Developing New Natural Surfactant from Date Seeds for Different Field Applications

Abstract:

The increase in using natural surfactants for enhanced oil recovery (EOR) purposes in recent years is mainly attributed to the widespread global awareness of the environmental effects the oil and gas industry causes. In accordance with KSA Vision 2030 and the corresponding global direction, the purpose of this study is to discover a cost effective, readily available, environmentally friendly, and locally sourced surfactant. This surfactant will help reduce the interfacial tension (IFT) between reservoir liquids to enhance the reservoir’s productivity and increase its ultimate recovery. In this study, date seeds have been chosen as the green surfactant source due to the abundance of such seeds. Al-Khalas, which is a well-known palm tree that grows in Qassim, Al-Kharj, and Al-Ahsa provinces in KSA was chosen. Properties such as surface tension (ST), IFT, pH, and density were measured to evaluate the effectiveness of date seeds as a natural surfactant. ST results showed a reduction from 72 mN/m (of distilled water) to 43 mN/m using the new surfactant in formation water at 10 wt% comprising a 40% reduction. Moreover, IFT of the new surfactant with Saudi medium oil (26 API) was 10 mN/m compared to 18 mN/m of a formation water-oil system which represents a 49% reduction in interfacial tension. Overall, the novel surfactant studied in this research shows great promise in being an effective EOR agent in addition to eliminating the negative impacts of regular surfactants on the environment.

• Periodical: Materials Science Forum (Volume 1125)
• Pages: 53-63
• DOI: https://doi.org/10.4028/p-ONoxF5
• Online since: September 2024
• Authors: Noah Al Otaibi, Moustafa Aly, Taha Moawad*
• Keywords: Crude Oil, Date Seeds, Enhanced Oil Recovery, Green Surfactant

References

[1] Afolabi RO, Oluyemi GF, Officer S, Ugwu JO. Hydrophobically associating polymers for enhanced oil recovery – Part A: A review on the effects of some key reservoir conditions. J Pet Sci Eng. 2019 Sep;180:681–98.

DOI: 10.1016/j.petrol.2019.06.016

[2] Sabhapondit A, Borthakur A, Haque I. Water Soluble Acrylamidomethyl Propane Sulfonate (AMPS) Copolymer as an Enhanced Oil Recovery Chemical. Energy Fuels. 2003 May 1;17(3):683–8.

DOI: 10.1021/ef010253t

[3] Wever DAZ, Picchioni F, Broekhuis AA. Polymers for enhanced oil recovery: A paradigm for structure–property relationship in aqueous solution. Prog Polym Sci. 2011 Nov;36(11):1558–628.

DOI: 10.1016/j.progpolymsci.2011.05.006

[4] Li Z, Wu H, Hu Y, Chen X, Yuan Y, Luo Y, et al. Ultra-low interfacial tension biobased and catanionic surfactants for low permeability reservoirs. J Mol Liq. 2020 Jul;309:113099.

DOI: 10.1016/j.molliq.2020.113099

[5] Olayiwola SO, Dejam M. A comprehensive review on interaction of nanoparticles with low salinity water and surfactant for enhanced oil recovery in sandstone and carbonate reservoirs. Fuel. 2019 Apr;241:1045–57.

DOI: 10.1016/j.fuel.2018.12.122

[6] Alzahid YA, Mostaghimi P, Walsh SDC, Armstrong RT. Flow regimes during surfactant flooding: The influence of phase behaviour. Fuel. 2019 Jan;236:851–60.

DOI: 10.1016/j.fuel.2018.08.086

[7] Daghlian Sofla SJ, Sharifi M, Hemmati Sarapardeh A. Toward mechanistic understanding of natural surfactant flooding in enhanced oil recovery processes: The role of salinity, surfactant concentration and rock type. J Mol Liq. 2016 Oct;222:632–9.

DOI: 10.1016/j.molliq.2016.07.086

[8] Sheng JJ. Enhanced oil recovery in shale reservoirs by gas injection. J Nat Gas Sci Eng. 2015 Jan;22:252–9.

[9] Alfarge D, Wei M, Bai B. IOR Methods in Unconventional Reservoirs of North America: Comprehensive Review. In: Day 3 Tue, April 25, 2017 [Internet]. Bakersfield, California: SPE; 2017 [cited 2023 Sep 25]. p. D031S008R005. Available from: https://onepetro.org/SPEWRM/proceedings/17WRM/3-17WRM/Bakersfield,%20California/195912

DOI: 10.2118/185640-ms

[10] Nowrouzi I, Mohammadi AH, Manshad AK. Chemical Enhanced Oil Recovery by Different Scenarios of Slug Injection into Carbonate/Sandstone Composite Oil Reservoirs Using an Anionic Surfactant Derived from Rapeseed Oil. Energy Fuels. 2021 Jan 21;35(2):1248–58.

