Characterisation of Polymer Electrolytes Based on High Molecular Weight PVC and BMIMCF3SO3

Nik Aisyah Suraya Nik Zulkepeli; Tan Winie; R.H.Y. Subban

doi:10.4028/www.scientific.net/KEM.705.150

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 705Characterisation of Polymer Electrolytes Based on...

Characterisation of Polymer Electrolytes Based on High Molecular Weight PVC and BMIMCF₃SO₃

Abstract:

Polymer electrolyte films of poly (vinyl) chloride (PVC) as polymer host doped with ionic liquid 1-butyl-3-methylimidazolium trifluoromethasulfonate (BMIMCF₃SO₃) were prepared by solution cast technique. Ionic conductivity was studied for 95 wt.% and 80 wt.% PVC by using Impedance Spectroscopy (IS). Arrhenius and Vogel-Tamman Fulcher (VTF) behavior were observed before and after T_g of the systems. Fourier Transform Infrared (FTIR) study confirmed that complexation occurred between PVC and BMIMCF₃SO₃.

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Periodical:

Key Engineering Materials (Volume 705)

Pages:

150-154

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.705.150

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Online since:

August 2016

Authors:

Nik Aisyah Suraya Nik Zulkepeli*, Tan Winie, R.H.Y. Subban

Keywords:

BMIMCF₃SO₃, FTIR, Polymer Electrolyte, PVC

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