Microstructure of Z-Phase Strengthened Martensitic Steels: Meeting the 650°C Challenge

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We studied three series of Z-phase strengthened steels using scanning electron microscopy, transmission electron microscopy, and atom probe tomography to reveal the detailed microstructure of these steels. In particular, the phase transformation from M(C,N) to Z-phase (CrMN) was studied. Carbon content in the steels is the governing factor in this transformation. The impact toughness of some test alloys was rather low. This is attributed to the formation of a continuous W-rich film along prior austenite grain boundaries. Cu and C addition to the test alloys changed Laves phase morphology to discrete precipitates and improved toughness dramatically. BN particles were found in some steels. Formation of BN is directly linked to the B concentration in the steels.

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1147-1152

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November 2016

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Uehara, A. Toji, S. Komatsubara, T. Fujita, in: J. Lecomte-Beckers, M. Carton, F. Schubert, P.J. Ennis (Eds. ) Materials for advanced power engineering, Forschungszentrum Jülich GmbH, Liege, Belgium, 2002, pp.1311-1320.

Google Scholar

[2] H.K. Danielsen, J. Hald, VGB PowerTech, Influence of Z-phase on long-term creep stability of martensitic 9 to 12 % Cr steels, 5 (2009) 68-73.

Google Scholar

[3] F. Liu, M. Rashidi, L. Johansson, J. Hald, H.O. Andren, A new 12% chromium steel strengthened by Z-phase precipitates, Scripta Materialia, 113 (2016) 93-96.

DOI: 10.1016/j.scriptamat.2015.10.030

Google Scholar

[4] F. Liu, H. -O. Andrén, Initial study on Z-phase strengthened 9-12% Cr steels by atom probe tomography, 9th Liège Conference on materials for anvanced power engineering, Liège, Belgium, 2010, pp. Paper 12.

Google Scholar

[5] F. Liu, H. -O. Andrén, Effect of Cu addition on the toughness of new Z-phase strengthened 12% Cr steels, EPRI 7th International Conference on Advances in Materials Technology for Fossil Power Plants, Hawaii, USA, (2013).

Google Scholar

[6] M. Rashidi, F. Liu, H. -O. Andrén, Microstructure characterization of two Z-phase strengthened 12% Chromium steels, 10th Liège Conference on Materials for Advanced Power Engineering, Liège, Belgium, (2014).

Google Scholar

[7] A. Cerezo, P.H. Clifton, M.J. Galtrey, C.J. Humphreys, T.F. Kelly, D.J. Larson, S. Lozano-Perez, E.A. Marquis, R.A. Oliver, G. Sha, K. Thompson, M. Zandbergen, R.L. Alvis, Atom probe tomography today, Materials Today, 10 (2007) 36-42.

DOI: 10.1016/s1369-7021(07)70306-1

Google Scholar

[8] F. Liu, H. -O. Andrén, Effects of laser pulsing on analysis of steels by atom probe tomography, Ultramicoscopy, 111 (2011) 633-641.

DOI: 10.1016/j.ultramic.2010.12.012

Google Scholar

[9] A. Golpayegani, F. Liu, H. Svensson, M. Andersson, H. -O. Andrén, Microstructure of a creep resistant 10% chromium steel containing 250 ppm boron, Metallurgical and Materials Transactions A 42 (2011) 940-951.

DOI: 10.1007/s11661-010-0555-1

Google Scholar

[10] K. Sawada, H. Kushima, K. Kimura, Z-phase Formation during Creep and Aging in 9–12 % Cr Heat Resistant Steels, ISIJ International, 46 (2006) 769-775.

DOI: 10.2355/isijinternational.46.769

Google Scholar

[11] H.K. Danielsen, J. Hald, M.A.J. Somers, Atomic resolution imaging of precipitate transformation from cubic TaN to tetragonal CrTaN, Scripta Materialia, 66 (2012) 261-264.

DOI: 10.1016/j.scriptamat.2011.11.005

Google Scholar

[12] F. Abe, Creep rates and strengthening mechanisms in tungsten-strengthened 9Cr steels, Materials Science & Engineering A, A319-321 (2001) 770-773.

DOI: 10.1016/s0921-5093(00)02002-5

Google Scholar

[13] H. Semba, F. Abe, Creep Deformation Behavior and Microstructure in High Boron Containing 9% Cr Ferritic Heat-Resistant Steels in: R. Viswanathan, D. Gandy, K. Coleman (Eds. ) The 4th international conference on advances in materials technology for possil power plants, ASM international, Hilton Head Island, SC, USA, 2004, p.1229.

Google Scholar