Efficient Micro-Arc Oxidation Technology for As-Cast AZ80 Magnesium Alloy

Article Preview

Abstract:

A new efficient micro-arc oxidation technology was developed for AZ80 magnesium alloy, the treating time was shorten to 3 min compared to the conventional micro-arc oxidation process. The surface morphologies and cross section morphology of the coatings were analyzed by scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS). The corrosion behavior and process of the coatings were investigated with potentiodynamic polarization tests and salt spry tests. The research results show that a 4 μm thick oxide film grew rapidly on the surface of AZ80 magnesium alloy under the special prepared electrolyte and high density current. The corrosion resistance of ceramic coating prepared by the new technology was greatly improved for four order of magnitude and it was mainly consisted of dense layer, the coated samples exhibit excellent corrosion resistance not only in the potentiodynamic polarization tests but also in the long term corrosion tests.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

406-415

Citation:

Online since:

February 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Wang L, Mostaed E, Cao X, et al. Effects of texture and grain size on mechanical properties of AZ80 magnesium alloys at lower temperatures[J]. Materials & Design, 89 (2016) 1-8.

DOI: 10.1016/j.matdes.2015.09.153

Google Scholar

[2] Cui X J, Li M T, Yang R S, et al. Structure and properties of a duplex coating combining micro-arc oxidation and baking layer on AZ91D Mg alloy[J]. Applied Surface Science, (2016) 363: 91-100.

DOI: 10.1016/j.apsusc.2015.10.236

Google Scholar

[3] Xiong Y, Hu Q, Hu X, et al. Microstructure and corrosion resistance of Ti 3 O 5-HA bio-ceramic coating fabricated on AZ80 magnesium alloy[J]. Surface and Coatings Technology, (2017).

DOI: 10.1016/j.surfcoat.2017.06.055

Google Scholar

[4] Xiong Y, Hu Q, Song R, et al. LSP/MAO composite bio-coating on AZ80 magnesium alloy for biomedical application[J]. Materials Science and Engineering: C, 75 (2017) 1299-1304.

DOI: 10.1016/j.msec.2017.03.003

Google Scholar

[5] Tan C, Zhu H, Kuang T, et al. Laser cladding Al-based amorphous-nanocrystalline composite coatings on AZ80 magnesium alloy under water cooling condition[J]. Journal of Alloys and Compounds, 690 (2017) 108-115.

DOI: 10.1016/j.jallcom.2016.08.082

Google Scholar

[6] Liu C, Liang J, Zhou J, et al. Characterization and corrosion behavior of plasma electrolytic oxidation coated AZ91-T6 magnesium alloy[J]. Surface and Coatings Technology, 304 (2016) 179-187.

DOI: 10.1016/j.surfcoat.2016.07.021

Google Scholar

[7] Yang W, Wang J, Xu D, et al. Microstructure and properties of duplex coatings on magnesium alloy[J]. Surface Engineering, 32(8) (2016) 601-606.

DOI: 10.1080/02670844.2015.1108049

Google Scholar

[8] Golshirazi A, Kharaziha M, Golozar M A. Polyethylenimine/kappa carrageenan: Micro-arc oxidation coating for passivation of magnesium alloy[J]. Carbohydrate Polymers, 167 (2017) 185-195.

DOI: 10.1016/j.carbpol.2017.03.025

Google Scholar

[9] Paksoy A H, Muhaffel F, Koca M, et al. Formation of a corrosion-resitance alumina coating on a 6061 aluminum alloy uning a combination of micro-arc oxidation and sealing treatments[J]. Materiali in tehnologije, 51(1) (2017) 117-121.

DOI: 10.17222/mit.2015.302

Google Scholar

[10] Fidan S, Muhaffel F, Riool M, et al. Fabrication of oxide layer on zirconium by micro-arc oxidation: Structural and antimicrobial characteristics[J]. Materials Science and Engineering: C, 71 (2017) 565-569.

DOI: 10.1016/j.msec.2016.11.035

Google Scholar

[11] Chen S, Tu J, Hu Q, et al. Corrosion resistance and in vitro bioactivity of Si-containing coating prepared on a biodegradable Mg-Zn-Ca bulk metallic glass by micro-arc oxidation[J]. Journal of Non-Crystalline Solids, 456 (2017) 125-131.

