Deposition and Electrical Resistivity of Oxygen-Deficient Tin Oxide Films Prepared by RF Magnetron Sputtering at Different Powers

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A series of oxygen-deficient tin oxide thin films were deposited by radio frequency magnetron sputtering a sintered tin oxide ceramic target under pure argon atmosphere at different sputtering powers (80-160 w) under the based pressure of no more than 2.0×10-4 Pa, sputtering pressure of 2.0 Pa and deposition time of 20 min. It was revealed that all the as-deposited films were oxygen-deficient tin oxide films, and the main defect in films was oxygen vacancy (VO), whose concentration gradually decreased with the increase of sputtering power. The films prepared at a power of no more than 120 w were amorphous, and as the sputtering power increased to 140 and 160 w, the deposited thin films exhibited polycrystalline characteristics with (110), (101) and (211) diffraction peaks of tin oxide. The grain size, deposition rate as well as thickness of the obtained films rose up with increasing sputtering power. In addition, as the sputtering power raised, the electrical resistivity of the films increased, due to the electron conducting mechanism controlled by VO in the samples.

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Solid State Phenomena (Volume 281)

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504-509

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August 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] S.S. Pan, C. Ye, X.M. Teng, et al., Localized exciton luminescence in nitrogen-incorporated SnO2 thin films, Appl. Phys. Lett. 89 (2006) 251911.

DOI: 10.1063/1.2416070

Google Scholar

[2] J.G. Song, L. Hua, Q. Shen, et al., Synthesis and characterization of SnO2nano-cystalline for dye sensitized solar cells,Key Eng. Mater. 602-603 (2014) 876-879.

DOI: 10.4028/www.scientific.net/kem.602-603.876

Google Scholar

[3] D.X. Zhou, L. Gan, Q.Y. Fu, et al., Gas sensing performance of macroporous SnO2 thin film prepared by using carbonaceous polysaccharide microspheres as pore-forming agent, Key Eng. Mater. 543 (2013) 121-124.

DOI: 10.4028/www.scientific.net/kem.543.121

Google Scholar

[4] J. Ni, X. Zhao, X. Zheng, et al., Electrical, structural, photoluminescence and optical properties of p-type conducting, antimony-doped SnO2 thin films, Acta Mater. 57 (2009) 278–285.

DOI: 10.1016/j.actamat.2008.09.013

Google Scholar

[5] Q. Wang, C.B. Wang, C. C. lv, et al.,Electrical conducting and mechanism of oxygen-deficient tin oxide films deposited by RF magnetron sputtering at various O2/Ar ratios, Surf. Rev. Lett. 25 (2017) 1850093.

DOI: 10.1142/s0218625x18500932

Google Scholar

[6] Y. Wang, Z.J. Peng, Q. Wang, et al., Composition, structure and electrical resistivity of ZnO1-x films deposited by RF magnetron sputtering under various O2/Ar gas ratios, Key Eng. Mater. 697(2016) 723-726.

DOI: 10.4028/www.scientific.net/kem.697.723

Google Scholar

[7] S.S. Chang, S.O. Yoon, H.J. Park, Characteristics of SnO2annealed in reducing atmosphere, Ceram. Int. 31 (2005) 405-410.

Google Scholar

[8] D. Cai, Y. Su, Y.Q. Chen, et al., Synthesis and photoluminescence properties of novelSnO2asterisk-like nanostructures, Mater. Lett. 59 (2005) 1984-(1988).

Google Scholar

[9] A.S. Reddy, N.M. Figueiredo, A. Cavaleiro, Pulsed direct current magnetron sputtered nanocrystalline tin oxide films, Appl. Surf. Sci. 258 (2012) 8902-8907.

DOI: 10.1016/j.apsusc.2012.05.112

Google Scholar

[10] Q.H. Wu, J. Song, J.Y. Kang, et al., Nano-particle thin films of tin oxides, Mater. Lett. 61 (2007) 3679-3684.

DOI: 10.1016/j.matlet.2006.12.016

Google Scholar

[11] J. Song, M.Z. Cai, Q.F. Dong, et al., Structural and electrochemical characterization of SnOx thin films for Li-ion microbattery, Electrochim.Acta 54 (2009) 2748-2753.

DOI: 10.1016/j.electacta.2008.11.026

Google Scholar