Investigation of the Structural Properties of Amorphous Philippine Bentonite Clay and its Potential Use for Topical Applications

Article Preview

Abstract:

This study aims to characterize the Philippine natural bentonite from Mangatarem, Pangasinan for potential topical applications. Six samples were obtained from the mine site. Using the low angle region of their XRD patterns, initial mineralogical analysis of the samples was conducted. The presence of the 6.08° peak, which represents the presence of pure smectite material, was only observed in one sample, D2. The long range XRD pattern of the D2 bentonite sample confirmed montmorillonite as the main component. Other clay minerals such as hectorite and mordenite were also detected in small intensities. In the chemical analysis, Si and Al were the primary elemental components. However, the presence of high amount of Ca revealed that the sample is Ca-bentonite. Also present are other exchangeable cations such as Na+, K+, and Mg2+. To confirm their applicability for topical uses, the CEC, pH and presence of E. coli were determined. The CEC of the sample was 114.32 meq/100g, and the pH value was 7.1. Microbial test also confirmed the absence of E. coli. These tests all validate that the sample is safe and viable for topical applications.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

401-406

Citation:

Online since:

June 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A. Liaquat, M. Valenzuela, A. Ehsan, F. Díaz, N. Khattak, Characterization of Pakistani purified bentonite suitable for possible pharmaceutical application, Appl. Clay Sci. 83-84 (2013) 50-55.

DOI: 10.1016/j.clay.2013.08.007

Google Scholar

[2] N. Amin, Use of clay as a pozzolona in high strength Portland cement and its thermal activation, Chin. J. Geochem. 29(2) (2010) 143-145.

DOI: 10.1007/s11631-010-0143-5

Google Scholar

[3] S. Mukherjee, Uses of clays in waste managements: toxic and non-toxic, in The Science of Clays, Netherlands: Springer Netherlands, 2013, Part III, pp.309-325.

DOI: 10.1007/978-94-007-6683-9_21

Google Scholar

[4] S. Mukherjee, Use of Clays as Drilling Fluids and Filters, in The Science of Clays, Netherlands: Springer Netherlands, 2013, Part II, pp.178-183.

DOI: 10.1007/978-94-007-6683-9_11

Google Scholar

[5] L. Benetoli, H. Santana, C. Zaia, D. Zaia, Adsorption of nucleic acid bases on clays: an investigation using Langmuir and Freundlich isotherms and FT-IR spectroscopy, Monatsh. Chem. 139(7) (2008) 753-761.

DOI: 10.1007/s00706-008-0862-z

Google Scholar

[6] C. Iborra, G. Cultrone, P. Cerezo, C. Aguzzi, M. Baschini, J. Vallés, A. López-Galindo, Characterisation of northern Patagonian bentonites for pharmaceutical uses, Appl. Clay Sci. 31(3-4) (2006) 272-281.

DOI: 10.1016/j.clay.2005.11.002

Google Scholar

[7] I. Odom, Smectite clay: Mineral Properties and Uses, Phil. Trans. R. Soc. Lond. A 1984 311, 391-409.

Google Scholar

[8] G. Kahr, F. Madsen, Determination of the cation exchange capacity and the surface area of bentonite, illite and kaolinite by methylene blue adsorption, Appl. Clay Sci. 9(5) (1995) 327-336.

DOI: 10.1016/0169-1317(94)00028-o

Google Scholar

[9] S. Magana, P. Quintana, D. Aguilar, J. Toledo, C. Angeles-Chavez, M. Cortes, L. Leon, Y. Freile-Pelegrın, T. Lopez, R. Torres Sanchez, Antibacterial activity of montmorillonites modified with silver, J. Molecul. Catal. A: Chem. 281(1-2) (2008).

Google Scholar

[10] E. Alvarez-Ayuso, A. Garcia-Sanchez, Removal of Heavy Metals from Waste Waters by Natural and Na-exchanged Bentonites, Clays Clay Min. 51(5) (2003) 475-480.

DOI: 10.1346/ccmn.2003.0510501

Google Scholar

[11] A. López-Galindo, C. Viseras, P. Cerezo, Compositional, technical and safety specifications of clays to be used as pharmaceutical and cosmetic products, Appl. Clay Sci. 36(1-3) (2007) 51-63.

DOI: 10.1016/j.clay.2006.06.016

Google Scholar

[12] R. Garrison, E. Espiritu, L. Horan, L. Mack, Petrology, Sedimentology, and Diagenesis of Hemipelagic Limestone and Tuffaceous Turbidites in the Aksitero Formation, Central Luzon, Philippines, in Geological Survey Professional Paper 1112, Washington: United States Govermenment Printing Office, (1979).

DOI: 10.3133/pp1112

Google Scholar

[13] H. D. Chapman, 1965. Cation exchange capacity. In: Black, C.A., et al. (Ed. ), Methods of Soil Analysis. Part 2. American Society of Agronomy, Madison, pp.891-901.

DOI: 10.2134/agronmonogr9.2.c6

Google Scholar

[14] A. D. Hitchins, T. T. Tran, J. E. McCarron, 2001. Microbiological Methods for Cosmetics, In Chapter 23, Bacteriological Analytical Manual Online, US Food and Drug Administration.

Google Scholar

[15] A. Fisher, M. Underwood, Calibration of an X-ray Diffraction Method to Determine Relative Mineral Abundances in Bulk Powders using Matrix Singular Value Decomposition: A Test from the Barbados Accretionary Complex, Proceedings of the Ocean Drilling Program, Initial Reports, 156 (1995).

DOI: 10.2973/odp.proc.ir.156.103.1995

Google Scholar

[16] D. Eberl, User's Guide to Rockjock - A Program for Determining Quantitative Mineralogy From Powder X-ray Diffraction Data, U.S. Geological Survey Open-File Report 03-78, (2003).

DOI: 10.3133/ofr200378

Google Scholar

[17] S. Modabberi, A. Namayandeh, A. López-Galindo, C. Viseras, M. Setti, M. Ranjbaran, Characterization of Iranian bentonites to be used as pharmaceutical materials, Appl. Clay Sci. 116-117 (2015) 193-201.

DOI: 10.1016/j.clay.2015.03.013

Google Scholar

[18] M. Carretero, M. Pozo, Clay and non-clay minerals in the pharmaceutical industry, Appl. Clay Sci. 46(1) (2009) 73-80.

DOI: 10.1016/j.clay.2009.07.017

Google Scholar

[19] US Pharmacopeia <61>, Microbiological Examination of Nonsterile Products: Microbial Enumeration Tests, US Pharmacopoeial Convention, Rockville, MD, p.2503.

DOI: 10.31003/uspnf_m98800_01_01

Google Scholar