DOI: 10.1016/j.jnoncrysol.2016.11.011

Google Scholar

[12] Tang H, Gao Y. Preparation and characterization of hydroxyapatite containing coating on AZ31 magnesium alloy by micro-arc oxidation[J]. Journal of Alloys and Compounds, 688 (2016) 699-708.

DOI: 10.1016/j.jallcom.2016.07.079

Google Scholar

[13] Hui J Z. The study of ceramic on aluminum-magnesium alloy surface treated by micro-arc oxidation under different electrical parameters[D], Chang'an University, (2006).

Google Scholar

[14] Xue W B, Chen Y F, Li Y L, etal. Surface protection of friction stir welding joint for AZ31 magnesium alloy coated by micro-arc oxidation[J]. Journal of Materials Engineering, 12 (2013) 1-6.

Google Scholar

[15] Cui X, Lin X, Liu C, et al. Fabrication and corrosion resistance of a hydrophobic micro-arc oxidation coating on AZ31 Mg alloy[J]. Corrosion Science, 90 (2015) 402-412.

DOI: 10.1016/j.corsci.2014.10.041

Google Scholar

[16] Chen Y, Zhou J, Liu H, et al. Overall micro-arc oxidation treatment for AZ31B–6061 magnesium–aluminium dissimilar metal connecting parts[J]. Corrosion Engineering, Science and Technology, (2017) 1-6.

DOI: 10.1080/1478422x.2017.1330800

Google Scholar

[17] Shokouhfar M, Allahkaram S R. Formation mechanism and surface characterization of ceramic composite coatings on pure titanium prepared by micro-arc oxidation in electrolytes containing nanoparticles[J]. Surface and Coatings Technology, 291 (2016).

DOI: 10.1016/j.surfcoat.2016.03.013

Google Scholar

[18] Cui L Y, Zeng R C, Guan S K, et al. Degradation mechanism of micro-arc oxidation coatings on biodegradable Mg-Ca alloys: The influence of porosity[J]. Journal of Alloys and Compounds, 695 (2017) 2464-2476.

DOI: 10.1016/j.jallcom.2016.11.146

Google Scholar

[19] Zhang Z, Zhang Y, Zhang L, et al. Application of Micro-arc Oxidation Technology in die magnesium alloy wheels in mass production[J]. Key Engineering Materials, (2016) 667.

DOI: 10.4028/www.scientific.net/kem.667.15

Google Scholar

[20] Tang H, Han Y, Wu T, et al. Synthesis and properties of hydroxyapatite-containing coating on AZ31 magnesium alloy by micro-arc oxidation[J]. Applied Surface Science, 400 (2017) 391-404.

DOI: 10.1016/j.apsusc.2016.12.216

Google Scholar

[21] Cui L Y, Gao S D, Li P P, et al. Corrosion Science, 118 (2017) 84-95.

Google Scholar

[22] Cui X, Yang R, Liu C, et al. Structure and corrosion resistance of modified micro-arc oxidation coating on AZ31B magnesium alloy[J]. Transactions of Nonferrous Metals Society of China, 26(3) (2016) 814-821.

DOI: 10.1016/s1003-6326(16)64172-9

Google Scholar

[23] Laleh M, Kargar F, Rouhaghdam A S. Investigation of rare earth sealing of porous micro-arc oxidation coating formed on AZ91D magnesium alloy[J]. Journal of rare earths, 30(12) (2012) 1293-1297.

DOI: 10.1016/s1002-0721(12)60223-3

Google Scholar

[24] Wang Z, Li Q, She Z, et al. Facile and fast fabrication of superhydrophobic surface on magnesium alloy[J]. Applied Surface Science, 271 (2013) 182-192.

DOI: 10.1016/j.apsusc.2013.01.158

Google Scholar

[25] Liu Y, Yin X, Zhang J, et al. A electro-deposition process for fabrication of biomimetic super-hydrophobic surface and its corrosion resistance on magnesium alloy[J]. Electrochimica Acta, 125 (2014) 395-403.

DOI: 10.1016/j.electacta.2014.01.135

Google Scholar