DOI: 10.1021/acs.energyfuels.0c03385

[11] Gong L, Liao G, Luan H, Chen Q, Nie X, Liu D, et al. Oil solubilization in sodium dodecylbenzenesulfonate micelles: New insights into surfactant enhanced oil recovery. J Colloid Interface Sci. 2020 Jun;569:219–28.

DOI: 10.1016/j.jcis.2020.02.083

[12] Yun W, Chang S, Cogswell DA, Eichmann SL, Gizzatov A, Thomas G, et al. Toward Reservoir-on-a-Chip: Rapid Performance Evaluation of Enhanced Oil Recovery Surfactants for Carbonate Reservoirs Using a Calcite-Coated Micromodel. Sci Rep. 2020 Jan 21;10(1):782.

DOI: 10.1038/s41598-020-57485-x

[13] Deljooei M, Zargar G, Nooripoor V, Takassi MA, Esfandiarian A. Novel green surfactant made from L-aspartic acid as enhancer of oil production from sandstone reservoirs: Wettability, IFT, microfluidic, and core flooding assessments. J Mol Liq. 2021 Feb;323:115037.

DOI: 10.1016/j.molliq.2020.115037

[14] Shadizadeh SR, Seyedi Abandankashi SR, Moradi S. Experimental Investigation Used of Albizia Julibrissin Extract as a Plant Surfactant on Oil Recovery. Iran J Oil Gas Sci Technol [Internet]. 2021 Jan [cited 2023 Sep 25];(Online First). Available from:

[15] Su L, Sun J, Ding F, Gao X, Zheng L. Effect of molecular structure on synergism in mixed zwitterionic/anionic surfactant system: An experimental and simulation study. J Mol Liq. 2021 Jan;322:114933.

DOI: 10.1016/j.molliq.2020.114933

[16] Groenendijk DJ, Van Wunnik JNM. The Impact of Micelle Formation on Surfactant Adsorption–Desorption. ACS Omega. 2021 Jan 26;6(3):2248–54.

DOI: 10.1021/acsomega.0c05532

[17] Kurnia I, Zhang G, Han X, Yu J. Zwitterionic-anionic surfactant mixture for chemical enhanced oil recovery without alkali. Fuel. 2020 Jan;259:116236.

DOI: 10.1016/j.fuel.2019.116236

[18] Esfandyari H, Moghani Rahimi A, Esmaeilzadeh F, Davarpanah A, Mohammadi AH. Amphoteric and cationic surfactants for enhancing oil recovery from carbonate oil reservoirs. J Mol Liq. 2021 Jan;322:114518.

DOI: 10.1016/j.molliq.2020.114518

[19] Khayati H, Moslemizadeh A, Shahbazi K, Moraveji MK, Riazi SH. An experimental investigation on the use of saponin as a non-ionic surfactant for chemical enhanced oil recovery (EOR) in sandstone and carbonate oil reservoirs: IFT, wettability alteration, and oil recovery. Chem Eng Res Des. 2020 Aug;160:417–25.

DOI: 10.1016/j.cherd.2020.04.033

[20] Asl HF, Zargar G, Manshad AK, Takassi MA, Ali JA, Keshavarz A. Experimental investigation into l-Arg and l-Cys eco-friendly surfactants in enhanced oil recovery by considering IFT reduction and wettability alteration. Pet Sci. 2020 Feb;17(1):105–17.

DOI: 10.1007/s12182-019-0354-2

[21] Do Vale TO, De Magalhães RS, De Almeida PF, Matos JBTL, Chinalia FA. The impact of alkyl polyglycoside surfactant on oil yields and its potential effect on the biogenic souring during enhanced oil recovery (EOR). Fuel. 2020 Nov;280:118512.

DOI: 10.1016/j.fuel.2020.118512

[22] Bahraminejad H, Manshad AK, Keshavarz A. Characterization, Micellization Behavior, and Performance of a Novel Surfactant Derived from Gundelia tournefortii Plant during Chemical Enhanced Oil Recovery. Energy Fuels. 2021 Jan 21;35(2):1259–72.

DOI: 10.1021/acs.energyfuels.0c03272

[23] Jiao K, Feng Q, Davarpanah A. Effect of anionic and non-anionic surfactants on the adsorption density. Pet Sci Technol. 2021 May 19;39(9–10):362–72.

DOI: 10.1080/10916466.2021.1893331

[24] Chen W, Schechter DS. Surfactant selection for enhanced oil recovery based on surfactant molecular structure in unconventional liquid reservoirs. J Pet Sci Eng. 2021 Jan;196:107702.

DOI: 10.1016/j.petrol.2020.107702

[25] Atta DY, Negash BM, Yekeen N, Habte AD. A state-of-the-art review on the application of natural surfactants in enhanced oil recovery. J Mol Liq. 2021 Jan;321:114888.

DOI: 10.1016/j.molliq.2020.114888

[26] Holmberg K. Natural surfactants. Curr Opin Colloid Interface Sci. 2001 May;6(2):148–59.

