Synthesis of some New Lariat Ethers as Molecular Motors

Abstract:

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the term "nanomotors" refers macromolecules that consume energy in order to perform certain specific cations. nanomachines could play a major role in the future of electronics, medicine and communications. The sulfoxide (1) was prepared by reaction p-cresol with SOCl2 in 65%, bisphonle (2) was prepared with reduction compound (1). Treatment of bisphenole (2) with methyl chloroacetate at refluxed gave dimethyl ester (3) in 98% yield. Macrocycle (4) in 70% yield was prepared by diamidation of diester (3) with diethylentriamine, Lariat ethers (5) and (6) were synthesized by reaction of macrocyle (4) with decasanoylechloride and ecasonoylechloride in 49% and 45% yield.

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Periodical:

Edited by:

Wu Fan

Pages:

3293-3296

DOI:

10.4028/www.scientific.net/AMM.110-116.3293

Citation:

A. G. Ebadi and S. Alami, "Synthesis of some New Lariat Ethers as Molecular Motors", Applied Mechanics and Materials, Vols. 110-116, pp. 3293-3296, 2012

Online since:

October 2011

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$35.00

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