Lotus Leaf Derived Natural Dye as Sensitizer and Biochar as Counter Electrode for Dye-Sensitized Solar Cells

Article Preview

Abstract:

Natural dyes were obtained from lotus leaf by ethanol extraction, and biochar was prepared by one-step pyrolysis in this study. The UV-Vis spectrum of lotus leaf derived natural dye indicated that it had good light absorption performance. The energy conversion efficiency (PCE) of dye-sensitized solar cell (DSSC) with the natural dye as sensitizer and platinum as counter electrode was 0.36%, and the filling factor was as high as 0.66. Owing to its relatively rich pore structures and glassy carbon materials, the biochar showed its good catalytic performance, which made the PCE of DSSC reach 1.42% when the biochar as counter electrode and N719 as sensitizer. Meanwhile, the PCE achieved 0.15% when lotus leaf derived natural dye as sensitizer and biochar as counter electrode simultaneously. This study has realized the full utilization of biomass in dye-sensitized solar cells, providing the possibility for preparation of low-cost and high-efficiency DSSC.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

884-892

Citation:

Online since:

May 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Yella A, Lee H W, Tsao H N, et al. Porphyrin-sensitized solar cells with cobalt (II/III)–based redox electrolyte exceed 12 percent efficiency[J]. Science, 2011, 334(6056): 629-634.

DOI: 10.1126/science.1209688

Google Scholar

[2] Zhou H, Wu L, Gao Y, et al. Dye-sensitized solar cells using 20 natural dyes as sensitizers[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2011, 219(2-3): 188-194.

DOI: 10.1016/j.jphotochem.2011.02.008

Google Scholar

[3] Ma T, Yun S. Dye-sensitized solar cells: theoretical basis to technical application[M]. Chemical Industry Press, (2013).

Google Scholar

[4] Wongcharee K, Meeyoo V, Chavadej S. Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers[J]. Solar Energy Materials and Solar Cells, 2007, 91(7): 566-571.

DOI: 10.1016/j.solmat.2006.11.005

Google Scholar

[5] Ludin N A, Mahmoud A M A A, Mohamad A B, et al. Review on the development of natural dye photosensitizer for dye-sensitized solar cells[J]. Renewable and Sustainable Energy Reviews, 2014, 31: 386-396.

DOI: 10.1016/j.rser.2013.12.001

Google Scholar

[6] Hwang I, Yong K. Counter Electrodes for Quantum‐Dot‐Sensitized Solar Cells[J]. ChemElectroChem, 2015, 2(5): 634-653.

DOI: 10.1002/celc.201402405

Google Scholar

[7] Du Z, Pan Z, Fabregat-Santiago F, et al. Carbon counter-electrode-based quantum-dot-sensitized solar cells with certified efficiency exceeding 11%[J]. The journal of physical chemistry letters, 2016, 7(16): 3103-3111.

DOI: 10.1021/acs.jpclett.6b01356

Google Scholar

[8] Jiao S, Du J, Du Z, et al. Nitrogen-Doped Mesoporous Carbons as Counter Electrodes in Quantum Dot Sensitized Solar Cells with a Conversion Efficiency Exceeding 12[J]. Journal of Physical Chemistry Letters, 2017, 8(3):559-564.

DOI: 10.1021/acs.jpclett.6b02864

Google Scholar

[9] Deng S, Deng Z, Fan Y, et al. Isolation and purification of three flavonoid glycosides from the leaves of Nelumbo nucifera (Lotus) by high-speed counter-current chromatography[J]. Journal of chromatography B, 2009, 877(24): 2487-2492.

DOI: 10.1016/j.jchromb.2009.06.026

Google Scholar

[10] Xu S, Liu C, Wiezorek J. 20 renewable biowastes derived carbon materials as green counter electrodes for dye-sensitized solar cells[J]. Materials Chemistry and Physics, 2018, 204: 294-304.

