Electroplating of Copper on the Continuous Carbon Fibers

Article Preview

Abstract:

Surface metallization of continuous carbon fibers (CFs) can improve the properties of the interface between the CFs and the metal matrix of the metal based composites. In this study, copper was coated on the surface of continuous CFs by electroplating in acidified copper sulfate electrolyte system. The effects of electroplating parameters such as current density, plating time, plating temperature and the pH value of electrolyte solution on the electroplating of the copper thin films on CFs were studied. The scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to determine the microstructure of the copper coatings, and its composition and crystal structure. The thermal gravimetric analysis (TGA) was used to study the thermal stability of the CFs after electroplating. The results showed that high quality copper-coated CFs can be obtained under the optimized plating parameters as follows: the current density 3~4mA/cm2, electroplating time 10~20min, the temperature and the pH value of electrolyte solution 3.0~4.0, 20~30°C respectively. The coatings were uniform and smooth, which were adhered to CFs. XRD patterns indicated that the copper coatings were mainly composed of pure copper. And TGA results identified an increase in thermal stability of the copper coated CFs.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

2205-2213

Citation:

Online since:

June 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Łągiewka M. Mechanical and Tribological Properties of Metal Matrix Composites Reinforced with Short Carbon Fibre. Archives of Metallurgy and Materials. 2014, 59 (2): 707-11.

DOI: 10.2478/amm-2014-0116

Google Scholar

[2] Hashim J, Looney L, Hashmi M. Metal matrix composites: production by the stir casting method. Journal of Materials Processing Technology. 1999, 92: 1-7.

DOI: 10.1016/s0924-0136(99)00118-1

Google Scholar

[3] Chand S. Review carbon fibers for composites. Journal of Materials Science. 2000, 35 (6): 1303-13.

Google Scholar

[4] Park S-J, Cho M-S. Effect of anti-oxidative filler on the interfacial mechanical properties of carbon–carbon composites measured at high temperature. Carbon. 2000, 38 (7): 1053-8.

DOI: 10.1016/s0008-6223(99)00210-9

Google Scholar

[5] Arsenault R, Wang L, Feng C. Strengthening of composites due to microstructural changes in the matrix. Acta metallurgica et materialia. 1991, 39 (1): 47-57.

DOI: 10.1016/0956-7151(91)90327-w

Google Scholar

[6] Metcalfe A. Interface in Metal Matrix Composites, vol. 1. Academic Press, New York; (1974).

Google Scholar

[7] Wang Y-Q, Zhou B-L. Behaviour of coatings on reinforcements in some metal matrix composites. Composites Part A: Applied Science and Manufacturing. 1996, 27 (12): 1139-45.

DOI: 10.1016/1359-835x(96)00072-3

Google Scholar

[8] Diwanji A, Hall I. Fibre and fibre-surface treatment effects in carbon/aluminium metal matrix composites. Journal of materials science. 1992, 27 (8): 2093-100.

DOI: 10.1007/bf01117922

Google Scholar

[9] Tham L, Gupta M, Cheng L. Effect of limited matrix–reinforcement interfacial reaction on enhancing the mechanical properties of aluminium–silicon carbide composites. Acta Materialia. 2001, 49 (16): 3243-53.

DOI: 10.1016/s1359-6454(01)00221-x

Google Scholar

[10] Seong H, Lopez H, Robertson D, Rohatgi P. Interface structure in carbon and graphite fiber reinforced 2014 aluminum alloy processed with active fiber cooling. Materials Science and Engineering: A. 2008, 487 (1): 201-9.

DOI: 10.1016/j.msea.2007.10.081

Google Scholar

[11] Chen H, Alpas A. Wear of aluminium matrix composites reinforced with nickel-coated carbon fibres. Wear. 1996, 192 (1): 186-98.

DOI: 10.1016/0043-1648(95)06795-7

Google Scholar

[12] Hua Z, Liu Y, Yao G, Wang L, Ma J, Liang L. Preparation and characterization of nickel-coated carbon fibers by electroplating. Journal of materials engineering and performance. 2012, 21 (3): 324-30.

