Synthesis, Structure and Properties of a Novel Metal-Organic Coordination Polymer, [Zn (NH₃)₂(BDC)]_n

Abstract:

A novel one-dimensional metal-organic coordination polymer, [Zn (NH₃)₂(BDC)]_n (BDC=1,4-benzenedicaboxylate), has been synthesized by solvent evaporation method through self-assembly of Zn (II) salts with terephthalic acid ligand in ammonia aqueous solution. Single crystal X-ray diffraction analysis indicated that each Zn (II) was coordinated by two nitrogen donors from two NH₃ and two oxygen counter donors from terephthalic acid ligand. The adjacent zigzag chains are arranged in a parallel fashion and linked by interchain hydrogen bonding interaction and π-π stacking interactions into higher-dimensional framework. The compound has also been characterized by CHN elemental analyses, Single crystal X-ray diffraction analysis, powder X-ray diffraction (PXRD) analysis, Fourier transform infrared (FT-IR) spectra, Thermalgravimetric-differential scanning calorimetric (TG-DSC) and Solid-state nuclear magnetic resonance (NMR), etc. Results showed that the framework of compound was stable at the temperature up to 246°C. The desolvated product [Zn (BDC)]_n, which was obtained by removal of molecular NH₃ from [Zn (NH₃)₂(BDC)]_n, can be transferred to the different skeleton structures through coordinating different small hydrogen-bond-forming molecules.

• Periodical: Key Engineering Materials (Volumes 575-576)
• Pages: 30-36
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.575-576.30
• Online since: September 2013
• Authors: Ning Ning Wu, Can Xiong Guo, Gui An Wu, Zhao Cai, Wan Hong He
• Keywords: Ammonia, Metal-Organic Coordination Polymer, Reversion, Terephthalic Acid, Volatilization

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