Molten Salt Synthesis of Multiple Manganese Oxides/Graphene Composites in Facile and Large Scale with Enhanced Supercapacitor Performance

Article Preview

Abstract:

A facile and effective approach to assemble graphene hybridized multiple manganese oxides /graphene ((m-MnO2/Gr) was explored. The structure varied from two-dimensional (2D) to one-dimensional (1D) club-shaped manganese oxides via blending of Gr into the molten salt precursor. Compared to the m-MnO2 and pristine Gr electrode, the m-MnO2/Gr composites displayed a superior synergistic effect in promoted capacitive performance, cycle performance, with capacity retention of about 90% after 2000 charge-discharge cycles. It expects to supply a promising strategy to synthesize large scalable production of hybrid supercapacitor electrode.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1035)

Pages:

746-751

Citation:

Online since:

June 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Chang, M. Jin, F. Yao, T. H. Kim, V. T. Le, H. Yue, F. Gunes, B. Li, A. Ghosh, S. Xie, Y. H. Lee, Asymmetric Supercapacitors Based on Graphene/MnO2 Nanospheres and Graphene/MoO3 Nanosheets with High Energy Density , Adv. Funct. Mater. 2013 (23) 5074-5083.

DOI: 10.1002/adfm201301851

Google Scholar

[2] X. Chang, X. Zhai, S. Sun, D. Gu, L. Dong, Y. Yin, Y. Zhu, Nanotechnology, MnO2/g-C3N4 nanocomposite with highly enhanced supercapacitor performance. 2017 (28) 135705-135710.

DOI: 10.1088/1361-6528/aa6107

Google Scholar

[3] Y. Z. Su, K. Xiao, N. Li, Z. Q. Liu, S. Z. Qiao, Amorphous Ni(OH)2@three-dimensional Ni core–shell nanostructures for high capacitance pseudocapacitors and asymmetric supercapacitors, J. Mater. Chem A, 2014 (2) 13845-13853.

DOI: 10.1039/c4ta02486a

Google Scholar

[4] H. Yang, H. Xu, L. Zhang, Y. Huang, X. Hu, Assembly of NiO/Ni(OH)2/PEDOT Nanocomposites on Contra Wires for Fiber-Shaped Flexible Asymmetric Supercapacitors, Appl. Mater. Inter, 2016 (3) 1774–1779.

DOI: 10.1021/acsami.5b09526

Google Scholar

[5] Z. Yu, B. Duong, D. Abbitt, J. Tomas, Energy Storage: Highly Ordered MnO2 Nanopillars for Enhanced Supercapacitor Performance, Adv. Mater. 2013 (25) 3302-3306.

DOI: 10.1002/adma.201300572

Google Scholar

[6] Y. Hou, Y. Cheng, T. Hobson, J. Liu, Design and synthesis of hierarchical MnO2 nanospheres/carbon nanotubes/conducting polymer ternary composite for high performance electrochemical electrodes, Nano Lett. 2010 (10) 2727-2733.

DOI: 10.1021/nl101723g

Google Scholar

[7] Y. Su, I. Zhitomirsky, Hybrid MnO2/carbon nanotube-VN/carbon nanotube supercapacitors, J. Pow. Sour. 267 (2014) 235-242.

DOI: 10.1016/j.jpowsour.2014.05.091

Google Scholar

[8] Z. Bai, H. Li, M. Li, C. Li, X. Wang, C. Qu, B. Yang, Flexible carbon nanotubes-MnO2/reduced graphene oxide-polyvinylidene fluoride films for supercapacitor electrodes, Int. J. Hydrogen Energy, 2015 (40) 16306-16315.

DOI: 10.1016/j.ijhydene.2015.09.065

Google Scholar

[9] S. Chasemi, R. Hosseinzadeh, M. Jafari, Int. J. MnO2 nanoparticles decorated on electrophoretically deposited graphene nanosheets for high performance supercapacitor, Hydrogen Energy. 2015 (40) 1037-1046.

DOI: 10.1016/j.ijhydene.2014.11.072

Google Scholar

[10] H. Zhou, X. Yang, J. Lv. Q. Dang, L. Kang, Z. Lei, Z. Yang, Z. Hao, Z. Liu, Graphene/MnO2 hybrid film with high capacitive performance, Electrochem. Acta, 2015 (154) 300-307.

DOI: 10.1016/j.electacta.2014.12.027

Google Scholar

[11] S. Deng, C. Wu, H. Wang, J. Liu, Y. Sun, H. Yan, Synthesis and electrochemical properties of MnO2 nanorods/graphene composites for supercapacitor applications, Electrochim. Acta, 2013 (111) 707-712.

DOI: 10.1016/j.electacta.2013.08.055

Google Scholar

[12] F. Yang, M. Xu, S. Bao, Q. Sun, MnO2-assisted fabrication of PANI/MWCNT composite and its application as a supercapacitor, ASC Adv. 2014 (4) 33569.

DOI: 10.1039/c4ra04905e

Google Scholar

[13] Z. Hu, X. Xiao, H. Jin, T. Li, M. Chen, Z. Liang, Z. Guo, J. Li, J. Wan, L. Huang, Y. Zhang, G. Feng, J. Zhou, A collection of 10,096 indica rice full-length cDNAs reveals highly expressed sequence divergence between Oryza sativa indica and japonica subspecies, Nat. Commun, 2017 (8) 15630-15638.

DOI: 10.1007/s11103-007-9174-7

Google Scholar

[14] N. Sui, Y. Duan, X. Jiao, D. Chen, Large-Scale Preparation and Catalytic Properties of One-Dimensional α/β-MnO2 Nanostructures, J. Phys. Chem. C, 2009 (113) 8560-8565.

DOI: 10.1021/jp810452k

Google Scholar

[15] P. H. Yang, Y. Ding, Z.Y. Lin, Z. W. Chen, Y.Z. Li, P. F. Qiang, Low-Cost High-Performance Solid-State Asymmetric Supercapacitors Based on MnO2 Nanowires and Fe2O3 Nanotubes, Nano Lett. 2014 (14) 731–736.

DOI: 10.1021/nl404008e

Google Scholar

[16] YH. Lei , N. Sheng, A. Hyono, M. Ueda, T. Ohtsuka, Electrochemical synthesis of polypyrrole films on copper from phytic solution for corrosion protection, Corr. Sci., 2013 (76) 302-309.

DOI: 10.1016/j.corsci.2013.07.003

Google Scholar

[17] P. Yu, Z. Zhang, L. Zhang, F. Ting, L. Hu, X. Fang, A Novel Sustainable Flour Derived Hierarchical Nitrogen‐Doped Porous Carbon/Polyaniline Electrode for Advanced Asymmetric Supercapacitors, Adv. Energy Mater. 2016 (6) 1601111.

DOI: 10.1002/aenm.201601111

Google Scholar