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LiBH4 Confined in Nitrogen-Doped Ordered Mesoporous Carbons for Hydrogen Storage

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Abstract:

Nitrogen-doped ordered mesoporous carbon has been synthesized and used to confine LiBH4 to improve its dehydrogenation properties. The carbon has a high BET specific surface up to 448.25 m2/g with pore size centered at 1.2 and 4.1 nm. The effects of ball milling time and speed on de-hydrogenation were investigated. The onset hydrogen desorption temperature of LiBH4 is reduced to 100 °C by addition 40 wt% carbon, and it can release hydrogen of 8.3 wt% at 380 °C. Furthermore, cyclic dehydrogenation is studiedto estimate the stability of the samples in the present work.

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Periodical:

Materials Science Forum (Volume 852)

Pages:

858-863

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.852.858

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Online since:

April 2016

Authors:

Rong Cai, Li Xian Sun, Fen Xu, Yong Jin Zou, Hai Liang Chu

Keywords:

Confinement, Hydrogen Storage, LiBH4, N-Doped Mesoporous Carbons

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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