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HomeNano Hybrids and CompositesNano Hybrids and Composites Vol. 43Structure and Characteristics of Opal - Bi12GeO20...

Structure and Characteristics of Opal - Bi₁₂GeO₂₀ and Opal - NaBi(MoO₄)₂ Nanocrystalline Composites

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Abstract:

In this work we investigate and analyze phase composition and structure parameters of the nanocomposites obtained by the melt-based impregnation of porous opal matrices with dielectrics prospective for optoelectronics applications Bi₁₂GeO₂₀ and NaBi (MoO₄)₂. The embedded material is formed inside opal pores as nanocrystals with an average linear size not exceeding 50 nm and modified lattice parameters. In the case of impregnating opals with Bi₁₂GeO₂₀, new additional compounds are produced and transformation of opal matrix from amorphous to crystalline state is observed. These effects are discussed in the framework of the interaction of bismuth cations with the surface of the 285 nm SiO₂ particles that compose opal matrix. No stoichiometry deviations and new phases are detected in “opal-NaBi (MoO₄)₂” composite.

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8th International Materials Science Conference HighMatTech-2023

Nano Hybrids and Composites Vol. 43

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Periodical:

Nano Hybrids and Composites (Volume 43)

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39-45

DOI:

https://doi.org/10.4028/p-H8L8po

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Online since:

April 2024

Authors:

Mykhailo Derhachov*, Vasyl Moiseienko, Bilal Abu Sal, Angela Latyshova

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Active Dielectrics, Lattice Parameters, Nanocrystals, Opal Matrix, Raman Spectra

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© 2024 Trans Tech Publications Ltd. All Rights Reserved

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