Study on Al-Li3AlH6-CaO Composite for Hydrogen Production Performance

Xiang Fei Zhang; Fen Xu; Li Xian Sun; Fang Yu; Chong Zhao

doi:10.4028/www.scientific.net/MSF.852.841

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HomeMaterials Science ForumMaterials Science Forum Vol. 852Study on Al-Li3AlH6-CaO Composite for Hydrogen...

Study on Al-Li₃AlH₆-CaO Composite for Hydrogen Production Performance

Abstract:

The Al-Li₃AlH₆ composite as a promising hydrogen production material has attracted increasing attention. However, the poor stability limits practical application. In this paper, the Al-Li₃AlH₆-CaO composite has been synthesized by ball milling. The results show that the increase of the amount of added CaO can enhance the rate of the hydrogen generation. The rate of the hydrogen generation reaches 40.1 % when the amount of added CaO is 30 wt%, which is due to the fact that the added CaO can destroys the Al₂O₃ films. The influence of amount of added CaO on the corrosion resistant of the Al-Li₃AlH₆-CaO is also investigated. The Al-Li₃AlH₆-CaO with 35 wt% CaO exhibits well corrosion resistant performance, and the hydrogen yield decreases by 22.65 % in 30 days, while the hydrogen yield of the Al-Li₃AlH₆-CaO without CaO drops by 45.4% in 5 days.

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Periodical:

Materials Science Forum (Volume 852)

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841-847

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.852.841

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Online since:

April 2016

Authors:

Xiang Fei Zhang, Fen Xu, Li Xian Sun, Fang Yu, Chong Zhao

Keywords:

Al-Li₃AlH₆-CaO Composite, Corrosion Resistance, Hydrogen Production, Mechanical Ball Milling

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References

[1] H.Z. Wang, D.Y.C. Leung, M.K.H. Leung and M. Ni: Renewable and Sustainable Energy Reviews, Vol. 13 (2009) No. 4, p.845.

Google Scholar

[2] X. Huang, T. Gao, X. Pan, D. Wei, C. Lv, L. Qin and Y. Huang: Journal of Power Sources, Vol. 229(2013) , p.133.

Google Scholar

[3] N. Patel and A. Miotello: International Journal of Hydrogen Energy, Vol. 40 (2015) No. 3, p.1429.

Google Scholar

[4] H.B. Dai, G.L. Ma, H.J. Xia and P. Wang: Energy & Environmental Science, Vol. 4 (2011) No. 6, p.2206.

Google Scholar

[5] J.Y. Uan, M.C. Lin, C.Y. Cho, K.T. Liu and H.I. Lin: International Journal of Hydrogen Energy, Vol. 34 (2009) No. 4, p.1677.

Google Scholar

[6] J. Skrovan, A. Alfantazi and T. Troczynski: Journal of Applied Electrochemistry, Vol. 39 (2009) No. 10, p.1695.

Google Scholar

[7] J.T. Ziebarth, J.M. Woodall, R.A. Kramer and G. Choi: International Journal of Hydrogen Energy, Vol. 36 (2011) No. 9, p.5271.

Google Scholar

[8] H. Luo, J. Liu, X. Pu, J. Liang, Z. Wang, F. Wang, K. Zhang, Y. Peng,; B. Xu, J. Li, X. Yu and J. Ferreira: Journal of the American Ceramic Society, Vol. 94 (2011) No. 11, p.3976.

Google Scholar

[9] M.Q. Fan, F. Xu and L.X. Sun: Energ Fuel, Vol. 21 (2007) No. 4, p.2294.

Google Scholar

[10] M.Q. Fan, Y. Wang, R. Tang, D. Chen, W. Liu, G.L. Tian, C.J. Lv and K.Y. Shu: Renewable Energy, Vol. 60 (2013) , p.637.

Google Scholar

[11] F. Xu, L.X. Sun,; X.F. Lan, H.L. Chu, Y.J. Sun, H.Y. Zhou, F. Li, L.N. Yang, X.L. Si, J. Zhang, S. Walter and Z. Gabelica: International Journal of Hydrogen Energy, Vol. 39 (2014) No. 11, p.5514.

DOI: 10.1016/j.ijhydene.2014.01.154

Google Scholar

[12] T. Wu, F. Xu, L.X. Sun, Z. Cao, H.L. Chu, Y.J. Sun, L. Wang, P.H. Chen, J. Chen,; Y. Pang, Y.J. Zou, S.J. Qiu, C.L. Xiang and H.Z. Zhang: International Journal of Hydrogen Energy, Vol. 39 (2014) No. 20, p.10392.

DOI: 10.1016/j.ijhydene.2014.04.159

Google Scholar

[13] S.S. Liu, Y. Zhang, L.X. Sun, J. Zhang, J.N. Zhao, F. Xu, F and L. Huang: International Journal of Hydrogen Energy, Vol. 35(2010) No. 10, p.4554.

Google Scholar