Fusible Glass Based on Glassy Chalcogenide Type Systems Ge-S(Se)Br, Ge-S(Se)I

Abstract:

Theoretical and practical results on the preparation and investigation of low-melting glasses using the example of glassy chalcogenide glasses of the Ge-S-Br, Ge-Se-Br systems are presented and summarized. On the basis of fundamental properties of matter, correlations were identified with uniform positions. The glass formation regularities in the indicated chalcogenide and oxyhalide systems were determined. Areas and compositions of low-melting chalcogenide and oxyhalide glasses were considered. Approaches to obtaining of thermostable and difficult to crystallize low-melting glasses were found. Areas of their practical application were identified. On the basis of the obtained data, approaches and criteria for obtaining compositions of low-melting chalcogenide and oxide glasses with practically useful properties are formulated.

• Periodical: Key Engineering Materials (Volume 822)
• Pages: 834-840
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.822.834
• Online since: September 2019
• Authors: Nikolai I. Krylov*, Mikhail D. Mikhailov, Lev N. Blinov, Elena V. Bochagina
• Keywords: Bromine, Chalcogenide Glassy Materials, Glasses, Iodine, IR Sensors, Low-Melting Glasses, Oxyhalide Glass Systems Containing Chlorine, Practical Applications, Production of Thermostable Glasses

References

[1] Zakery A, Elliott SR. Optical properties and applications of chalcogenide glasses: a review. Journal of Non-Crystalline Solids. 2003 Nov 15;330(1-3):1-2.

DOI: 10.1016/j.jnoncrysol.2003.08.064

[2] Blinov L.N. Modelling, synthesis and study of new glassy chalcogenide materials// Glass Physics and Chemistry. 2015.V.41, №1. P.531-533.

[3] Klinkov, V.A., Semencha, A.V. and Tsimerman, E.A., 2017. Advanced Materials for Fiber Communication Systems. In Internet of Things, Smart Spaces, and Next Generation Networks and Systems (pp.184-195). Springer, Cham.

DOI: 10.1007/978-3-319-67380-6_17

[4] Bormashenko E., Pogreb R., Sutovski S., Levin . Optical properties and infrared optics of composite films based on polyethylene and low-melting point chalcogenide glass// Opt. Eng. 2002. V. 41. P. 295-302.

DOI: 10.1117/1.1430424

[5] Gibson D.J. and Harrington J.A. Extrusion of hollow waveguideperforms with a one-dimensional photonic bandgap structure// J. Appl.Phys. 2004. V.95. №8. P.3895-3900.

DOI: 10.1063/1.1667277

[6] Kuriki K., Shapira O., Hart S.D., Benoit G., Kuriki Y., Viens J.F., Bayindir M., Joannopoulos J.D. and Fink Y. Hollow multilayer photonicbandapfibers for NIR applications// Opt. Express. 2004. V.12. №8. P.1510-1517.

DOI: 10.1364/opex.12.001510

[7] Isayev, A. I., Mekhtiyeva, S. I., Garibova, S. N., Alekperov, R. I., & Zeynalov, V. Z. (2011). Study of optical parameters of the Se-As chalcogenide semiconductor system containing EuF 3 impurities. Semiconductors, 45(8), 993.

DOI: 10.1134/s1063782611080100

[8] Isayev, A. I., Mekhtiyeva, S. I., & Alekberov, R. I. (2016). The influence of doping by samarium on the structure and surface morphology of the As33. 3Se33. 3S33. 4, As33. 3Se33. 3Te33. 4 chalcogenide glass semiconductor films. JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 18(1-2), 39-43.

[9] Dieke, G.H., Crosswhite, H.M. and Crosswhite, H., 1968. Spectra and energy levels of rare earth ions in crystals.

[10] Khanin, V.M., Rodnyi, P.A., Wieczorek, H. and Ronda, C.R., 2017. Electron traps in Gd 3 Ga 3 Al 2 O 12: Ce garnets doped with rare-earth ions. Technical Physics Letters, 43(5), pp.439-442.

DOI: 10.1134/s1063785017050042

[11] Klinkov, V.A. and Semencha, A.V., 2018. Spectral Properties of Doped Glasses of the 35Bi2O3· 40PbO· 25Ga2O3 Composition Synthesized in a Quartz Crucible. Glass Physics and Chemistry, 44(3), pp.234-237.

DOI: 10.1134/s1087659618030057

[12] Khistiaeva, V.V., Melnikov, A.S., Slavova, S.O., Sizov, V.V., Starova, G.L., Koshevoy, I.O. and Grachova, E.V., 2018. Heteroleptic β-diketonate Ln (iii) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties. Inorganic Chemistry Frontiers, 5(12), pp.3015-3027.

DOI: 10.1039/c8qi00712h

[13] Alekberov, R. I., Isayev, A. I., Mekhtiyeva, S. I., & Isayeva, G. A. (2014). Role of samarium atoms in the formation of the structure of As-Se-S chalcogenide vitreous semiconductors. Semiconductors, 48(6), 796-799.

DOI: 10.1134/s1063782614060025

[14] Kurushkin M.V., Semencha A.V., Blinov L.N., Milkailov M.D. Lead-containing oxyhalide glass// Glass physics and chemistry. 2014. V. 40. №4. P.421-427.

DOI: 10.1134/s1087659614040063

[15] Blinov L.N., Orkina T.N. Dielectric Materials Based on Chalcogenide Glassy Systems: Properties, Ways of Preparation, Possibilities of Application// Russian Journal of Applied Chemistry. 2000. V. 73. №9. P.1561-1571.

[16] Tanaka K. Layer structures in chalcogenide glasses// J.Non.cryst.Solids.1988.V.103.№1.P.149-150.

DOI: 10.1016/0022-3093(88)90428-0

[17] Krylov N.I., Blinov L.N. Halogen-Containing Chalcogenide Glasses: Synthesis and Properties// Glass Physics and Chemistry. 2017. V. 43. №4. P.326-329.

DOI: 10.1134/s1087659617040071