Synthesis, Photochromism and Optical Storage of a New Type of Diarylethene Compound

Li Qin Wang; Shou Zhi Pu; Liu Shui Yan; Shi Qiang Cui

doi:10.4028/www.scientific.net/AMR.399-401.945

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 399-401Synthesis, Photochromism and Optical Storage of a...

Synthesis, Photochromism and Optical Storage of a New Type of Diarylethene Compound

Abstract:

A new unsymmetrical photochromic diarylethene 1-(2-methylbenzothiophene-3-yl)-2-(2-nbutyl-5-(2,2′-dicyanovinyl)thiophene-3-yl)perfluoroncyclopen-tene (1a), was synthesized and its optoelectronic properties, such as photochromism in solution as well as in poly-methylmethacrylate (PMMA) amorphous films, and the fluorescence spectra of diarylethene 1a was investigated. The photochromic reaction kinetics indicated that the cyclization process of 1a belongs to the zeroth order reaction and the cycloreversion process belongs to the first order reaction. The diarylethene can be potentially used as holographic optical recording medium.

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Periodical:

Advanced Materials Research (Volumes 399-401)

Pages:

945-948

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.399-401.945

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Online since:

November 2011

Authors:

Li Qin Wang, Shou Zhi Pu, Liu Shui Yan, Shi Qiang Cui

Keywords:

Diarylethene, Fluorescence, Holographic Optical Recording, Photochromic

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