[27] Sen R. Biotechnology in petroleum recovery: The microbial EOR. Prog Energy Combust Sci. 2008 Dec;34(6):714–24.

[28] Imanivarnosfaderani MR, Gomari SR, Dos Santos RG. Effects of rhamnolipid bio-surfactant and sodium dodecylbenzene sulfonate (SDBS) surfactant on enhanced oil recovery from carbonate reservoirs. Braz J Chem Eng. 2022 Sep;39(3):825–33.

DOI: 10.1007/s43153-021-00208-0

[29] Kumar S, Kumar A, Mandal A. Characterizations of surfactant synthesized from Jatropha oil and its application in enhanced oil recovery. AIChE J. 2017 Jul;63(7):2731–41.

DOI: 10.1002/aic.15651

[30] Pal N, Kumar S, Bera A, Mandal A. Phase behaviour and characterization of microemulsion stabilized by a novel synthesized surfactant: Implications for enhanced oil recovery. Fuel. 2019 Jan;235:995–1009.

DOI: 10.1016/j.fuel.2018.08.100

[31] Khandoozi S, Sharifi A, Riazi M. Enhanced oil recovery using surfactants. In: Chemical Methods [Internet]. Elsevier; 2022 [cited 2023 Sep 25]. p.95–139. Available from: https://linkinghub.elsevier.com/retrieve/pii/B9780128219317000079

DOI: 10.1016/b978-0-12-821931-7.00007-9

[32] Bachari Z, Isari AA, Mahmoudi H, Moradi S, Mahvelati EH. Application of Natural Surfactants for Enhanced Oil Recovery – Critical Review. IOP Conf Ser Earth Environ Sci. 2019 Mar 1;221:012039.

DOI: 10.1088/1755-1315/221/1/012039

[33] Jahan R, Bodratti AM, Tsianou M, Alexandridis P. Biosurfactants, natural alternatives to synthetic surfactants: Physicochemical properties and applications. Adv Colloid Interface Sci. 2020 Jan;275:102061.

DOI: 10.1016/j.cis.2019.102061

[34] Mujumdar S, Joshi P, Karve N. Production, characterization, and applications of bioemulsifiers (BE) and biosurfactants (BS) produced by Acinetobacter spp.: A review. J Basic Microbiol. 2019 Mar;59(3):277–87.

DOI: 10.1002/jobm.201800364

[35] Tackie-Otoo BN, Ayoub Mohammed MA. Experimental investigation of the behaviour of a novel amino acid-based surfactant relevant to EOR application. J Mol Liq. 2020 Oct;316:113848.

DOI: 10.1016/j.molliq.2020.113848

[36] Kumar P, Mittal KL, editors. Handbook of Microemulsion Science and Technology [Internet]. 1st ed. CRC Press; 2018 [cited 2023 Sep 25]. Available from: https://www.taylorfrancis.com/books/9781351442343

[37] Li Z, Wu H, Yang M, Jiang J, Xu D, Feng H, et al. Spontaneous Emulsification via Once Bottom-Up Cycle for the Crude Oil in Low-Permeability Reservoirs. Energy Fuels. 2018 Mar 15;32(3):3119–26.

DOI: 10.1021/acs.energyfuels.7b03720

[38] Vatanparast H, Alizadeh AH, Bahramian A, Bazdar H. Wettability Alteration of Low-permeable Carbonate Reservoir Rocks in Presence of Mixed Ionic Surfactants. Pet Sci Technol. 2011 Jul 28;29(18):1873–84.

DOI: 10.1080/10916461003610389

[39] Nandwani SK, Chakraborty M, Bart HJ, Gupta S. Synergism, phase behaviour and characterization of ionic liquid-nonionic surfactant mixture in high salinity environment of oil reservoirs. Fuel. 2018 Oct;229:167–79.

DOI: 10.1016/j.fuel.2018.05.021

[40] Pillai P, Mandal A. Synthesis and characterization of surface-active ionic liquids for their potential application in enhanced oil recovery. J Mol Liq. 2022 Jan;345:117900.

DOI: 10.1016/j.molliq.2021.117900

[41] AlAwad MNJ, Fattah KA. Superior fracture-seal material using crushed date palm seeds for oil and gas well drilling operations. J King Saud Univ - Eng Sci. 2019 Jan;31(1):97–103.

DOI: 10.1016/j.jksues.2017.01.003

[42] Moawad TM, Al-Dhafeeri AM, Mohamed TI. Reservoir Management Tool-Kits in Offshore Khafji Field: Successful Solutions for Field Case Studies on Water Conning Problems in Sandstone Reservoirs. In: All Days. Cairo, Egypt: SPE; 2013. p. SPE-164642-MS. Available from: https://onepetro.org/SPENATC/proceedings/13NATC/All-13NATC/Cairo,%20Egypt/ 17779

DOI: 10.2118/164642-ms