Advanced Materials Research Vol. 1085

Abstract: A method to modify polymer surface properties responsible for wettability and surface free energy has been proposed. Plasma-based chemical modification of polymer surfaces with gas discharges allows adjusting their functional properties. The main changes in polymer wettability occur within short-term exposure of polymer surfaces to pulsed plasma at atmospheric pressure (1-60 sec). The contact angle values for the modified polymers depend on the gaseous medium and the conditions of the plasma processing. Changing the power, the pulse repetition rate and plasma exposure time allow controlling the free surface energy, making the surface either hydrophobic or hydrophilic.

Abstract: The paper is devoted to studying the stability of of dispersed systems (DS) of nanoparticles (NP) of nickel (nNi), platinum (nPt), titanium dioxide (nTiO2), zinc oxide, multicomponent nanopowder (MNP) and multi-walled carbon nanotubes (MWCNT), formed basing on the growth media used in bioassay with application of aquatics: bacterial test-cultures Ecolum, Photobacterium phosphoreum and Escherihia coli, unicellular algae Chlorella vulgaris Beijer, infusoria Paramecium caudatum, cladocera Daphnia magna Straus and Ceriodaphnia affinis, fish Danio rerio. In the process of establishing a test-system the increase in the initial nanosubstance concentration of more than 5 mg/l results in the increase in the speed of aggregation of NP into DS and the decrease in their final concentration. We suggest the variants of estimation of effective concentration of NP in long-term biotesting.

Abstract: Structural properties of porous TiNi-based materials produced by SHS method and sintering have been investigated. The material having different pore wall surface topography, porosity and pore size distribution was shown to be produced depending on the powder metallurgy method for porous TiNi-based alloy. All the materials having porosity of 55-70%, mean pore size 90-150 μm, as well as normal pore size distribution are most preferable. Ultimate strength and breaking point were determined to depend on porosity, pore size distribution, pore intersections and phase chemical composition of the material. Strength properties of the sintered alloy are twice as much compared to the SHS-produced ones due to homogeneity of its macrostructure, low chemical heterogeneity and TiNi₃ precipitations strengthening the TiNi matrix.

Abstract: Methylglyoxal (MG) – is a high reactive α- oxoaldehyde, which can be synthesized through various biochemical processes in vivo. MG is capable of interacting with nucleophilic groups of proteins, lipids and nucleic acids which leads to their glycation. Covalent compounds that formed in this process were named advanced glycation end products. Advanced glycation end products play an important role in the pathogenesis of diabetes, chronic inflammation, cancer and Alzheimer's disease. One of the most stable compounds, which is formed by reacting of methylglyoxal with the nitrogenous bases of the DNA molecule is N²- carboxyethyl -2' - deoxyguanosine (CEdG). This compound can be used as a marker for monitoring of various diseases, investigation of the role of glycation end products in their pathogenesis, as well as to search for the therapeutic targets. To perform our molecular-biological investigations by mass spectrometry, we synthesized N²- carboxyethyl -2' - deoxyguanosine, and have proposed a new method for purifying compounds by reverse - phase HPLC. As a result, we achieved the optimal purity of the sample, while substantially reducing the cost of the purification procedure.

Abstract: Using differential scanning calorimetry and synchronous thermal analysis under dynamic conditions, kinetic regularities of copolymerization of α- glycolide and a mixture of α-β-glycolidewith D,L-lactide in the presence of stannous octoate as a catalyst have been investigated. Some thermodynamic and kinetic parameters of cationic copolymerization of monomers have been determined.

Abstract: We studied medical records and endomyocardial biopsies of patients with morphological confirmed lymphocytic myocarditis. The patients were divided into two groups: 1 - patients with arrhythmias; group 2 - patients with predominance syndrome heart failure. Morphological verification of myocarditis was based on World Heart Federation Consensus definition of Inflammatory Cardiomyopathy, 1997. Immunohistological study was performed to identify antigens of cardiotrophic viruses. We revealed some features in topic and character of morphological changes in depending on clinical scenario of myocarditis. In patients with chronic heart failure due to myocarditis revealed a high incidence of expression of LMP-antigen Epstein-Barr virus, the lack of expression of adenovirus antigens. Arrhythmic presentation of myocarditis was characterized by a high frequency of expression of enteroviral VP-1 antigen and the type 1 antigen herpes virus. We were not detected expression of the VP-2 antigen parvovirus B19. As a result the most severe inflammatory changes and interstitial fibrosis of intraventricular septum, widespread damage of myocytes the severe myocardial remodeling was found in patients with presentation of myocarditis by chronic heart failure. Interstitial fibrosis of the outflow tracts of the right ventricle, the low activity of inflammation and mild fibrotic changes were feature of arrhythmic scenario of myocarditis.

Abstract: The paper presents foundations of the algorithm of processing primary radiographic images of large-size cargoes that allows determination of their masses. Two possible approaches to form definite algorithm of processing radiographic information were analyzed. The choice of the approaches depends on the completeness of information about the test object. The first approach to design mass determination algorithm is connected with inspecting industrial products. Industrial inspecting products are characterized by a completeness of information about the material, its structure, the geometry. The information augmented by selecting maximum X-ray energy and calibrating by test object allows determination the mass of inspecting object by the only radiographic image with high precision. The second approach is caused by indeterminacy and incomplete information about inspecting object. This case is typical for problems of cargo inspection. Corresponding algorithm modification is based on using dual-energy X-ray imaging that allows determination of the effective atomic number of test object and provision of the required precision of mass estimation.

Abstract: In this study, the phenomenon of creep of face-centered cubic (FCC) crystals have been studied by mathematical modeling. The effect of applied stress on creep curves of copper at different temperatures and stress were performed. We have found that steady-state creep rate is proportional to the applied stress and observed the Stages I-III of creep.

Abstract: A method for choosing rehabilitation programs on the basis of fuzzy classifiers and approximators is proposed. Fuzzy systems are identified using swarm intelligence methods and methods based on derivatives. The results of the system operation on the real data are given.

Abstract: In the work the results of research emerging polarization current and of the electromagnetic signal with a change in the intense-deformed state of rock samples are presented. It is established that at stage of the intense-deformed state of rocks there is a correlation between emerging polarization current and the amplitude of the electromagnetic signal.