Well-Designed Spherical Morphology Li1.2Mn0.54Ni0.13Co0.13O2 as Superior Cathode Materials for Lithium-Ion Batteries

Shao Meng Ma; Xian Hua Hou; Yan Ling Huang; Xiao Li Zou; She Jun Hu

doi:10.4028/www.scientific.net/MSF.852.853

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HomeMaterials Science ForumMaterials Science Forum Vol. 852Well-Designed Spherical Morphology...

Well-Designed Spherical Morphology Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ as Superior Cathode Materials for Lithium-Ion Batteries

Abstract:

Li-rich layered cathode materials with an average composition of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ have been successfully synthesized via one-pot facile co-precipitation method. The spherical cathode material and the unconsolidated shape one are obtained by optimizing the experimental condition. The results of electrochemical performance test expose that the spherical cathode material exhibits more excellent cycle ability and rate performance than the unconsolidated one. The initial charge-discharge specific capacities of the spherical cathode are approximately 323.4 mAh g^-1 and 266.4 mAh g^-1, respectively, showing an initial coulombic efficiency of 82.4%. A high discharge capacity of 241.1 mAh g^-1 is maintained with the capacity retention of 90.5% after 50 cycles at a constant current density of 50 mA g^-1 (1 C=250 mAh g^-1).

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Periodical:

Materials Science Forum (Volume 852)

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853-857

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.852.853

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Online since:

April 2016

Authors:

Shao Meng Ma, Xian Hua Hou, Yan Ling Huang, Xiao Li Zou, She Jun Hu

Keywords:

Co-Precipitation Method, Li-Rich Materials, Lithium Ion Battery, Morphology

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References

[1] S.J. Shi, J.P. Tu, Y.Y. Tang, Y.Q. Zhang, X.L. Wang, C.D. Gu: Journal of Power Sources. Vol. 240 (2013), p.140.

Google Scholar

[2] Hyung-Joo Noh, Sungjune Youn, Chong Seung Yoon, Yang-Kook Sun: Journal of Power Sources. Vol. 233(2013), p.121.

Google Scholar

[3] Z.H. Li, T.P. Zhao, X.Y. Zhan, D.S. Gao, Q.Z. Xiao, G.T. Lei: Electrochimica Acta. Vol. 55(2010), p.4594.

Google Scholar

[4] X.Y. Zhang, W.J. Jiang, A. Mauger, Qilu, F. Gendron, C.M. Julien: Journal of Power Sources. Vol. 195(2010), p.1292.

DOI: 10.1016/j.jpowsour.2009.09.029

Google Scholar

[5] J. Li, R. Klopsch, M. c. Stan, S. Nowak, M. Kunze, M. Winter, S. Passerini: Journal of Power Sources. Vol. 196(2011), p.4821.

Google Scholar

[6] Ozan Toprakci, Hatice A.K. Toprakci, Ying Li, Liwen Ji, Leigang Xue, Hun Lee, Shu Zhang, Xiangwu Zhang: Journal of Power Sources. Vol. 241(2013), pp.522-524.

DOI: 10.1016/j.jpowsour.2013.04.155

Google Scholar

[7] K.J. Rosina, M. Jiang, D.L. Zeng, E. Salager, A.S. Best, C.P. Grey, J. Mater: Chem. Vol. 22(2012), p.20602.

Google Scholar

[8] H.B. Ren, X. Li, Z.H. Peng: Electrochim Acta. Vol. 56(2011), p.7088.

Google Scholar

[9] Xiaowei Miao, Yuan Yan, Chunguang Wang, Leilei Cui, Jianhui Fang, Gang Yang: Journal of Power Sources. Vol. 247(2014), p.224.

Google Scholar