Investigation of Viscosity Measurements of Molten Fe-Si-B-Nb Alloys

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The properties of Iron-based metallic glasses, such as glass-forming ability and soft magnetic properties, (MGs) have been widely investigated. However, seldom reports are available concerning the properties of these iron-based melts. In the present work, the viscosity of superheated Fe-Si-B-Nb metallic glass forming liquids (MGFLs) was measured by a torsional oscillating viscometer. It has been found that the crucial condition to get viscosity data using graphite crucibles is to reach a superheated degree of at least 250 K for melts prior to measurements. The viscosity increases monotonically with a decrease in temperature before solidification, without distinct changes of dynamic mechanism during cooling. The present work indicates that these iron-based melts are heterogeneous even above the liquidus temperature. This finding helps to understand the melts of iron-based MGs and to improve the production process of iron-based glass ribbons.

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45-51

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March 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Inoue and G. S. Gook, Fe-based ferromagnetic glassy alloys with wide supercooled liquid region, Mater. Trans. JIM 36(1995) 1180-1183.

DOI: 10.2320/matertrans1989.36.1180

Google Scholar

[2] A. Inoue and G. S. Gook, Effect of additional elements (M) on the thermal stability of supercooled liquid in Fe72-xAl5Ga2P11C6B4Mx glassy alloys, Mater. Trans. JIM 37(1996) 32-38.

Google Scholar

[3] Akihisa Inoue and Baolong Shen, Soft magnetic bulk glassy Fe-B-Si-Nb alloys with high saturation magnetization above 1. 5 T, Mater. Trans. JIM 43(2002) 766-769.

DOI: 10.2320/matertrans.43.766

Google Scholar

[4] T. D. Shen and R. B. Schwarz, Bulk ferromagnetic glasses prepared by flux melting and water quenching, Appl. Phys. Lett. 75(1999) 49-51.

DOI: 10.1063/1.124273

Google Scholar

[5] B. L. Shen, H. M. Kimura, A. Inoue and T. Mizushima, Bulk glassy Fe-Co-Ga-P-C-B alloys with high glass-forming ability, high saturation magnetization and good soft magnetic properties, Mater. Trans. JIM 41(2000) 1675-1678.

DOI: 10.2320/matertrans1989.41.1675

Google Scholar

[6] B. L. Shen, H. Koshiba, T. Mizushima and A. Inoue, Bulk amorphous Fe-Ga-P-B-C alloys with a large supercooled liquid region, Mater. Trans. JIM 41(2000) 873-876.

DOI: 10.2320/matertrans1989.41.873

Google Scholar

[7] A. Inoue, T. Zhang, H. Koshiba and A. Makino, New bulk amorphous Fe-(Co, Ni)-M-B (M=Zr, Hf, Nb, Ta, Mo, W) alloys with good soft magnetic properties, J. Appl. Phys. 83(1998) 6326-6328.

DOI: 10.1063/1.367811

Google Scholar

[8] A. Inoue, T. Zhang and A. Takeuchi, Bulk amorphous alloys with high mechanical strength and good soft magnetic properties in Fe-TM-B (TM=IV-VIII group transition metal) system, Appl. Phys. Lett. 71(1997) 464-466.

DOI: 10.1063/1.119580

Google Scholar

[9] S. Pang, T. Zhang, K. Asami and A. Inoue, New Fe-Cr-Mo-(Nb, Ta)-C-B glassy alloys with high glass-forming ability and good corrosion resistance, Mater. Trans. JIM 42(2001) 376-379.

DOI: 10.2320/matertrans.42.376

Google Scholar

[10] Y.Z. Yue, Fictive temperature, cooling rate, and viscosity of glasses, J. Chem. Phys. 120(2004) 8053.

Google Scholar

[11] Chao Zhou, Lina Hu, Qijing Sun et al., Indication of liquid-liquid phase transition in CuZr-based melts, Appl. Phys. Lett. 103(2013) 171904.

DOI: 10.1063/1.4826487

Google Scholar

[12] Caiwei Wang, Lina Hu, Chen Wei et al., Sub-Tg relaxation patterns in Cu-based metallic glasses far from equilibrium, J. Chem. Phys. 141(2014) 164507.

DOI: 10.1063/1.4898695

Google Scholar

[13] C.A. Angell, Formation of glasses from liquids and biopolymers, Science 267(1995) 1924-(1935).

DOI: 10.1126/science.267.5206.1924

Google Scholar

[14] X.F. Bian, B.A. Sun, L.N. Hu et al., Fragility of superheated melts and glass-forming ability in Al-based alloys, Phys. Lett. A 335(2005) 61-67.

DOI: 10.1016/j.physleta.2004.12.018

Google Scholar

[15] Q.G. Meng, J.K. Zhou, H.X. Zheng and J.G. Li, Fragility of superheated melts and glass-forming ability in Pr-based alloys, Scr. Mater. 54(2006) 777-781.

DOI: 10.1016/j.scriptamat.2005.11.023

Google Scholar

[16] Lina Hu, Chao Zhou, C.Z. Zhang, and Y.Z. Yue, Thermodynamic anomaly of the sub-Tg relaxation in hyperquenched metallic glasses, J. Chem. Phys. 138(2013) 174508.

DOI: 10.1063/1.4803136

Google Scholar

[17] J.C. Mauro, Y.Z. Yue, A.J. Ellison et al., Viscosity of glass-forming liquids, Proc. Natl. Acad. Sci. USA 106(2009) 19780-19784.

DOI: 10.1073/pnas.0911705106

Google Scholar

[18] J. Guo and X.F. Bian, A correlation between superheated liquid fragility and supercooled liquid fragility in La- and Sm-based glass-forming alloys, J. Alloy Compd. 504(2010) S205-S207.

DOI: 10.1016/j.jallcom.2010.04.015

Google Scholar

[19] C. Zhou and L.N. Hu, Investigation of viscosity measurements of molten Cu-Zr-Al alloys, Mater. Sci. Forum 745-746(2013) 781.

DOI: 10.4028/www.scientific.net/msf.745-746.781

Google Scholar