Study on the Preparation of Silver Nanoparticles Coated with Diamond-Like Carbon Film and their Properties

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Abstract:

Ag nanoparticles (NPs) have prominent local surface plasma resonance effect (LSPR), and Ag NPs exhibit sharpest and strongest bands among all metals. Diamond-like carbon (DLC) film have good biological compatibility and also have high transmissibility in the visible and near-infrared region. A new LSPR interface between Ag NPs and ultra-thin DLC film was formed by Plasma Enhanced Chemical Vapor Deposition. The morphologies and properties of the Ag NPs coated with DLC film were studied with SEM and AFM. The results indicated that the thickness of DLC film increased with the deposition time. LSPR peak became sharper after depositing for 1 or 2 min. DLC film was prior to nucleate on the surface of Ag NPs, and it has high content of sp2 bonds near the interface. The sensitivity of new LSPR interface deposited for 20s was about the half of the sensitivity of bare Ag NPs and the sensitivity significantly decreased with deposition time. This result is helpful to understand the behavior of the new LSPR interface and to improve its sensitivity.

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Materials Science Forum (Volumes 745-746)

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60-65

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February 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] N. Nath, A. Chilkoti, A colorimetric gold nanoparticle sensor to interrogate biomolecular interactions in real time on a surface, Anal. Chem. 74 (2002) 504-509.

DOI: 10.1021/ac015657x

Google Scholar

[2] F. Frederix, J. Friedt, K. Choi, W. Laureyn, A. Campitelli, D. Mondelaers, G. Maes, G. Borghs, Biosensing based on light absorption of nanoscaled gold and silver particles, Anal. Chem. 75 (2003) 6894-6900.

DOI: 10.1021/ac0346609

Google Scholar

[3] M. Lahav, A. Vaskevich, I. Rubinstein, Biological sensing using transmission surface plasmon resonance spectroscopy, Langmuir 20 (2004) 7365-7367.

DOI: 10.1021/la0489054

Google Scholar

[4] A.J. Haes, W.P. Hall, L. Chang, W.L. Klein, R.P. Van Duyne, A localized surface plasmon resonance biosensor: first steps toward an assay for Alzheimer's disease, Nano Lett. 4 (2004) 1029-1034.

DOI: 10.1021/nl049670j

Google Scholar

[5] T. Endo, K. Kerman, N. Nagatani, Y. Takamura, E. Tamiya, Label-free detection of peptide nucleic acid–DNA hybridization using localized surface Plasmon resonance based optical biosensor, Anal. Chem. 77 (2005) 6976-6984.

DOI: 10.1021/ac0513459

Google Scholar

[6] E. Petryayeva, U.J. Krull, Localized surface plasmon resonance: Nanostructures, bioassays and biosensing—A review. Analytica Chimica Acta 706 (2011) 8-24.

DOI: 10.1016/j.aca.2011.08.020

Google Scholar

[7] T.R. Jensen, M.D. Malinsky, C.L. Haynes, R.P. Van Duyne, Nanosphere 450 lithography: tunable localized surface plasmon resonance spectra of silver 451 nanoparticles, J. Phys. Chem. B 104 (2000) 10549-10556.

DOI: 10.1021/jp002435e

Google Scholar

[8] McFarland, R.P. Van Duyne, Single silver nanoparticles as real-time optical 453 sensors with zeptomole sensitivity, Nano Lett. 3 (2003) 1057-1062.

DOI: 10.1021/nl034372s

Google Scholar

[9] J. Robertson, Diamond-like amorphous carbon. Materials Science and Engineering R 37 (2002) 129-281.

Google Scholar

[10] A.C. Ferrari, J. Robertson, Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rcv. B 61 (2000) 14095-14107.

DOI: 10.1103/physrevb.61.14095

Google Scholar

[11] Haes, A.J. Van Duyne, R.P., Probing the Long Range Distance Dependence of Noble Metal Nanoparticles Anal. Bioanal. Chem. 379 (2004) 920-930.

DOI: 10.1557/proc-789-n16.9

Google Scholar

[12] K.N. Liou, A Complementary Theory of Light Scattering by Homogeneous Spheres. Applied mathmeatics and computation. 3 (1977) 331-358.

DOI: 10.1016/0096-3003(77)90018-2

Google Scholar