Paper Titles

Influence of Acid-Treatment on Waste Lignin for Synthesis of Carbon Nanoparticle
p.1

Promotion of Osteoblast Proliferation Activated by Betaglucan (BG) Derived from Yeast Sludge
p.8

Preparation and Properties of Polylactide Reinforced with Eggshell Modified with Different Fatty Acids
p.16

Transformation of Waste Marigold Flowers into Porous Carbons via Hydrothermal Carbonization
p.23

Production and Characterization of Bacterial Cellulose from Rice Washing Drainage (RWD) by Komagataeibacter nataicola Li1
p.30

Antifouling Property and Morphology of Polyethersulfone Membranes Blended with Bio-Based Amphiphilic Polymer Additives
p.38

Silver Recovery and Reduction of Chemical Oxygen Demand from Used Fixing Reagent of X-Ray Laboratory Using Electrolysis Coupled with Adsorption onto Crab-Shell Chitosan and Black Rice-Husk Ash
p.45

Effect on the Properties of Brake Pads of Recycling Dust as Filler
p.52

HomeKey Engineering MaterialsKey Engineering Materials Vol. 824Influence of Acid-Treatment on Waste Lignin for...

Influence of Acid-Treatment on Waste Lignin for Synthesis of Carbon Nanoparticle

Article Preview

Abstract:

Waste lignin (WL) obtained from paper mills, was studied for its potential application in preparing carbon nanoparticles (CNPs) with high porosity. This was done by impregnation of 0, 5, 10 and 20% concentrations of phosphoric acid under various carbonization temperatures (600, 700, 800 and 900°C). The physicochemical properties of CNPs were characterized through nitrogen sorption, X-ray diffraction (XRD), Scanning electron microscopy (SEM), and Fourier transforms infrared spectroscopy (FTIR). Nitrogen sorption revealed that the condition using 10% concentration of phosphoric acid treatment at a carbonization temperature of 700°C formed carbon nanoparticles with a highly porous structure (Surface area 27.65 m²/g and pore volume 0.07 cm³/g). Additionally, in order to high surface area, porosity and concentrated carbon nanoparticle.

You might also be interested in these eBooks

Green Convergence on Materials Frontiers II

Info:

Periodical:

Key Engineering Materials (Volume 824)

Pages:

1-7

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.824.1

Citation:

Cite this paper

Online since:

October 2019

Authors:

Nutchaporn Ngamthanacom, Napat Kaewtrakulchai, Weerawut Chaiwat, Laemthong Chuenchom, Masayoshi Fuji, Apiluck Eiad-Ua*

Keywords:

Acid Treatment, Carbon Nanoparticle, Carbonization, Waste Lignin

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Venkata Mohan, J. Karthikeyan, Removal of lignin and tannin colour from aqueous solution by adsorption onto activated charcoal. Environ. Pollut. 97 (1997) 183 - 187.

DOI: 10.1016/s0269-7491(97)00025-0

[2] Z. Qinglin, C. Karl T., Adsorption of organic pollutants from effluents of a Kraft pulp mill on activated carbon and polymer resin. Adv. Environ. Res. 3 (2001) 251 - 258.

DOI: 10.1016/s1093-0191(00)00059-9

[3] M. Dinesh, P. Charles U. Jr., and S. Philip H., Single, binary and multicomponent adsorption of copper and cadmium from aqueous solutions on Kraft lignin—A biosorbent. J. Colloid Interf. Sci. 297(2) (2006) 489 - 504.

DOI: 10.1016/j.jcis.2005.11.023

[4] J. Lora, Industrial commercial lignins: Sources, properties and applications. in Monomers, Polymers and Composites from Renewable Resources, edited by Belgacem, M., and Gandini, A. (eds.), Elsevier, Oxford, UK (2008) 225 – 241.

