Advanced Materials Research Vols. 418-420

Abstract: In this paper, the computer-aided calculation is introduced to study the influences of the reflux ratio on the theoretical plate number of rectification column. It is found that the number of theoretical plates of rectification column is increasing as the decreasing of the reflux ratio, which is mainly caused by the increasing of the plate number in rectifying section. On the other hand, it is found that when reflux ratio is reduced in small interval, the theoretical plate number is increased in a zigzag shape. This interesting phenomenon is analyzed in depth and a reasonable explanation is given.

Abstract: CNC machining centers were analyzed by the failure mode, effect and criticality analysis (FMECA) method for identifying the weakest links of a CNC machining center and obtaining that the spindle system is the primary factor that affects the reliability of CNC machining centers. The spindle system was analyzed at different feed speed by the finite element method. The results have important guiding significance for the reliability research of CNC machine tools.

Abstract: Extraction of anthocyanins in red cabbage leaves was taken up using hydrochloric acid solution. Raw silk fibers were degummed with traditional Marseille soap. Then the dyeing of degummed silk fibers with anthocyanins extracted from red cabbage was investigated. It was concluded that, K/S of silk increased in the order of the dyeing with Co(II) > Zn(II) > Ni(II) > Fe(II) > Al(III). The maximum adsorption wavelength of dyed samples at different pH values shifted to different values and the color strength values also changed. In addition, the higher dye concentration, the higher color strength values. Deep shade (K/S value = 6.655) was achieved at 40°C and pH 2 using zinc chloride.

Abstract: Bacterial cellulose-poly (ethylene glycol) composites (BC-PEG) were biosynthesized by adding different molecular weight of poly (ethylene glycol) into Acetobacter xylimum culture medium. The obtained BC-PEG composites were characterized by scanning electron microscopy (SEM), thermogravimetry (TG), X-ray diffractometry (XRD) and tensile test. SEM images showed that the morphology of BC-PEG composites changed. TG results indicated their thermal stability also changed. XRD profiles suggested their crystalline morphology no much difference. But the tensile tests appeared that the adding of different molecular weight PEG modified the mechanical properties of BC-PEG composites.

Abstract: Rubber composite armor panels have been used for many years as very efficient add-on armor against shaped charge warheads. In this work, we did some DOP test about four types woven fiber reinforced rubber composite armor against shaped charge jet and explained the origin of the disturbances on the jet due to the interaction with the forward plate. The results of DOP test showed that the Kevlar or PBO woven fiber reinforced rubber composite armor performs better than E-glass and carbon types.

Abstract: A low-cost non-vacuum process for fabrication of Cu2ZnSnSe4 (CZTSe) films by solvent-free mechanochemical method and spin-coating process is described. First, highly monodisperse Cu, Zn, Sn oxides nanoparticles are synthesized via a facile, solvent-free route. Second, the oxide particulate precursors are deposited in a thin layer by spin-coating technique. Finally, the dry layers are sintered into CZTSe thin films selenization. Through X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), it is found that near stoichiometric CZTSe films with a micron-sized grains are obtained in our work.

Abstract: In this paper, the author successfully fabricated Mg-3Sr-xY alloys by melting-leaching reduction method using SF₆ and N₂ as protected gas. The microstructures of the Mg-3Sr-xY alloys were investigated in details，and the results showed that Mg-3Sr-xY alloys are composed of dendrite α-Mg and eutectic α-Mg and Mg₁₇Sr₂ and Mg₂₄Y₅ particulates, the second phases distribute in the α-Mg dendrites and interdendrites. The fiber microstructures form after thermal extrusion and the dynamic recrystallization occurs. In Mg-3Sr-xY alloy, the tensile strengths, the yield strengths and elongation rates increase firstly, reach the peak values, decrease with the increasing in Y content. Mg-3Sr-xY alloy have the best mechanics properties, including yield strengths and ultimate strengths and elongation rates and creep properties by the addition of 0.6%Y content. The tensile behaviors at elevated temperatures are accord to general laws for the metals at room temperature. The Mg-3Sr-xY alloys with 0.4-1.0% Y are of best creep limit. The dislocation sliding and climbing is the main creep mechanism for Mg-3Sr-0.6Y alloys.

Abstract: Abstract: Base on finite element method of composite, take 5MW horizontal axis wind turbine blades as example, skin uses a mixture of fiberglass and carbon fiber as ply, spar caps and web adopt carbon fiber ply entirely to build the finite element model of the blade. The total weigh of the blade is 20.2 ton. Use Bladed software calculated the limit load of each cross-section, analyzed the stress distribution of each section and the modal characteristics of the blade, these provide a theoretical reference for the application of carbon fiber using on MW class wind turbine blade.

Abstract: Through laboratory experiments, a green cross-linked movable gel has been developed, which has been used for reservoir profile modification. The main agent of gel is hydrophobic associating polymer, concentration is 3000mg/L; the cross-linking agent is Aluminum citrate from complex of Aluminum ion and citric acid root ion. The best molar ratio of aluminum ions and citrate ions is 1.5:1 in complex reaction, the amount is 140mg/L; the retarder is tartaric acid sodium, the amount is 150mg/L; The stabilizer is thiourea, the amount is 800mg/L; The strength of the green cross-linked movable gel is 3.12×10⁴mPa.s, gelling time 36h, Stable time 160d; It is suitable for low-temperature reservoir profile modification, and salt resistance is good. Laboratory experiments show that the green cross-linked movable gel have strong plugging capacity and improving profile ability. The green cross-linked movable gel has strong three dimensional network structure, which be observed through the environmental scanning electron microscopy.

Abstract: Aluminophosphate molecular sieve and Ni(II)-containing APO-5 materials were synthesized hydrothermally and characterized by various analytical and spectroscopic techniques. It indicates that the nickel ions with a divalent oxidation state can incorporate into the tetrahedral coordination in mesoporous aluminophosphate very well. The better crystallizing temperature is explored. A stronger crystalline form is obtained with the addition of HF. Further, microporous aluminophosphate molecular sieves and Ni(II) ions remain in a tetrahedral geometry even after calcination at 550 °C.