Rheological Investigation of Cu Alloy Feedstock for Metal Injection Moulding Using Polyamide(PA) Based Binder

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The influence of polyamide-6 (PA6), polyamide-12 (PA12), and their compositions was analyzed to determine the rheological behavior of the feedstock with 43% solid loading. The feedstock with Cu/PA composite constituents were extruded into filaments. The sphericity of particles, particle distribution, and voids was identified using Scanning Electron Microscopy (SEM). The capillary rheometer method was utilized to examine how shear rate and temperature impact the results. The viscosity and shear rate of the material was assessed at different temperatures and shear rates using an L/D ratio of 20 mm and a diameter of 11 mm capillary rheometer. The test results indicated that the polyamide composition influenced the feedstock's rheological properties. The viscosity of the feedstock decreased with an increase in the polyamide composition. Feedstock Cu/PA6 with a composition of 14wt%-Cu has the higher rheological properties among the variation of other composition both for PA-6 and PA-12. Viscosity and Flow energy activation Cu/PA-12 higher than Cu/PA-6.

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57-64

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October 2025

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© 2025 Trans Tech Publications Ltd. All Rights Reserved

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[1] Horton MJ, Schmid SR. Library of Congress Cataloging-in-Publication Data Kalpakjian, Serope, 1928-Manufacturing engineering and technology / Serope Kalpakjian. n.d.

Google Scholar

[2] Hausnerova B, Mukund BN, Sanetrnik D. Rheological properties of gas and water atomized 17-4PH stainless steel MIM feedstocks: Effect of powder shape and size. Powder Technol 2017;312:152–8.

DOI: 10.1016/j.powtec.2017.02.023

Google Scholar

[3] Amin SYM, Muhamad N, Jamaludin KR. Rheological properties analysis of WC-Co injection feedstock. Materials Science Forum, vol. 773–774, Trans Tech Publications Ltd; 2014, p.880–6.

DOI: 10.4028/www.scientific.net/MSF.773-774.880

Google Scholar

[4] R. K. Gupta, "Polymer and Composite Rheology, Second Edition, Plastics Engineering," (2000)

Google Scholar

[5] Marie-Aude Porter, Effects of Binder Systems for Metal Injection Moulding, master's thesis, Luleå University of Technology, (2003)

Google Scholar

[6] Soo Park M, Kon Kim J, Ahn S, Jin Sung H. Water-soluble binder of cellulose acetate butyrate/poly(ethylene glycol) blend for powder injection molding. n.d.

DOI: 10.1023/a:1012579010171

Google Scholar

[7] Askari A, Momeni V. Rheological investigation and injection optimization of Fe–2Ni–2Cu feedstock for metal injection molding process. Mater Chem Phys 2021;271.

DOI: 10.1016/j.matchemphys.2021.124926

Google Scholar

[8] Mindivan AF. EFFECT OF CRYSTALLINE FORM (γ) OF POLYAMIDE 6 / GRAPHENE NANOPLATELETS (PA6/GN) NANOCOMPOSITES ON ITS STRUCTURAL AND THERMAL PROPERTIES. n.d.

Google Scholar

[9] Martynková GS, Slíva A, Kratošová G, Barabaszová KČ, Študentová S, Klusák J, et al. Polyamide 12 materials study of morpho-structural changes during laser sintering of 3d printing. Polymers (Basel) 2021;13.

DOI: 10.3390/polym13050810

Google Scholar

[10] Maron SH, Sisko AW. APPLICATION OF REE-EYRING GENERALIZED FLOW THEORY TO SUSPENSIONS OF SPHERICAL PARTICLES. H. FLOW IN LOW SHEAR REGION. vol. 12. 1957.

DOI: 10.1016/0095-8522(57)90031-4

Google Scholar

[11] Liu ZY, Loh NH, Tor SB, Khor KA. Characterization of powder injection molding feedstock. Mater Charact 2003;49:313–20.

DOI: 10.1016/S1044-5803(02)00282-6

Google Scholar

[12] Foong ML, Tam KC. Application of Polymer Technology to Metal Injection Molding (MIM) Processing. n.d.

DOI: 10.1016/b978-081551426-8.50012-x

Google Scholar

[13] bin Suleiman @ Ahmad MJ, binti Abdulah N, bin Omar MA, binti Mohd Zainon N, bin Mahaidin AA, bin Nurul Hadi MA, et al. Rheological Study of a Copper Feedstock. Adv Mat Res 2016;1133:329–33.

DOI: 10.4028/www.scientific.net/amr.1133.329

Google Scholar

[14] Thavanayagam G, Pickering KL, Swan JE, Cao P. Analysis of rheological behaviour of titanium feedstocks formulated with a water-soluble binder system for powder injection moulding. Powder Technol 2015;269:227–32.

DOI: 10.1016/j.powtec.2014.09.020

Google Scholar

[15] Li G, Xia H, Lei Y, Yang W Bin, Liu T, He JP. Highly conductive polymer composites with excellent toughness, fluidity and temperature-independent conductivity. J Appl Polym Sci 2020;137.

DOI: 10.1002/app.48820

Google Scholar

[16] Ferrández-Montero A, Lieblich M, Benavente R, González-Carrasco JL, Ferrari B. Study of the matrix-filler interface in PLA/Mg composites manufactured by Material Extrusion using a colloidal feedstock. Addit Manuf 2020;33.

DOI: 10.1016/j.addma.2020.101142

Google Scholar

[17] Thalib S, Huzni S, Fonna S, Azhari CH, Zakaria S. The effect of particle compositions on the activation energy of the pa6/bagasse composite. IOP Conf Ser Mater Sci Eng, vol. 602, Institute of Physics Publishing; 2019.

DOI: 10.1088/1757-899X/602/1/012086

Google Scholar

[18] Liu D, Chen R, Zhan K, Chen Z, Luo X. Study on wall-slipping mechanism of nano-injection polymer under the constant temperature fields. E-Polymers 2023; 23. https://doi.org/10.1515/ epoly-2023-0085.

DOI: 10.1515/epoly-2023-0085

Google Scholar

[19] Chawla KK. Composite materials: Science and engineering, third edition. Springer New York; 2012.

DOI: 10.1007/978-0-387-74365-3

Google Scholar

[20] Thavanayagam G, Pickering KL, Swan JE, Cao P. Analysis of rheological behaviour of titanium feedstocks formulated with a water-soluble binder system for powder injection moulding. Powder Technol 2015;269:227–32.

DOI: 10.1016/j.powtec.2014.09.020

Google Scholar

[21] Goyal RK, Kambale KR, Nene SS, Selukar BS, Arbuj S, Mulik UP. Fabrication, thermal and electrical properties of polyphenylene sulphide/copper composites. Mater Chem Phys 2011;128:114–20.

DOI: 10.1016/j.matchemphys.2011.02.065

Google Scholar