Characterization of Zirconia for Ceramic Dental Implant Coated with Carbonate Apatite

Abstract:

Zirconia-based dental implant in Indonesia is rarely used, especially due to low demand. High production cost makes the price of each zirconia dental implant piece become expensive. The fabrication process of the dental implant using 3 mol% Yttria-stabilized Zirconia (3YSZ) as a starting powder, or being synthesized using ZrCl3 and YCl4 precursor were costly and complicated. The aim of this study is to investigate morphology and phase analysis in the ceramic dental implant which coated with carbonate apatite (CO₃Ap). The industrial 3YSZ powder was compacted using a manual hydraulic press and sintered at 1500°C approximately to 11 mm pellet size. Specimens were pre-treated using 9% hydrofluoric acid (HF) before coated by CO₃Ap, while others without treatment as a control. Then, the specimens were dipped into CO₃Ap suspension and heat treated with temperature variable of 300°C or 500°C. The fabrication of specimen using manual hydraulic press creates monoclinic phase more than expected, while SEM discovered that the particle size of the specimen was 130-500nm. In conclusion, the effective method to coat the ceramic dental implant with CO₃Ap was using 9% HF as a pre-treatment and calcinate in 300°C as confirmed in XRD and EDS.

• Periodical: Key Engineering Materials (Volume 829)
• Pages: 138-144
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.829.138
• Online since: December 2019
• Authors: Fauziah Erfin, Rasmi Rikmasari, Lisda Damayanti, Andrie Harmaji, Arief Cahyanto*
• Keywords: Carbonate Apatite Coating, Morphology, XRD, Zirconia Implant

References

[1] R.B. Osman, and M.V. Swain, A critical review of dental implant materials with an emphasis on titanium versus zirconia, Materials (Basel). 8 (2015) 932–958.

DOI: 10.3390/ma8030932

[2] Z. Özkurt, and E. Kazazoğlu, Zirconia dental implants: a literature review, J. Oral Implantol. 37 (2011) 367–376.

DOI: 10.1563/aaid-joi-d-09-00079

[3] C.E. Misch, H.A. Abbas, Contemporary Implant Dentistry, 3rd ed., Mosby Elsevier Missouri, (2008).

[4] Y. Doi, H. Iwanaga, T. Shibutani. T, Y. Moriwaki, and Y. Iwayama, Osteoclastic responses to various calcium phosphates in cell cultures, J. Biomed. Mater. Res. 47 (1999) 424–433.

DOI: 10.1002/(sici)1097-4636(19991205)47:3<424::aid-jbm19>3.0.co;2-0

[5] P. Avés, et al., Comparative study of hydroxyapatite coatings obtained by sol-gel and electrophoresis on titanium sheets, Matéria (Rio de Janeiro). 12 (2007) 156–163.

DOI: 10.1590/s1517-70762007000100020

[6] M. Hirota, T. Hayakawa, C. Ohkubo, M. Sato, T. Toyama, and Y. Tanaka, Bone responses to zirconia implants with a thin carbonate-containing hydroxyapatite coating using a molecular precursor method, J. Biomed. Mater. Res. Part B (2014) 014:00B.

DOI: 10.1002/jbm.b.33112

[7] D. Peredni, and L.J Gauckler. Thin film deposition using spray pyrolysis, J. Electroceram. 14 (2005) 103-111.

DOI: 10.1007/s10832-005-0870-x

[8] A.K Riau, D. Modal, M. Setiawan, A. Palaniappan, G.H.F Yam, B Liedberg, S.S. Venkatraman, and J. S. Mehta. Functionalization of polymeric surface with bioceramic nanoparticles via novel, non-thermal dip coating method. ACS Appl. Mater. Interfaces. Downloaded from http://pubs.acs.org on October 1 (2018).

DOI: 10.1021/acsami.6b12371

[9] Hasanuzzaman, Sintering and characterization of nano sized yttria stabilized zirconia. A thesis for master engineering. School of Mechanical and Manufacturing Engineering. University of Dublin City, 2006, pp.28-29.

[10] A. Cahyanto, M. Maruta, K. Tsuru, Fabrication of bone cement that fully transforms to carbonate apatite, Dent. Mater. J. 34-3 (2015) 394–401.

DOI: 10.4012/dmj.2014-328

[11] A. Cahyanto, M. Maruta, K. Tsuru, et al., Basic Properties of carbonate apatite cement consisting of vaterite and dicalcium phosphate anhydrous. Key Eng. Mater. 529-530 (2012) 192-196.

DOI: 10.4028/www.scientific.net/kem.529-530.192

[12] B. Mavis, and C. Tas, Dip coating of calcium hydroxyapatite on Ti-6Al-4V substrates, J. Am. Ceram. Soc. 83-4 (2000) 989–991.

DOI: 10.1111/j.1151-2916.2000.tb01314.x

[13] B. R. Patterson, and J. A. Griffin, Effect of particle size distribution on sintering of tungsten, modem development in powder metallurgy, Metal Powder Industries Federation, 15 (1985) 279-288.

[14] A. Cahyanto, R. Toita, K. Tsuru, K. Ishikawa, Effect of particle size on carbonate apatite cement properties consisting of calcite (or vaterite) and dicalcium phosphate anhydrous, Key Eng. Mater. 631 (2015) 128-134.

DOI: 10.4028/www.scientific.net/kem.631.128

[15] C. Piconi, G. Maccauro, Zirconia as ceramic biomaterial, Biomaterials. 20 (1999) 1-25.

DOI: 10.1016/s0142-9612(98)00010-6

[16] ISO Standard 13356:2008. Implants for surgery – materials based on yttria-stabilized tetragonal zirconia (Y-TZP).

DOI: 10.3403/30276374

[17] V. Turp, D. Sen, G. Goller, M. Ozcan, Evaluation of air particle abrasion of Y-TZP with different particles using microstructural analysis, Aus. Dent. J. 58 (2013) 183-191.

DOI: 10.1111/adj.12065

[18] E. Landi, A. Tampieri, G. Celotti, L. Vichi, M. Sandri, Influence of synthesis and sintering parameters on the characteristics of carbonate apatite, Biomaterials. 25 (2004) 1763-1770.

DOI: 10.1016/j.biomaterials.2003.08.026