Phase Transition of GeSbTe Thin Films Induced by Thermal Treatment and Laser Irradiation

Article Preview

Abstract:

GeSbTe (GST) thin films were deposited on Si substrates using electron beam evaporation system and then annealed in nitrogen atmosphere at different temperatures. X-ray diffraction (XRD) and Atomic Force Microscope (AFM) measurements were used to characterize as-deposited and annealed films. Annealing treatment was found to induce changes in microstructure, surface roughness, grain size and so on, indicating that with the increase of annealing temperature, the amorphous state of GST materials change first to face-centered-cubic (fcc) phase state and finally to the stable hexagonal (hex) state. Amorphous Ge1Sb2Te4 film will crystallize under laser irradiation. With increasing irradiation time or irradiation power, the degree of crystallization increases. The Raman spectra of thin film shows three peaks after laser irradiation, the peaks can be attributed to the key vibrations which were caused by crystallization. With the irradiation time increases, the peaks shift.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

1048-1051

Citation:

Online since:

August 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S.R. Ovshinsky, Phys. Rev. Lett. 21, 1450(1968).

Google Scholar

[2] Y. -S. Shin, 2005 Symposium on VLSI Circuits, Digest of Technical Papers, p.156.

Google Scholar

[3] R. Bez, Microelectron. Eng. 80, 249 (2005).

Google Scholar

[4] R. Detemple, D. Wamwangi, M. Wuttig, Appl. Phys. Lett. 83,2572 (2003).

Google Scholar

[5] Zhanghua Wu, Fuxi Gan, Jun Hu and Minqian Li: Applied Surface Science 72, 245-248(1993).

Google Scholar

[6] Yingxue Xi,Huiqing Fan,Weiguo Liu,Journal of Alloys and Compounds 496, 695-698(2001).

Google Scholar

[7] Hoon Sang Choi, Kwang Soo Seol, Kazuo Takeuchi, Junya Fujita and Yoshimichi Ohki, Jpn. J. Appl. Phys. 44, 7720-7722 (2005).

Google Scholar

[8] Tae-Jin Park, Se-Young Choi and Myung-Jin Kang, Thin Solid Films, 515, Issue 12, 5049-505323(2007).

Google Scholar

[9] Bong-Sub Lee and John R. Abelson, Stephen G. Bishop , Dae-Hwan Kang and Byung-ki Cheong, Ki-Bum Kim J. Appl. Phys. 97, 093509 (2005).

Google Scholar

[10] Hyun Kyoung Yang, Jong Won Chung, Byung Kee Moon, Byung Chun Choi, Jung Hyun Jeong, Soung Soo Yi, Jung Hwan Kim and Kwang Ho Kim, Journal of Luminescence 129, Issue 5, 492-495 (2009).

DOI: 10.1109/isscc.2009.4977341

Google Scholar

[11] Junji Tominaga and Nobufumi Atoda , Jpn. J. Appl. Phys. 38 , 322-323(1999).

Google Scholar

[12] E. Cho, S. Yoon, H. R. Yoon and W. Jo, Journal of the Korean Physical Society, Vol. 48, No. 6, 1616-1619 (2006).

Google Scholar

[13] B. Liu, Z. Song, T. Zhang, S. Feng and B. Chen, Chin. Phys. Vol. 13 No. 11, 1947 (2004).

Google Scholar

[14] K.S. Andrikopoulos, S.N. Yannopoulos, A.V. Kolobov, P. Fons, J. Tominaga, Journal of Physics and Chemistry of Solids 68, 1074–1078 (2007).

DOI: 10.1016/j.jpcs.2007.02.027

Google Scholar

[15] A. V. Kolobov, P. Fons, J. Tominaga, A. I. Frenkel, A. L. Ankudinov, T. Uruga, Journal of Ovonic Research Vol. 1, No. 1, p.21 – 24(2005).

Google Scholar

[16] Adam A. Bahishti, M.A. Majeed Khan, B.S. Patel, F.S. Al-Hazmi and M. Zulfequar, Journal of Non-Crystalline Solids Vol. 355, Issues 45-47, 2314-2317(2009).

DOI: 10.1016/j.jnoncrysol.2009.07.005

Google Scholar

[17] Yoshihito Maeda and Masatoshi Wakagi , Jpn. J. Appl. Phys. 30 , 101-106 (1991).

Google Scholar