Plastics and Nanoparticles for Green Production of Nano Structural Materials, in: O.V. Kharissova, L.M.T. MartínezB.I. Kharisov Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications, Springer International Publishing, Cham, 2021, 599-630.

DOI: 10.1007/978-3-030-36268-3_93

Google Scholar

[23] S.A. Bello, F.O. Kolawole, S.I. Durowaye, S.W. Balogun, M.Y. Kolawole, S.A. Mohammed,Recent Developments in Techniques and Technologies for Analytical, Spectroscopic, Structural, and Morphological Characterisation of Modern Materials of Advanced Applications, in: N. KulkarniB.I. Kharissov Handbook of Emerging Materials for Sustainable Energy, Elsevier Amsterdam, 2024, 675-724.

DOI: 10.1016/b978-0-323-96125-7.00037-x

Google Scholar

[24] S.A. Bello, N.K. Raji, M.Y. Kolawole, M.K. Adebayo, J.A. Adebisi, K.A. Okunola, M.O. AbdulSalaam, Eggshell nanoparticle reinforced recycled low-density polyethylene: A new material for automobile application, Journal of King Saud University - Engineering Sciences, 35 (2023) 406-414.

DOI: 10.1016/j.jksues.2021.04.008

Google Scholar

[25] ASTM D256-10(2018), Standard Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics, ASTM International, West Conshohocken, PA, 2018.

Google Scholar

[26] A.B.D. Nandiyanto, R. Oktiani, R. Ragadhita, How to Read and Interpret FTIR Spectroscope of Organic Material, Indonesian Journal of Science & Technology, 4 (2019) 97-118.

DOI: 10.17509/ijost.v4i1.15806

Google Scholar

[27] G.H. Jeffery, J. Basset, J. Mendham, R.C. Denney, VOGEL's Textbook of Quantitative Chemical Analysis,5, Longman Scientific and Technical, New York, 1989.

Google Scholar

[28] S.A. Bello, Wear and thermal resistance properties of aluminium particulate microcomposites, Bulletin of Materials Science, 43 (2020) 1-15.

DOI: 10.1007/s12034-020-02206-3

Google Scholar

[29] S.A. Bello, J.O. Agunsoye, J.A. Adebisi, N.K. Raji, R.G. Adeyemo, A.G.F. Alabi, S.B. Hassan, Flexural Performances of Epoxy Aluminium Particulate Composites, Engineering Journal, Chulalongkorn University, 22 (2018) 97-107.

DOI: 10.4186/ej.2018.22.4.97

Google Scholar

[30] S.A. Bello, J.O. Agunsoye, J.A. Adebisi, S.B. Hassan, Optimisation of charge ratios for ball milling synthesis: agglomeration and refinement of coconut shells, Engineering and Applied Science Research (EASR), 42 (2018) 262-272.

Google Scholar

[31] S.A. Bello, S.B. Hassan, J.O. Agunsoye, M.G.Z. Kana, R.I. A, Synthesis of Uncarbonised Coconut Shell Nanoparticles: Characterisation and Particle Size Determination Tribology in Industry, 37 (2015) 257-263.

Google Scholar

[32] P. Bazan, P. Nosal, B. Kozub, S. Kuciel, Biobased Polyethylene Hybrid Composites with Natural Fiber: Mechanical, Thermal Properties, and Micromechanics, Materials (Basel), 13 (2020)

DOI: 10.3390/ma13132967

Google Scholar

[33] I.O. Oladele, O.G. Agbabiaka, A.A. Adediran, A.D. Akinwekomi, A.O. Balogun, Structural performance of poultry eggshell derived hydroxyapatite based high density polyethylene bio-composites, Heliyon, 5 (2019) e02552.

DOI: 10.1016/j.heliyon.2019.e02552

Google Scholar

[34] S.A. Bello, M.K. Adebayo, R.G. Adeyemo, P.A. Popoola, Sustainable hybrid nanoparticle reinforced low-density polyethylene: emerging materials for engineering applications, Iranian Polymer Journal, 33 (2024) 965-980.

DOI: 10.1007/s13726-024-01307-8

Google Scholar

[35] J.O. Agunsoye, S.A. Bello, L.O. Adetola, Experimental investigation and theoretical prediction of tensile properties of Delonix regia seed particle reinforced polymeric composites, Journal of King Saud University - Engineering Sciences, 31 (2019) 70-77.

DOI: 10.1016/j.jksues.2017.01.005

Google Scholar

[36] S.A. Bello, S.I. Durowaye, W.E. Aigbona, B.O. Bolasodun, K. Audu, S.O. Abdul Ganiyu,Parquetina nigrescens–Reinforced Polylactic Acid (PLA) Composites for Engineering Applications, in: S.A. Bello Hybrid Polymeric Nanocomposites from Agricultural Waste, CRC, Taylor and Francis, USA, 2022, 279-319.

DOI: 10.1201/9781003170549-15

Google Scholar

[37] X. Li, C. Guo, X. Liu, L. Liu, J. Bai, F. Xue, P. Lin, C. Chu, Impact behaviors of poly-lactic acid based biocomposite reinforced with unidirectional high-strength magnesium alloy wires, Progress in Natural Science: Materials International, 24 (2014) 472-478.

DOI: 10.1016/j.pnsc.2014.08.003

Google Scholar

[38] S.A. Bello, O.E. Egbanubi, A.G.F. Alabi, Emerging hybrid particle-reinforced high-density polyethylene nanocomposite for bone replacement, Polymer Bulletin, 81 (2024) 1743-1766.

DOI: 10.1007/s00289-023-04791-9

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.