Effect of Selenium on Structure and Electrical Property for Bi0.4Sb1.6Se3xTe3(1-x) Novel Hexagonal Rods

Article Preview

Abstract:

Novel hexagonal rods of Bi0.4Sb1.6Se3xTe3(1-x) (0.0≤x≤1.0) were synthesized successfully through solid-state microwave synthesis. These hexagonal rods were explored using field emission scanning electron microscopy images. The X-ray diffraction results indicate that the powders (0.0≤x≤0.8) can be indexed as the rhombohedral phase, whereas the sample with x=1.0 has an orthorhombic phase structure. The electrical conductivity gradually decreases as Se increased, resulting in an increase in the Seebeck coefficient. Ascribing to the increased Seebeck coefficient for the sample with x=0.8, the maximum power factor is 7.47 mW/mK2 at 373 K.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

80-84

Citation:

Online since:

May 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. G. Kanatzidis, S. D. Mahanti, and T. P. Hogan, Chemistry, Physics and Materials Science of Thermoelectric Materials, second ed., Plenum, New York, 2003.

Google Scholar

[2] G. S. Nolas, J. Sharp, and H. J. Goldsmid, Thermoelectrics, first ed., Springer, New York, 2001.

Google Scholar

[3] M. Christine, W. L. Jonathan and A. A. Jennifer, Rapid solid-state synthesis of binary group15 chalcogenides using microwave irradiation, J. Solid State Chem. 180 (2007) 3262–3270.

DOI: 10.1016/j.jssc.2007.09.001

Google Scholar

[4] Z. Zhou, Y.-J. Chien, C. Uher, Thin-film ferromagnetic semiconductors based on Sb2−xVxTe3 with TC of 177 K, Appl. Phys. Lett. 87 (2005) 112503.

DOI: 10.1063/1.2045561

Google Scholar

[5] A. Kadhim, A. Hmood and H. Abu Hassan, Physical properties of Bi2(Te,Se)3 and Bi2Se1.2Te1.8 prepared using solid-state microwave synthesis, Mater. Lett.65 (2011) 3105-3018.

DOI: 10.1016/j.matlet.2011.06.069

Google Scholar

[6] T. Plechacek, J. Navratil and J. Horak, Free current carrier concentration and point defects in Bi2−xSbxSe3 crystals, J. Solid State Chem. 165 (2002) 35-41.

DOI: 10.1006/jssc.2001.9486

Google Scholar

[7] J. L.Cui, W. J. Xiu, L.D. Mao, P. Z. Ying, L. Jiang and X. Qian, Thermoelectric properties of Agdoped n-type (Bi2Te3)0.9–(Bi2−xAgxSe3)0.1 (x=0–0.4) alloys prepared by spark plasma sintering, J. Solid State Chem. 180 (2007) 1158-1162.

DOI: 10.1016/j.jssc.2006.12.010

Google Scholar

[8] W. Shanyu, X. Wenjie, L. Han and T. Xinfeng, Enhanced performances of melt spun Bi2(Te,Se)3 for n-type thermoelectric legs, Intermetallics 19 (2011) 1024-1031.

DOI: 10.1016/j.intermet.2011.03.006

Google Scholar

[9] H. C. Kim, T. S. Oh and D-B. Hyun, Thermoelectric properties of the p-type Bi2Te3–Sb2Te3–Sb2Se3 alloys fabricated by mechanical alloying and hot pressing, Phys. J. Chem. Solids 61 (2000) 743–749.

DOI: 10.1016/s0022-3697(99)00269-3

Google Scholar