DOI: 10.1016/j.matchemphys.2017.10.056

Google Scholar

[11] Lim A, Kumara N, Tan A L, et al. Potential natural sensitizers extracted from the skin of Canarium odontophyllum fruits for dye-sensitized solar cells[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, 138: 596-602.

DOI: 10.1016/j.saa.2014.11.102

Google Scholar

[12] Narayan M, Raturi A. Investigation of some common Fijian flower dyes as photosensi-tizers for dye sensitized solar cellsabstract[J]. Applied Solar Energy, 2011, 47(2): 112.

DOI: 10.3103/s0003701x11020149

Google Scholar

[13] Hao S, Wu J, Huang Y, et al. Natural dyes as photosensitizers for dye-sensitized solar cell[J]. Solar energy, 2006, 80(2): 209-214.

DOI: 10.1016/j.solener.2005.05.009

Google Scholar

[14] Narayan M R. Dye sensitized solar cells based on natural photosensitizers[J]. Renewable and Sustainable Energy Reviews, 2012, 16(1): 208-215.

DOI: 10.1016/j.rser.2011.07.148

Google Scholar

[15] Wongcharee K, Meeyoo V, Chavadej S. Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers[J]. Solar Energy Materials and Solar Cells, 2007, 91(7): 566-571.

DOI: 10.1016/j.solmat.2006.11.005

Google Scholar

[16] Polo A S, Itokazu M K, Iha N Y M. Metal complex sensitizers in dye-sensitized solar cells[J]. Coordination Chemistry Reviews, 2004, 248(13-14): 1343-1361.

DOI: 10.1016/j.ccr.2004.04.013

Google Scholar

[17] Hemalatha K V, Karthick S N, Raj C J, et al. Performance of Kerria japonica and Rosa chinensis flower dyes as sensitizers for dye-sensitized solar cells[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2012, 96: 305-309.

DOI: 10.1016/j.saa.2012.05.027

Google Scholar

[18] Qu S, Wang X, Lu Q, et al. A Biocompatible Fluorescent Ink Based on Water-Soluble Luminescent Carbon Nanodots[J]. Angewandte Chemie International Edition, 2012, 51(49):12215-12218.

DOI: 10.1002/anie.201206791

Google Scholar

[19] Shereema R M, Sankar V, Raghu K G, et al. One step green synthesis of carbon quantum dots and its application towards the bioelectroanalytical and biolabeling studies[J]. Electrochimica Acta, 2015, 182: 588-595.

DOI: 10.1016/j.electacta.2015.09.145

Google Scholar

[20] Jiang Q W, Li G R, Wang F, et al. Highly ordered mesoporous carbon arrays from natural wood materials as counter electrode for dye-sensitized solar cells[J]. Electrochemistry Communications, 2010, 12(7):924-927.

DOI: 10.1016/j.elecom.2010.04.022

Google Scholar

[21] Chou C S, Chen C Y, Lin S H, et al. Preparation of TiO2 /bamboo-charcoal-powder composite particles and their applications in dye-sensitized solar cells[J]. Advanced Powder Technology, 2015, 26(3):711-717.

DOI: 10.1016/j.apt.2014.12.013

Google Scholar

[22] Biochar production from date palm waste: Charring temperature induced changes in composition and surface chemistry[J]. Journal of Analytical and Applied Pyrolysis, 2015, 115:392-400.

DOI: 10.1016/j.jaap.2015.08.016

Google Scholar

[23] Moisés Frías, Savastano H, Villar E, et al. Characterization and properties of blended cement matrices containing activated bamboo leaf wastes[J]. Cement and Concrete Composites, 2012, 34(9):1019-1023.

DOI: 10.1016/j.cemconcomp.2012.05.005

Google Scholar

[24] Xu S, Luo Y, Zhong W. Investigation of catalytic activity of glassy carbon with controlled crystallinity for counter electrode in dye-sensitized solar cells[J]. Solar Energy, 2011, 85(11):2826-2832.

DOI: 10.1016/j.solener.2011.08.014

Google Scholar