DOI: 10.1016/b978-0-08-045316-3.00010-7

[5] R. Aravamuthan, W.Y. Chen, K. Zargarian, and G. C. April, Ethanol from southern hardwoods: the role of presulphonation in the acid hydrolysis process. Biotechnology and Bioengineering Symposium, John Wiley & Sons (1986) 115 – 127.

DOI: 10.1080/00986448808940608

[6] R.J.A. Gosselink, E. de Jong, B. Guran, and A. Abächerli, Coordination network for lignin-standardisation. production and applications adapted to market requirements (EUROLIGNIN). Ind. Crops Prod. 20 (2004) 121 - 129.

DOI: 10.1016/j.indcrop.2004.04.015

[7] A.L. Macfarlane, R. Prestidge, M.M. Farid, and J.J.J. Chen, Dissolved air flotation: A novel approach to recovery of organosolv lignin. Chemical Engineering Journal 148(1) (2009) 15 - 19.

DOI: 10.1016/j.cej.2008.07.036

[8] B. Krzysztof, J. Krzysztof, KOH activated lignin-based nanostructured carbon exhibiting high hydrogen electrosorption. Carbon 46 (2008) 1948 - (1956).

DOI: 10.1016/j.carbon.2008.08.005

[9] B. Krzysztof, J. Dawid, J. Krzysztof, Electrochemical hydrogen storage in activated carbons with different pore structures derived from certain lignocellulose materials. Carbon 50 (2012) 5017 - 5026.

DOI: 10.1016/j.carbon.2012.06.030

[10] T. Nagy L., H. Ming, I. Shinsuke, S. Hiroaki, B. Alexis A., I. Masataka, A. Katsuhiko, S. Yoshio, and Y. Yusuke, Direct synthesis of MOF-derived nanoporous carbon with magnetic Co nanoparticles toward efficient water treatment. Small 10 (2014) 2096 - 2107.

DOI: 10.1002/smll.201302910

[11] C. Binling, M. Guiping, K. Dali, Z. Yanqiu, and X. Yongde, Atomically homogeneous dispersed ZnO/N-doped nanoporous carbon composites with enhanced CO2 uptake capacities and high efficient organic pollutants removal from water. Carbon 95 (2015) 113 - 124.

DOI: 10.1016/j.carbon.2015.08.015

[12] P. Maryam, Q. Ali, R. Ramakrishnan, and F. Henry C., On the effects of confinement within a catalyst consisting of platinum embedded within nanoporous carbon for the hydrogenation of alkenes. Carbon 66 (2014) 459 - 466.

DOI: 10.1016/j.carbon.2013.09.022

[13] V. Aleksey N., G. Leonid V., P. Vladimir A., Z. Eugene, C. Jengshiou, and K. Johannes G., Functionalized nanoporous carbon as a catalyst for Suzuki coupling reactions. Microporous and Mesoporous Mater. 101 (2007) 342 - 347.

DOI: 10.1016/j.micromeso.2006.11.026

[14] L. Jung Joon, H. Sangjin, K. Heeyeon, K. Jae Hyun, H. Taeghwan, M. Sang Heup, Performance of CoMoS catalysts supported on nanoporous carbon in the hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene. Catalysis Today 86 (2003) 141 - 149.

DOI: 10.1016/s0920-5861(03)00408-5

[15] Y. Zhuxian, X. Yongde, and M. Robert, Enhanced hydrogen storage capacity of high surface area zeolite-like carbon materials. J. Am. Chem. Soc. 129 (2007) 1673 - 1679.

DOI: 10.1021/ja067149g

[16] H. Sangjin, K. Sukjae, L. Hacgyu, C. Wonyong, P. Hyunwoong, Y. Jeyong, and H. Taeghwan, New nanoporous carbon materials with high adsorption capacity and rapid adsorption kinetics for removing humic acids. Microporous Mesoporous Mater. 58 (2003) 131 - 135.

