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HomeMaterials Science ForumMaterials Science Forum Vol. 960Fast Activating Persulfate by Crystallization of...

Fast Activating Persulfate by Crystallization of Fe-Based Metallic Glasses with External Energy

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Abstract:

Very recently, crystallization of metallic glasses (MGs) has presented promising properties in the catalytic field. This work has investigated enhanced catalytic performance of crystallized Fe₇₈Si₉B₁₃ ribbons for fast activating persulfate (PS) with assistance of UV-vis light and heat. The ribbons were obtained by annealing at 750°C (Fe-A750) and cibacron brilliant yellow 3G-P (BY 3G-P) dye was used as pollutant. The results indicated that UV-vis light had limited capability to enhance PS activation efficiency by crystallized ribbons while the reaction rate using heat at 65°C was 7.5 times higher than at 25°C, suggesting an advanced performance with heat assistance of Fe-A750 ribbons. Activation energy ∆E for Fe-A750 was measured as 44.5 kJ mol^-1. In addition, 5 times reusability could be achieved for Fe-A750 ribbons under 45°C without catalytic decay. The surface morphologies of glassy ribbons, as-annealed Fe-A750 ribbons, HCl-treated Fe-A750 ribbons and after-reused Fe-A750 ribbons have also been systematically studied. This work provides a novel clue to promote applicability of novel crystallized ribbons from MGs.

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Materials for Modern Technologies V

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Periodical:

Materials Science Forum (Volume 960)

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200-206

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https://doi.org/10.4028/www.scientific.net/MSF.960.200

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Online since:

June 2019

Authors:

Shunxing Liang, Lai Chang Zhang*

Keywords:

Crystallization, Electron Transfer, Metallic Glasses, Persulfate, Reusability

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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