TTT-Diagram of Intermetallic Phases Formation in Heat-Resistant Titanium Alloys

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The silicides and aluminides particles precipitation in near α-and two-phase (α + β) titanium – alloys has been investigated. It is shown that in Ti-Al-Si-Zr alloys three different types of particles are precipitated: (Ti,Zr)5Si3 (S1), (Ti,Zr)6Si3 (S2), (Ti,Zr)2Si (S3). The types of precipitated particles depend on the heat treatment modes and an alloying elements ratio. The investigation of silicide particles influence on the mechanical properties of the alloys has shown that silicides S1 reduced viscosity characteristics. While silicides S2 and S3 were found to reduce the heat resistance due to the depletion of solid solution by Al and Si and to impede the formation of α2 - phase particles. Microstructural investigation has been performed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The orientation relationships between silicides and matrix phase were identified by electron diffraction. Based on obtained results the schematic TTT-diagram of intermetallic phases formation has been suggested.

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67-73

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September 2017

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