DOI: 10.1007/s11665-011-9958-4

Google Scholar

[13] Vidal-Setif M, Lancin M, Marhic C, Valle R, Raviart J-L, Daux J-C, et al. On the role of brittle interfacial phases on the mechanical properties of carbon fibre reinforced Al-based matrix composites. Materials Science and Engineering: A. 1999, 272 (2): 321-33.

DOI: 10.1016/s0921-5093(99)00487-6

Google Scholar

[14] Warrier S, Blue C, Lin R. Control of interfaces in Al-C fibre composites. Journal of materials science. 1993, 28 (3): 760-8.

Google Scholar

[15] Yang H, Gu M, Jiang W, Zhang G. Interface microstructure and reaction in Gr/Al metal matrix composites. Journal of materials science. 1996, 31 (7): 1903-7.

DOI: 10.1007/bf00372206

Google Scholar

[16] Lin RY. Interface evolution in aluminum matrix composites during fabrication. Key Engineering Materials; Trans Tech Publ; 1995. pp.507-22.

DOI: 10.4028/www.scientific.net/kem.104-107.507

Google Scholar

[17] Rasmussen FE, Ravnkilde JT, Tang PT, Hansen O, Bouwstra S. Electroplating and characterization of cobalt–nickel–iron and nickel–iron for magnetic microsystems applications. Sensors and Actuators A: Physical. 2001, 92 (1): 242-8.

DOI: 10.1016/s0924-4247(01)00556-8

Google Scholar

[18] Ning Z-H, He Y-D. Rapid electroplating of Cu coatings by mechanical attrition method. Transactions of Nonferrous Metals Society of China. 2008, 18 (5): 1100-6.

DOI: 10.1016/s1003-6326(08)60188-0

Google Scholar

[19] Zhang Z, Leng W, Cai Q, Cao F, Zhang J. Study of the zinc electroplating process using electrochemical noise technique. Journal of electroanalytical Chemistry. 2005, 578 (2): 357-67.

DOI: 10.1016/j.jelechem.2005.01.029

Google Scholar

[20] Abe H, Yoshii K, Nishida K, Imai M, Kitazawa H. Electroplating of the superconductive boride MgB 2 from molten salts. Journal of Physics and Chemistry of Solids. 2005, 66 (2): 406-9.

DOI: 10.1016/j.jpcs.2004.06.051

Google Scholar

[21] Datta M, Landolt D. Fundamental aspects and applications of electrochemical microfabrication. Electrochimica acta. 2000, 45 (15): 2535-58.

DOI: 10.1016/s0013-4686(00)00350-9

Google Scholar

[22] Ahmed A-MM, Abdel-Rahman AA-H, El Adl AF. Electroplating of Copper in the Presence of 5, 6-Dihydropyrimidine-2-(1H)-thione, 2-Methylthiopyrimidine-4-(1H)-one, 2-Thiopyrimidine-4- (1H)-ones, and 2, 4-Pyrimidine (1H, 3H)-dione Derivatives as Organic Additives. Journal of Dispersion Science and Technology. 2011, 32 (3): 453-63.

DOI: 10.1080/01932690903232279

Google Scholar

[23] Grujicic D, Pesic B. Electrodeposition of copper: the nucleation mechanisms. Electrochimica Acta. 2002, 47 (18): 2901-12.

DOI: 10.1016/s0013-4686(02)00161-5

Google Scholar

[24] Park S-J, Seo M-K, Lee Y-S. Surface characteristics of fluorine-modified PAN-based carbon fibers. Carbon. 2003, 41 (4): 723-30.

DOI: 10.1016/s0008-6223(02)00384-6

Google Scholar

[25] Ko TH, Lin CH, Ting HY. Structural changes and molecular motion of polyacrylonitrile fibers during pyrolysis. Journal of applied polymer science. 1989, 37 (2): 553-66.

DOI: 10.1002/app.1989.070370220

Google Scholar