Ionic Seebeck Effect in Alkali Niobophosphate Glasses

Article Preview

Abstract:

Ionic Seebeck effect has been investigated in Li (Na,K)2O‐Nb2O5‐P2O5 glasses. Ionic Seebeck coefficients and heats of ion transfer have been measured. Soret coefficients have been calculated for glasses being studied. Temperature dependence and content of Nb2O5 dependence of Soret coefficients have been analyzed. Hypotheses of coefficients of self-diffusion and thermodiffusion ratio when temperature and content of Nb2O5 change have been proposed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

818-823

Citation:

Online since:

September 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] M. Dubov, V. Mezentsev, A.A. Manshina, I.A. Sokolov, A. V. Povolotskiy, Y. V. Petrov, Waveguide fabrication in lithium-niobo-phosphate glasses by high repetition rate femtosecond laser: route to non-equilibrium material's states, Opt. Mater. Express. 4 (2014) 1197.

DOI: 10.1364/ome.4.001197

Google Scholar

[2] S. Eaton, H. Zhang, P. Herman, F. Yoshino, L. Shah, J. Bovatsek, A. Arai, Heat accumulation effects in femtosecond laser-written waveguides with variable repetition rate., Opt. Express. 13 (2005) 4708–4716.

DOI: 10.1364/opex.13.004708

Google Scholar

[3] K. Miura, M. Shimizu, M. Sakakura, T. Kurita, Y. Shimotsuma, K. Hirao, Formation Mechanism and Applications of Laser Induced Elemental Distribution in Glasses, in: Prog. Electromagn. Res. Symp., 2012: p.18–23.

Google Scholar

[4] S. Chenu, U. Werner-Zwanziger, C. Calahoo, J.W. Zwanziger, Structure and properties of NaPO3-ZnO-Nb2O5-Al2O3glasses, J. Non. Cryst. Solids. 358 (2012) 1795–1805.

DOI: 10.1016/j.jnoncrysol.2012.05.027

Google Scholar

[5] H. Maeda, S. Lee, T. Miyajima, A. Obata, K. Ueda, T. Narushima, T. Kasuga, Structure and physicochemical properties of CaO–P2O5–Nb2O5–Na2O glasses, J. Non. Cryst. Solids. 432 (2016) 60–64.

DOI: 10.1016/j.jnoncrysol.2015.06.003

Google Scholar

[6] M.K. Balapanov, I.B. Zinnurov, G.R. Akmanova, The ionic Seebeck effect and heat of cation transfer in Cu 2-δSe superionic conductors, Phys. Solid State. 48 (2006) 1868–1871.

DOI: 10.1134/s1063783406100076

Google Scholar

[7] A.A. Man'shina, A. V. Povolotskiĭ, I.A. Sokolov, M. V. Kurushkin, The formation of optical phase structures in the volume of phosphate glasses by means of thermal diffusion caused by the action of femtosecond laser radiation, J. Opt. Technol. 82 (2015) 120.

DOI: 10.1364/jot.82.000120

Google Scholar

[8] J. Hoyo, B. Sotillo, M. Hernandez, T. Toney Fernandez, P. Haro-González, D. Jaque, P. Fernandez, C. Domingo, J. Siegel, J. Solis, Strong ion migration in high refractive index contrast waveguides formed by femtosecond laser pulses in phosphate glass, in: J.I. Mackenzie, H. JelÍnková, T. Taira, M. Abdou Ahmed (Eds.), Proc. SPIE - Int. Soc. Opt. Eng., 2014: p. 91351G.

DOI: 10.1117/12.2052441

Google Scholar

[9] T. Toney Fernandez, P. Haro-González, B. Sotillo, M. Hernandez, D. Jaque, P. Fernandez, C. Domingo, J. Siegel, J. Solis, Ion migration assisted inscription of high refractive index contrast waveguides by femtosecond laser pulses in phosphate glass, Opt. Lett. 38 (2013) 5248.

DOI: 10.1364/ol.38.005248

Google Scholar

[10] A. Lipovskii, V. Zhurikhina, D. Tagantsev, 2D-structuring of glasses via thermal poling: A short review, Int. J. Appl. Glas. Sci. (2017).

