Synthesis of Nano-Sized SrTiO3 Photocatalyst by Sol-Gel Method

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Abstract:

A sol-gel processing technology was employed to synthesize fine SrTiO3 powder by using strontium nitrate (Sr(NO3)2) , butyl titanate (Ti(OC4H9)4) as precursors, citric acid (C6H8O6) as complexing agent and (ethylene) glycol (C2H6O2) as stabilizer. Prepared the precursors in liquid phase and then calcined the precursors to achieve nano-sized SrTiO3 powders. The microstructure and composition of the as-synthesized samples were characterized by X-ray diffraction (XRD), Scan Electron Microscopy (SEM), and the photocatalytic activity was studied. The results showed that all the SrTiO3 particles were identified as perovskite phase. The pH values, the content of the acetic acid, the heat treat temperature play important roles on the synthesis of the SrTiO3 photocatalyst. When the pH=1, n(Sr(NO3)2 ) : n(Ti(OC4H9)4) = 1 : 1, n(Sr(NO3)2 ) : n(C6H8O6)=1:1.7, the product has better rate of photodegradation for the Methylene Blue under the ultraviolet condition.

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Key Engineering Materials (Volumes 512-515)

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1673-1676

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y.B. Mao, S. Banerjee, S.S. Wong, Large-scale synthesis of single-crystal line perovskite nanostructures, J. Am. Chem. Soc. 125(2003)15718-15719.

DOI: 10.1021/ja038192w

Google Scholar

[2] K. Anna, F.G. Marcos, C. Gerardo. Advanced Nanoarchitectures for Solar Photocatalytic Applications, Chem. Rev. online publication.

Google Scholar

[3] H.Y. Xu, S.Q. Wei, H. Wang,et al. Preparation of shape controlled SrTiO3 crystallites by sol-gel-hydrothermal method, J. Cryst. Growth. 292(2006)159-164.

DOI: 10.1016/j.jcrysgro.2006.04.089

Google Scholar

[4] M. Xu, Y.N. Lu, Y.F. Liu, et al. Synthesis of monosized strontium titanate particles with tailored morphologies, J. Am. Ceram. Soc. 89(2006)3631-3634.

DOI: 10.1111/j.1551-2916.2006.01283.x

Google Scholar

[5] N. Wang, D.T. Kong, H.C. He, Solvothermal synthesis of strontium titanate nanocrystallines from metatitanic acid and photocatalytic activities, Powder Technology. 207 (2011) 470–473.

DOI: 10.1016/j.powtec.2010.11.034

Google Scholar

[6] K. Domen, S. Naito, T. Onishi, et al. Study of the Photocatalytic Decomposition of Water Vapor over a Nickel(II) Oxide-strontium Titanate (SrTiO3) Catalyst, J. Phys. Chem, 86(1982) 3657-3661 .

DOI: 10.1021/j100215a032

Google Scholar

[7] H.T. Zhang, X.B. Wu, Y.M. Wang, et al. Preparation of Fe2O3/SrTiO3 composite powders and their photocatalytic properties, J. Phys. Chem. Solids. 68(2007)280-283.

Google Scholar

[8] L. Chen, S.C. Zhang, L.Q. Wang, Preparation and photocatalytic properties of strontium titanate powders via sol-gel process, J. Cryst. Growth. 311(2009)746-748.

DOI: 10.1016/j.jcrysgro.2008.09.185

Google Scholar