Adsorption Characteristics of Uranyl Ions on Carboxymethylated Polyethyleneimine (CM-PEI) / Activated Carbon Composites

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Abstract:

We present the adsorption characteristics of uranyl ions on a new and innovative composite which was composed of a carboxymethylated polyethyleneimine (CM-PEI) and an activated carbon (F400) with a nanopore less than 2 nm in diameter. In this study, we examined the adsorption phenomena of uranyl ions on the CM-PEI/F400 composite and evaluated the adsorption data using various isotherm models. It was found that the adsorption of uranyl ions on the CM-PEI/F400 composite obeys the Langmuir isotherm model. In addition, it was observed that pH of solutions had great influence on the adsorption capacity of uranyl ions on the CM-PEI/F400 composite. Specially, the adsorption capacity of uranyl ions was linearly increased with an increase of pH at pH > 3.0.

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Solid State Phenomena (Volumes 124-126)

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1257-1260

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June 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] K. E. Geckler and K. Volchek: Environ. Sci. Tech. Vol. 30 (1996), p.725.

Google Scholar

[2] D. Leroy, L. Martinot, P. Mignonsin, D. Strivay, G. Weber, G. Weber, C. Jérôme and R. Jérôme: J. Appl. Poly. Sci. Vol. 88 (2003), p.352.

DOI: 10.1002/app.12028

Google Scholar

[3] E. Guibal, I. Saucedo, J. Roussy and P. L. Choirec: React. Polym. Vol. 23, (1994), p.147.

Google Scholar

[4] M. Chanda and G.L. Rempel: React. Polym. Vol. 25, (1995), p.25.

Google Scholar

[5] A. Denizli, S. Senel, G. Alsancak, N. Tüzmen and R. Say: React. Funct. Polym. Vol. 55, (2003), p.121.

Google Scholar

[6] I. Langmuir: J. Am. Chem. Soc. Vol. 38, (1916), p.2221.

Google Scholar

[7] H.M.F. Freundlich: Z. Phys. Chem. Vol. 57, (1906), p.385.

Google Scholar

[8] S.J. Allen, G. Mckay and J.F. Porter: J. Colloid Interface. Sci. Vol. 280, (2004), pp.322-0. 0 0. 3 0. 6 0. 9 1. 2 1. 5 qe (mg of U(VI) / g of composite) pH.

Google Scholar