Materials Science Forum Vols. 503-504

Abstract: Typically, magnesium alloys with conventional grain size exhibit microplastic behaviour already at low stresses. This behaviour restricts the technological utilization of these materials. The aim of this study was to investigate whether ECAP can be applied to enlarge the elastic range of AS21X. Cyclic tensile tests at room temperature were carried out to examine the effect of the ECAP induced grain refinement on the elastic properties. The results obtained are compared with the cyclic behaviour of conventional, coarse-grained AS21X. The differences in mechanical properties between the two conditions are discussed.

Abstract: Fine-grained structures in Fe-36mass%Ni Invar alloy have been investigated by using transmission electron microscopy (TEM). Particular attention has been paid on the role of deformation twinning in the formation of fine-grained structures and its influence on tensile stressstrain behaviours of rolled specimens. In Fe-Ni Invar alloy with a moderate stacking fault energy, deformation twin did not appear in usual cold-rolling at room temperature (RT), where a kind of cell walls was formed and the Cu-type texture was observed. On the other hand, twinning was occurred by rolling when specimens were cooled to liquid nitrogen temperature (LNT) immediately before the rolling. In such case, a fine lamellar structure was developed and the brass-type texture appeared. However, the lamella boundaries did not coincide with any crystallographic planes, and they were intersected with the bands of deformation twin. Specimens rolled by 90% in thickness reduction exhibited tensile stressstrain behaviours similar to those observed in specimens with SPD structures. In particular, specimens rolled at LNT showed high yield strengths and non-uniform deformation.

Abstract: The Cu-10vol.% Cr in situ composites were fabricated and their mechanical and corrosion properties were determined. For an equivalent amount of deformation, fcc-bcc composites have a much thinner effective fibre thickness and a much larger interfacial area than do fcc-fcc composite. The yield strength and the modulus of the composite decrease with temperature whereas the failure strain increases with temperature. The observed increase in failure strain with an increase in temperature from 22-600°C is as high as 333 %. Corrosion potential and rate in aerated hydro-sulfuric acid solution are -36.6 mVSHE and 3.525x10-3 A/cm2, respectively. Based on the electrochemical behaviors of the copper and chromium and observation of corrode surface, the corrosion mechanism of the copper-10% chromium composites in aerated hydro-sulfuric acid solution includes deallying mechanism in α-phase and galvanic corrosion at the interface between copper and chromium.

Abstract: Martensite transformation of the ultrafine grained (UFG) austenite fabricated by the accumulative roll bonding (ARB) process was studied. The Fe-28.5at.%Ni alloy sheet was severely deformed in austenite state by the ARB process up to 5 cycles. The ARB processed sheet had the ultrafine lamellar boundary structure. The mean lamellar spacing was 230 nm in the 5 cycles specimen. The sheets ARB processed by various cycles were cooled down to 77 K to cause the martensite transformation. Martensite transformation starting (Ms) temperature decreased with increasing the number of the ARB process. The Ms temperature of the ultrafine lamellar austenite in the 5 cycles specimen was 225 K, which was lower than that (247 K) of the conventionally recrystallized specimen with mean grain size of 22 μm. The martensite having characteristic morphologies appeared from the UFG austenite, although the martensite transformed from the coarse-grained specimen showed typical plate (or lenticular) morphology. The strength of the nano-martensite transformed from the UFG austenite was about 1.5 times higher than that of the UFG austenite, and it reached to 970 MPa.

Abstract: The recrystallization behavior and texture development in copper accumulative roll-bonding (ARB) processed by various cycles (2, 4 and 6 cycle) were studied by differential scanning calorimetry (DSC) analysis and SEM/EBSP method. The exothermic peaks caused by recrystallization appeared at 210 ~ 253 􀍠 in each sample. The peak positions shifted to lower temperature as the number of ARB cycles increased. This result indicated that the evolution of finer microstructure with increasing number of the ARB cycles enhanced the occurrence of recrystallization at lower temperature. The stored energy calculated from the DSC curve of the ARB processed copper increased with the increasing strains. During an annealing, the preferential growth of cube-oriented grains ({100}<001>) occurred in each sample. The recystallization behavior of ARB processed copper having low stacking fault energies was distinguished from that of so-called “recovery type” materials, i.e. aluminum and low carbon steels, which shows rather continuous changes in microstructure during annealing. The accumulated strains provided the driving force for the preferential growth, which was the same mechanism as the preferential growth in normally rolled copper. The sharpest cube texture developed in ARB processed copper by 4 cycles. The difference of cube texture development between 2 cycles and 4 cycles was caused by the distribution of cube-oriented regions which corresponded to the nucleation sites of recrystallized grains before annealing. More nanocystalline layers in the vicinity of bonded interfaces were distributed in ARB processed copper by 6 cycles than 4cycles. The nanocystalline structure could grow faster than the cube-oriented grains and led to the inhibition of sharp cube texture in the ARB processed copper by 6 cycles.

Abstract: Grain boundary structures in the Accumulative roll-bonding (ARB) processed copper (ARB-Cu) have been studied. The grain boundary structures were observed by high-resolution transmission electron microscopy (HRTEM). In order to clarify the difference between the grain boundaries in ARB-Cu and equilibrium boundaries, calculated atomic structure of symmetric tilt grain boundaries with <110> common axis (<110> symmetric tilt grain boundary; <110> STGB) in Cu were used. The near 14° boundary in the ARB-Cu could be described by the dislocation model, but the dense dislocation region existed near the grain boundary. The high angle boundaries in ARB-Cu could be described by the structural units which were obtained by molecular dynamics (MD) simulation. Furthermore, in the 2 cycles and 6 cycles ARB-Cu (2cARB-Cu and 6cARB-Cu), the deformation twin boundaries could be observed and described by the structural unit. Therefore, it was concluded that the grain boundary structure in the ARB-Cu was not much different from the normal equilibrium grain boundary and explained by conventional dislocation and structural unit models.

Abstract: Plastic deformation behavior during equal channel multi-angular pressing (ECMAP) was analyzed using the three dimensional finite volume method of the commercial code MSC.Superforge. In order to understand local and global deformation characteristics, effective strain and pressing load histories were investigated. The predicted plastic deformation behavior of the workpiece material during ECMAP of route A, route B and route C with a theoretical total strain of ~2.2 upon a single pass at three different friction factors (m=0, 0.1 and 0.2) was compared. The predicted strain results show different values in outside and similar values in central regions of the processed workpieces with different friction and forming routes. The pressing loads are higher under higher friction condition, showing almost no difference with three different pressing routes.

Abstract: The texture and grain boundary evolution during equal channel angular pressing (ECAP) of a spray-cast Al-7034 (Al-Zn-Mg-Cu) alloy containing intermetallic particles with a range of sizes was studied through electron backscatter diffraction (EBSD). Up to 8 passes of ECAP using route Bc were employed. The initial ECAP pass leads to the development of low angle grain boundaries and subsequent passes lead to a relatively rapid increase in the fraction of high angle grain boundaries. Before ECAP, the material possessed a strong <111> and <100> fibre texture. On ECAP, the <111> fibre texture component is mostly retained but the <100> fibre develops to a Cube texture after the first ECAP pass. Goss textures form from about 4 passes of ECAP.