DOI: 10.1111/ijag.12273

Google Scholar

[11] A.V. Redkov, V.G. Melehin, D.V. Raskhodchikov, I.V. Reshetov, D.K. Tagantsev, V.V. Zhurikhina, A.A. Lipovskii, Modifications of poled silicate glasses under heat treatment, J. Non. Cryst. Solids. 503–504 (2019) 279–283.

DOI: 10.1016/j.jnoncrysol.2018.10.011

Google Scholar

[12] A.A. Lipovskii, A.I. Morozova, D.K. Tagantsev, Giant Discharge Current in Thermally Poled Silicate Glasses, J. Phys. Chem. C. 120 (2016) 23129–23135.

DOI: 10.1021/acs.jpcc.6b07144

Google Scholar

[13] A.A. Lipovskii, V.V. Rusan, D.K. Tagantsev, Imprinting phase/amplitude patterns in glasses with thermal poling, Solid State Ionics. 181 (2010) 849–855.

DOI: 10.1016/j.ssi.2010.05.001

Google Scholar

[14] A.A. Lipovskii, A.V. Redkov, A.A. Rtischeva, D. Tagantsev, V.V. Zhurikhina, Kinetics of ion-exchange-induced vitrification of glass-ceramics, J. Am. Ceram. Soc. (2018).

DOI: 10.1111/jace.16253

Google Scholar

[15] E. Stavrou, D. Palles, E.I. Kamitsos, A. Lipovskii, D. Tagantsev, Y. Svirko, S. Honkanen, Vibrational study of thermally ion-exchanged sodium aluminoborosilicate glasses, J. Non. Cryst. Solids. 401 (2014) 232–236.

DOI: 10.1016/j.jnoncrysol.2013.12.017

Google Scholar

[16] V.A. Klinkov, A. V Semencha, Spectral Properties of Doped Glasses of the 35Bi2O3 · 40PbO · 25Ga2O3 Composition Synthesized in a Quartz Crucible, Glas. Phys. Chem. 44 (2018) 234–237.

DOI: 10.1134/s1087659618030057

Google Scholar

[17] H. Reuther, J. Wiegmann, W. Hinz, Thermotransport in Silicatglasern, Glasstechn. 56 (1983) 19–25.

Google Scholar

[18] H. Reuther, W. Hinz, Thermotransport in lithium silicate glasses, Phys. Status Solidi. 59 (1980) K87–K89.

DOI: 10.1002/pssa.2210590173

Google Scholar

[19] C.J. Meechan, G.W. Lehman, Diffusion of Au and Cu in a Temperature Gradient, J. Appl. Phys. 33 (1962) 634–641.

DOI: 10.1063/1.1702479

Google Scholar

[20] Y. Liu, C.T. Liu, E.P. George, X.Z. Wang, Thermal diffusion and compositional inhomogeneity in cast Zr50Cu50 bulk metallic glass, Appl. Phys. Lett. 89 (2006).

DOI: 10.1063/1.2335380

Google Scholar

[21] Y. Liu, C.T. Liu, E.P. George, X.Z. Wang, The Soret effect in bulk metallic glasses, Intermetallics. 15 (2007) 557–563.

DOI: 10.1016/j.intermet.2006.09.007

Google Scholar

[22] A. HONDERS, J. DERKINDEREN, A. VANHEEREN, J. DEWIT, G. BROERS, The thermodynamic and thermoelectric properties of LixTiS2 and LixCoO2, Solid State Ionics. 14 (1984) 205–216.

DOI: 10.1016/0167-2738(84)90100-0

Google Scholar

[23] S.M. Girvin, Thermoelectric power of superionic conductors, J. Solid State Chem. 25 (1978) 65–76.

DOI: 10.1016/0022-4596(78)90044-0

Google Scholar

[24] J.F. Smith, D.T. Peterson, M.F. Smith, An interpretation of Q*in thermotransport, J. Less-Common Met. 106 (1985) 19–26.

DOI: 10.1016/0022-5088(85)90361-3

Google Scholar

[25] S.R. de Groot, Thermodynamics of irreversible processes, Print book, Amsterdam : North Holland Pub. Co., (1951).

Google Scholar

[26] V.A. Markov, I.A. Sokolov, M. V. Kurushkin, A. V. Povolotskiy, Electrodiffusion of alkali ions in alkali niobophosphate glasses and glass-forming melts, Int. J. Appl. Glas. Sci. 10 (2019) 69–74.

DOI: 10.1111/ijag.12435

Google Scholar