Synthesis and Characterization of Ammonium Decavanadate (V)

M.R. Todorović; U.B. Mioč; I. Holclajtner-Antunović; D. Šegan

doi:10.4028/www.scientific.net/MSF.494.351

Paper Titles

Characterization of Carbon Cryogel Synthesized by Sol-Gel Polycondensation and Freeze-Drying
p.327

Nickel/Silica Precursor from Sodium Silicate Solution - Synthesis and Characterization
p.333

The Influence of Acid Treatment on the Nanostructure and Textural Properties of Bentonite Clays
p.339

Reduction of NiO-WO₃ Oxide Mixtures Synthesized by Gel-Combustion Technique: A Route to Ni-W Alloys
p.345

Synthesis and Characterization of Ammonium Decavanadate (V)
p.351

Structural Characterization of Poly(o-Tolidine)
p.357

Characterization and Catalytic Activity of Poly(4-Vinylpyridine-Co-Divinylbenzene)-Co²⁺ Complex
p.363

Examinations of Cross-Linked Polyvinylpyridine in Open Reactor
p.369

Investigation of Thermal Stability of Zn(II), Pt(II) and Pd(II) Complexes with (E)-2-oxo-2-{N'-[1-(pyridin-2-yl)ethylidene]hydrazino}acetamide
p.375

HomeMaterials Science ForumMaterials Science Forum Vol. 494Synthesis and Characterization of Ammonium...

Synthesis and Characterization of Ammonium Decavanadate (V)

Abstract:

It is known that various polyoxovanadates interact specifically with enzymes, which is the main way of their biochemical activity. Therefore we have synthesized ammonium decavanadate, (NH4)6V10O28·6H2O. The novel compound was characterized by elemental and thermal analysis, X-ray powder and single crystal diffraction and IR and Raman spectroscopy. Its conductive properties have been studied, too. The spectroscopic analysis has shown the presence of hydrogen bonds of different strengths. In order to improve the biochemical activity of this compound and having in mind the presence of strong hydrogen bonds, we essayed the synthesis of complex of polyoxovanadate with alanine. The obtained product was characterized by the mentioned methods.

You might also be interested in these eBooks

Current Research in Advanced Materials and Processes

View Preview

Info:

Periodical:

Materials Science Forum (Volume 494)

Pages:

351-356

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.494.351

Citation:

Cite this paper

Online since:

September 2005

Authors:

M.R. Todorović, U.B. Mioč, I. Holclajtner-Antunović, D. Šegan

Keywords:

Ammonium Decavanadate, Conductivity, IR Spectra, Polyoxometalate POM, Raman Spectra, Thermal Analysis, X-Ray Diffraction (XRD)

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] D. C. Crans, Comments Inorg. Chem. Vol. 16 (1994), p.35.

Google Scholar

[2] C. Eglmeier, K. J. Range, A. Kleynhans, A. Heyns, S. Afr. J. Chem. Vol. 46 (1993), p.7.

Google Scholar

[3] S. Sredić, T. Čajkovski, M. Davidović, V. Likar-Smiljanić, M. Marinović-Cincović, U. B. Mioč, Z. Nedić and R. Biljić, Material Science Forum Vol. 453-454 (2004), p.153.

DOI: 10.4028/www.scientific.net/msf.453-454.157

Google Scholar

[4] U. B. Mioč, S. Milonjić, D. Malović, V. Stamenković, Ph. Colomban, M. Mitrović and R. Dimitrijević, Solid State Ionics Vol. 97 (1997), p.239.

DOI: 10.1016/s0167-2738(97)00089-1

Google Scholar

[5] G. Bogdanović, N. Bošnjaković-Pavlović, A. Spasojević-Bire, N.E. Ghermani, to be published.

Google Scholar

[6] N. Tjapkin, Ph. Colomban and U. Mioč, Solid State Ionics Vol. 61 (1993), p.179.

Google Scholar

[7] S. Sredić, M. Davidović, A. Spasojević-de-Bure, U. B. Mioč, M. Todorović, D. Šegan, D. Jovanović and P. Pissis, Solid State Proton Conductors-12, Upsala, Sweden, 15-19. VIII 2004., Proceedings, p.107.

Google Scholar