Adsorption for Au³⁺ by Persimmon Tannins Immobilized on Collagen Fiber

Abstract:

A novel adsorbent which is effective to adsorb Au³⁺ was prepared using immobilized persimmon tannin (PT) on collagen fiber by glutaraldehyde crosslinking. The adsorption behaviour of this new adsorbent to Au³⁺ in aqueous solution was investigated. The effects of various factors such as initial solution pH, temperature, ionic strength and initial concentration of Au³⁺ on the influence of the adsorption process were studied. The equilibrium adsorption capacity reached 2347 mg/g at 323 K and pH value 2.0 when the initial concentration of Au³⁺ in aqueous solution was 500 mg/L. The immobilized PT was characterized by FT-IR, XRD and SEM. The results indicated that Au³⁺ changed to gold by oxidation adjacent phenol hydroxyl groups of persimmon tannin. Experiments also showed that adsorption isotherms of immobilized tannin for Au³⁺ could be described by Langmuir models. Immobilized PT adsorption provided a new way for the separation of the precious metal ions

• Periodical: Materials Science Forum (Volumes 745-746)
• Pages: 39-45
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.745-746.39
• Online since: February 2013
• Authors: Feng Lei Liu, Zhong Min Wang, Jian Cui, Zhi De Zhou, Gui Yin Li, Huai Ying Zhou
• Keywords: Adsorption, Au³⁺, Collagen Fiber (CF), Persimmon Tannins

References

[1] E. Chiessi, B. Pispisa, Polymer-supported catalysis oxidation of catecholamine by Fe3+ and Cu2+ complexes immobilized to chitosan, J. Mol. Catal. 87 (1994) 177-194.

DOI: 10.1016/0304-5102(93)e0235-9

[2] S. Babel, T.A. Kurniawan, Low-cost adsorbent for heavy metals uptake from contaminated water, J. Hazardous Materials. 97 (2003) 219-243.

DOI: 10.1016/s0304-3894(02)00263-7

[3] G. Vazquez, S. Freire, et al., Removal of cadmium and mercury ions form aqueous solution by sorption on treated pinus pinater bark kinetics and isotherms. J. Chemical Technology and Biotechnology. 82 (2002) 247-256.

DOI: 10.1016/s0960-8524(01)00186-9

[4] B. Shi, Y. Di, Plant PolypHenol, China Science Press, Beijing, 2000, pp.124-126.

[5] D.W. Sun, The Chemistry of Vegetable Tannin, China Forestry Publishing House, Beijing, 1988, pp.5-6.

[6] G. Sun, S.W. X, Sunflower stakes as adsorbent for the removal of metal ions form waste water, J. Ind. Eng. Chem. Res. 37 (1998) 1324-1328.

[7] X.M. Zhan, X. Zhao, Mechanism of lead adsorption form aqueous solutions using an adsorbent synthesized from natural condensed tannin, J. Water Research. 37 (2003) 3905-3912.

DOI: 10.1016/s0043-1354(03)00312-9

[8] M.M. Donlad, I. Mila, A. Scalbert, Precipitation of metal ions by plant polyphones Optimal conditions and origin of precipitation, J. Agricultural and Food Chemistry. 44 (1996) 599-606.

DOI: 10.1021/jf950459q

[9] M. Goto, K. Suyama, Appl. Biochemist. Biotechnology. 47 (2002) 84-86.

[10] A. Nakajima, T. Sakaguchi, Uptake and removal of ion by immobilized persimmon tannin, J. Chemical Technology and Biotechnology. 75 (2000) 977-982.

DOI: 10.1002/1097-4660(200011)75:11<977::aid-jctb305>3.0.co;2-j

[11] T. Ogato, Y. Nakano, Mechanism of gold recovery from aqueous solutions using a novel tannin gel adsorbent synthesized from natural condensed tannin, J. Water Research. 39 (2005) 4281-4286.

DOI: 10.1016/j.watres.2005.06.036

[12] Y. Jiala, C.J. Steele, et al., Mechanism of adsorption of gold and silver species on activated carbon, J. Carbon. 36 (1998) 1299-1308.

DOI: 10.1016/s0008-6223(98)00091-8

[13] M. Yalcin, I. Arola, Gold cyanide adsorption characteristics of activated carbon of non-count shell origin, J. Hydrometallurgy. 63 (2002) 201-206.

DOI: 10.1016/s0304-386x(01)00203-1

[14] D. Parajuli, H. Kawakita, K. Inoue, Persimmon peel gel for the selective recovery of gold, J. Hydrometallurgy. 87 (2007) 133-139.

DOI: 10.1016/j.hydromet.2007.02.006

[15] X. Huang, Y.P. Wang, X.P. Liao, B. Shi, Adsorptive recovery of Au3+ from aqueous solutions using bayberry tannin-immobilized mesoporous silica. J. Hazardous Materials. 183 (2010) 793-789.

DOI: 10.1016/j.jhazmat.2010.07.096

[16] Morenovi, Rivasbl, Retention of metal ions in ultra filtration of mixtures of divalent metal ions and water–soluble polymer at constant ionic strength based on Freundlich and Langmuir isotherms, J. Membrane Sci. 215 (2000) 195-202.

DOI: 10.1016/s0376-7388(02)00613-0

[17] Y.H. Zeng, X. Sun, X.P. Liao, B. Shi, Preparation of Tannin Immobilized onto Collagen Adsorbent and its Adsorption to Pd2+, J. Leather Science And Engineerring. 17 (1998) 5-6.

[18] J.W. Lin, Y.H. Zhan, Z.L. Zhu, Y.Q. Xing, Adsorption of tannin acid from aqueous solution onto surfactant-modified zeolite, J. Hazardous Materials. 193 (2011) 102-111.

DOI: 10.1016/j.jhazmat.2011.07.035

[19] S.Y. Gao, L. He, X.P. Liao, B. Shi, Preparation, Characteristics and Antibacterial Activity of Nano-Ag Loaded on Beyberry Tannin-grafted Collagen Fiber, J. Fine Chemicals. 27 (2001) 10-11.