DOI: 10.1016/s1387-1811(02)00611-x

[17] J.P. Ruparelia, S.P. Duttagupta, A.K. Chatterjee, and S. Mukherji, Potential of carbon nanomaterials for removal of heavy metals from water. Desalination 232 (2008) 145 - 156.

DOI: 10.1016/j.desal.2007.08.023

[18] L. Krisztina, T. Etelka, and K. Péter, Surface chemistry of nanoporous carbon and the effect of pH on adsorption from aqueous phenol and 2,3,4-trichlorophenol solutions. Colloids Surfaces a Physicochem. Eng. Aspects 230 (2003) 13 - 22.

DOI: 10.1016/j.colsurfa.2003.09.009

[19] B. Xiao, K. M. Thomas, Competitive adsorption of aqueous metal ions on an oxidized nanoporous activated carbon. Langmuir 20 (2004) 4566 - 4578.

DOI: 10.1021/la049712j

[20] A. Yazdankhah, S.E. Moradi, S. Amirmahmoodi, M. Abbasian, and S. Esmaeily Shoja, Enhanced sorption of cadmium ion on highly ordered nanoporous carbon by using different surfactant modification. Microporous Mesoporous Mater. 133 (2010) 45 - 53.

DOI: 10.1016/j.micromeso.2010.04.012

[21] G. Fuat, S. Hasan, S. Gülbahar Akkaya, and K. Filiz, Elimination of anionic dye by using nanoporous carbon prepared from an industrial biowaste. J. Mol. Liq. 194 (2014) 130 - 140.

DOI: 10.1016/j.molliq.2014.01.018

[22] L. Bo, S. Hiroshi, J. Hailong, Z. Xinbo, and X. Qiang, Metal-organic framework (MOF) as a template for syntheses of nanoporous carbons as electrode materials for supercapacitor. Carbon 48 (2010) 456 - 463.

DOI: 10.1016/j.carbon.2009.09.061

[23] C. Watcharop, H. Ming, W. Hongjing, H. Hou-Sheng, F. Taketoshi, W. Kevin C.-W., C. Lin-Chi, Y. Yusuke and A. Katsuhiko, Nanoporous carbons through direct carbonization of a zeolitic imidazolate framework for supercapacitor electrodes. Chem. Commun. 48 (2012) 7259 - 7261.

DOI: 10.1039/c2cc33433j

[24] S. Rahul R., K. Yuichiro, T. Nagy L., H. Soo Min, S. Ziqi, D. Shi Xue, K. Jung Ho, and Y. Yusuke, Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons. J. Mater. Chem. A 2 (2014) 19848 - 19854.

DOI: 10.1039/c4ta04277h

[25] Suhas, P.J.M. Carrott, and M.M.L. Ribeiro Carrott, Lignin - from natural adsorbent to activated carbon: A review. Bioresource Technology 98 (2007) 2301 - 2312.

DOI: 10.1016/j.biortech.2006.08.008

[26] K.K. Pandey, A.J. Pitman, FTIR Studies of the Changes in Wood Chemistry Following Decay by Brown-rot and White-rot Fungi. International Biodeterioration & Biodegradation 52 (2003) 151 - 160.

DOI: 10.1016/s0964-8305(03)00052-0

[27] J. Z. Mao, L. Zhang, and F. Xu, Fractional and Structural Characterization of Alkaline Lignins From Carex Meyeriana Kunth. Cellulose chemtechnol 46 (3-4) (2012) 193 - 205.

[28] K. Minu, K. Kurian Jiby, and V.V.N. Kishore, Isolation and Purification of Lignin and Silica from the Black Liquor Generated During the Production of Bioethanol from Rice Straw. Biomass and Bioenergy 39 (2012) 210 – 217.

DOI: 10.1016/j.biombioe.2012.01.007

[29] S. Javad, K. Sally, D. S. Rosa, L. Alcides, and S. Mohini, Thermal Characteristics of Lignin Residue from Industrial Processes. BioResources 9(1) (2014) 725 – 737.