Photocatalytic Enhancement in Methylene Blue Degradation of TiO2 Photocatalysts via Graphene Hybridization

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A facile route was demonstrated to obtain an efficient graphene-hybridized TiO2 photocatalyst. The photodegradation results of Methylene Blue over graphene hybridized with TiO2 showed that the photocatalytic activity could be significantly enhanced under UV light irradiation. The structure between TiO2 and graphene as well as its effect on the photocatalytic activity were systematically investigated. The mechanism of the enhanced photocatalytic activity is based to the high migration efficiency and the inhibition of recombination of photoinduced electron-hole pairs. The graphene hydridization is proven to be a promising approach to develop highly efficient and stable photocatalysts under UV light irradiation.

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Key Engineering Materials (Volumes 512-515)

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1677-1681

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode, Nature. 238 (1972) 37-38.

DOI: 10.1038/238037a0

Google Scholar

[2] G.M. Liu, X.Z. Li, J.C. Zhao, Photooxidation pathway of sulforhodamine-B dependence on the adsorption mode on TiO2 exposed to visible light radiation, Environ. Sci. Technol. 34 (2000) 3982-3990.

DOI: 10.1021/es001064c

Google Scholar

[3] R. Asahi, T. Morikawa, T. Ohwaki, et al. Visible-light photocatalysis in nitrogen-doped titanium oxides. Science. 293 (2001) 269-271.

DOI: 10.1126/science.1061051

Google Scholar

[4] F. Zhou , K.M. Liang, G.L. Wang, et al., Crystallization Behavior of Li+-doped SiO2-TiO2 Films Prepared by Sol-gel Dip Coating, J. Cryst. Growth. 264 (2004) 297-301.

DOI: 10.1016/j.jcrysgro.2003.12.060

Google Scholar

[5] J.Y. Zhang, H.L. Zhu, Zheng SK, et al. TiO2 Film/Cu2O Microgrid Heterojunction with Photocatalytic Activity under Solar Light Irradiation. Appl. Mater. Int. 1 (2009) 2111-2114.

DOI: 10.1021/am900463g

Google Scholar

[6] N. Tatsuda, H. Itahara, N. Setoyama, et al. Preparation of titanium dioxide/activated carbon composites using supercritical carbon dioxide. Carbon. 43 (2005) 2358-2365.

DOI: 10.1016/j.carbon.2005.04.016

Google Scholar

[7] X.Y. Zhang, H.P. Li, X.L. Cui, Preparation and Photocatalytic Activity for Hydrogen Evolution of TiO2/Graphene Sheets Composite. Chin. J. Inor. Chem. 25 (2009) 1903-1907.

Google Scholar

[8] A.K. Geim, K.S. Novoselov, The rise of graphene. Nature Mater. 6 (2007) 183-191.

Google Scholar

[9] F. Zhou, R. Shi, Y.F. Zhu, Significant enhancement of the visible photocatalytic degradation perfor- mances of γ-Bi2MoO6 nanoplate by graphene hybridization, J. Mole. Catal. A. 340 (2011) 77-82

DOI: 10.1016/j.molcata.2011.03.012

Google Scholar

[10] W.S. Hummers, R.E. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80 (1958) 1339-1339

DOI: 10.1021/ja01539a017

Google Scholar

[11] D. Wang, D. Choi, J. Li, et al. Self-Assembled TiO2-Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion. ACS Nano. 3 (2009) 907-914.

DOI: 10.1021/nn900150y

Google Scholar

[12] D. Li, M.B. Muller, S. Gilje, et al. Processable aqueous dispersions of graphene nanosheets, Nature Nanotechnology 3 (2008) 101-105.

DOI: 10.1038/nnano.2007.451

Google Scholar

[13] K.F. Zhou, Y.H. Zhu, X.L. Yang, et al, Preparation of graphene-TiO2 composites with enhanced photocatalytic activity, New J. Chem. 35 (2011) 353-359.

Google Scholar

[14] T.G. Xu, L.W. Zhang, H.Y. Cheng, et al, Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study, Appl. Catal. B: Environ. 101 (2011) 382-387.

DOI: 10.1016/j.apcatb.2010.10.007

Google Scholar