Preparation and Characterization of Polylactic Acid Coating on the Surface of Magnesium Alloy

Article Preview

Abstract:

Magnesium is one of the elements necessary for the body, is the man behind the body’s content of potassium ions within the cell are involved in a series of metabolic processes in vivo, including the formation of bone cells , acceleration of bone healing ability. Resulting from the good mechanical properties and biocompatibility, magnesium alloy is used in medical intervention material, but the high corrosion rate of magnesium alloys is the main drawback to their widespread use, especially in biomedical applications. There is a need for developing new coatings that provide simultaneously corrosion resistance and enhanced biocompatibility. In this work the medical magnesium alloy surface are dipped and coated with polylactic acid, so that obtain a dense uniform polylactic acid coating. And the corrosion resistance of the coating is studied in order to obtain controlled degradable and corrosion resisted magnesium alloy biological material. This paper mainly studies the influence of different concentrations of polylactic acid coating on AZ91D magnesium alloy corrosion resistance. The coated samples were immersed in Hank’s solution and the coating performance was studied by electrochemical impedance spectroscopy and scanning electron microscopy. This research is about the influence of the coating on the corrosion resistance of magnesium alloy through the open circuit potential, polarization curves, electrochemical impedance spectroscopy and Mott-Schottky. The results confirmed that the polylactic acid slow down the corrosion rate of AZ91D magnesium alloys in Hank’s solution. And along with the increase of poly lactic acid concentration, the corrosion resistance of magnesium alloys is improved. There is a wide variation of the corrosion morphology magnesium alloy AZ91D specimens after the surface modification using polylactic acid coating, compared with the unmodified.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

132-136

Citation:

Online since:

March 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Xin Y, Hu T, Chu PK. In vitro studies of biomedical magnesium alloys in a simulated physiological environment: a review. Acta Biomater 2011; 7: 1452–9.

DOI: 10.1016/j.actbio.2010.12.004

Google Scholar

[2] Zomorodian A, Brusciotti F, Fernandes A, Carmezim MJ, Moura e Silva T, Fernandes JCS. Anti-corrosion performance of a new silane coating for corrosion protection of AZ31 magnesium alloy in Hank's solution, Surf Coat Technol 2012; 206: 4368–75.

DOI: 10.1016/j.surfcoat.2012.04.061

Google Scholar

[3] Staiger MP, Pietak AM, Huadmai J, Dias G. Magnesium and its alloys as orthopedic biomaterials: a review. Biomaterials 2006; 27: 1728–34.

DOI: 10.1016/j.biomaterials.2005.10.003

Google Scholar

[4] Witte F. The history of biodegradable magnesium implants: a review. Acta Biomater 2010; 6: 1680–92.

Google Scholar

[5] Witte F, Hort N, Vogt C, Cohen S, Kainer KU, Willumeit R, et al. Degradable biomaterials based on magnesium corrosion. Curr Opin Solid State Mater Sci 2008; 12: 63–72.

DOI: 10.1016/j.cossms.2009.04.001

Google Scholar

[6] Xin Y, Hu T, Chu PK. In vitro studies of biomedical magnesium alloys in a simulated physiological environment: a review. Acta Biomater 2011; 7: 1452–9.

DOI: 10.1016/j.actbio.2010.12.004

Google Scholar

[7] Zeng RC, Dietzel W, Witte F, Hort N, Blawert C. Progress and challenge for magnesium alloys as biomaterials. Adv Eng Mater 2008; 10: B13–4.

DOI: 10.1002/adem.200800035

Google Scholar

[8] Gu XN, Zheng YF, Cheng Y, Zhong SP, Xi TF. In vitro corrosion and biocompatibility of binary magnesium alloys. Biomaterials 2009; 30: 484–98.

DOI: 10.1016/j.biomaterials.2008.10.021

Google Scholar

[9] Thomann M, Krause C, Angrisani N, Bormann D, Hassel T, Windhagen H, et al. Influence of a magnesium-fluoride coating of magnesium-based implants (MgCa0. 8) on degradation in a rabbit model. J Biomed Mater Res Part A 2010; 93A: 1609–19.

DOI: 10.1002/jbm.a.32639

Google Scholar

[10] Xu LP, Pan F, Yu GN, Yang L, Zhang EL, Yang K. In vitro and in vivo evaluation of the surface bioactivity of a calcium phosphate coated magnesium alloy. Biomaterials 2009; 30: 1512–23.

DOI: 10.1016/j.biomaterials.2008.12.001

Google Scholar

[11] Wong HM, Yeung KWK, Lam KO, Tam V, Chu PK, Luk KDK, et al. A biodegradable polymer-based coating to control the performance of magnesium alloy orthopaedic implants. Biomaterials 2010; 31: 2084–96.

DOI: 10.1016/j.biomaterials.2009.11.111

Google Scholar

[12] Witte F, Fischer J, Nellesen J, Crostack HA, Kaese V, Pisch A, et al. In vitro and in vivo corrosion measurements of magnesium alloys. Biomaterials 2006; 27: 1013–8.

DOI: 10.1016/j.biomaterials.2005.07.037

Google Scholar

[13] da Conceicao TF, Scharnagl N, Blawert C, Dietzel W, Kainer KU. Surface modification of magnesium alloy AZ31 by hydrofluoric acid treatment and its effect on the corrosion behaviour. Thin Solid Films 2010; 518: 5209–18.

DOI: 10.1016/j.tsf.2010.04.114

Google Scholar

[14] Pereda MD, Alonso C, Gamero M, del Valle JA, Fernández Lorenzo de Mele M. Comparative study of fluoride conversion coatings formed on biodegradable powder metallurgy Mg: the effect of chlorides at physiological level. Mater Sci Eng C 2011; 31: 858–65.

DOI: 10.1016/j.msec.2011.01.010

Google Scholar

[15] Kirkland NT. Magnesium biomaterials: past, present and future. Corros Eng Sci Technol 2012; 47: 322–8.

Google Scholar

[16] L. Jianrui, G. Yina, H. Weidong, Surf. Coat. Technol. 201 (2006) 1536.

Google Scholar

[17] da Conceicao TF, Scharnagl N, Blawert C, Dietzel W, Kainer KU. Surface modification of magnesium alloy AZ31 by hydrofluoric acid treatment and its effect on the corrosion behaviour. Thin Solid Films 2010; 518: 5209–18.

DOI: 10.1016/j.tsf.2010.04.114

Google Scholar

[18] Yan TT, Tan LL, Xiong DS, Liu XJ, Zhang BC, Yang K. Fluoride treatment and in vitro corrosion behavior of an AZ31B magnesium alloy. Mater Sci Eng C: Mater Biol Appl 2010; 30: 740–8.

DOI: 10.1016/j.msec.2010.03.007

Google Scholar