Study of Interlayer Element Effect on Properties of AlCrTiSiN Thin Film

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In this work, the effect of different interlayer elements on the properties of the top AlCrTiSiN film, i.e. titanium and chromium called as Ti/AlCrTiSiN and Cr/AlCrTiSiN, respectively, was studied. The film was deposited by cathodic arc physical vapor deposition on tungsten carbide (WC) specimen which is extensively used as cutting tools material. Various properties including the surface hardness, the scratch resistance and tribological performance were later studied. The surface hardness of both Ti/AlCrTiSiN and Cr/AlCrTiSiN coatings were higher than 29 GPa. The critical load for both coating suggesting supurb adhesion strength of the coating system. However, Ti interlayer was found to result in higher critical compressive stress for first damage and full delamination at room temperature. The wear resistance of coated specimens was far better than the uncoated one both at room temperature and high temperature, i.e. ball on disc tests at room temperature, 300 °C, and 500 °C were performed. The coeeficient of friciton of both coatings were found to depend strongly on the wear behavior of the system and the characters of the wear debris. A sign of better tribological performance at high temperature, i.e. 500°C, could be noticed with Cr interlayer as the lower mismatch in coefficient of thermal expansion became more crucial in film damage phenomina at such temperature.

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543-549

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February 2014

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[1] L. Aihua, D. Jianxin, C. Haibing, C. Yangyang, and Z. Jun, Friction and wear properties of TiN, TiAlN, AlTiN and CrAlN PVD nitride coatings, Int. Journal of Refractory Metals and Hard Materials 31 (2012) 82–88.

DOI: 10.1016/j.ijrmhm.2011.09.010

Google Scholar

[2] M. Godet, Y. Berthier, L. Vincent, L. Flamand, Hard Coating for Tribological Applications: a‏ Pluridisciplinary Approach, Surface and Coatings Technology 45 (1991) 1-8.

DOI: 10.1016/0257-8972(91)90199-7

Google Scholar

[3] D.M. Mattox , Handbook of physical deposition (PVD) processing, New Jersey, (1998).

Google Scholar

[4] N. Panich, S. Surinphong, D.A. Karpov, Y. Kwang Tan, C.F. Goh, J. Ma, Mechanical Properties of AlCrTiSiN Coatings Developed by Cathodic Arc for Protection Applications, Solid State Phenomena Vol. 185 (2012) 81-83.

DOI: 10.4028/www.scientific.net/ssp.185.81

Google Scholar

[5] H. Du, H. Zhao, J. Xiong, and G. Xian, Effect of interlayers on the structure and properties of TiAlN based coatings on WC-Co cemented carbide, Int. Journal of Refractory Metals and Hard Materials 37 (2013) 60 – 66.

DOI: 10.1016/j.ijrmhm.2012.10.017

Google Scholar

[6] K.L. Johnson, Contact mechanics, Cambridge, (1985).

Google Scholar

[7] Information on http: /www. meadinfo. org/2010/03/s45c-jis-mechanical-properties. html.

Google Scholar

[8] T. Usana - ampaipong, S. Prapasuk, K. Feung – im, K. Tuchinda, K. Wathanyu, S. Surinphong and N. Panich, The Study of Interlayer Element Effect on the Properties of AlCrTiSiN Thin Film for Milling Process, Senior project, KMUTT, (2012).

DOI: 10.4028/www.scientific.net/amr.893.543

Google Scholar

[9] H. Ezura, K. Ichijo, H. Hasegawa, K. Yamamoto, A. Hotta, and T. Suzuki, Micro-hardness, microstructures and thermal stability of (Ti, Cr, Al, Si)N films deposited by cathodic arc method, Vacuum 82 (2008) 476 – 481.

DOI: 10.1016/j.vacuum.2007.07.048

Google Scholar

[10] K. Ichijo, H. Hasegawa, and T. Suzuki, Microstructures of (Ti, Cr, Al, Si)N films synthesized by cathodic arc method , Surface, Surface & Coatings Technology 201 (2007) 5477 – 5480.

DOI: 10.1016/j.surfcoat.2006.07.016

Google Scholar

[11] T.V. Rajan, C.P. Sharma, and A. Sharma, Heat Treatment Principles and Techniques, fifteenth ed., Delhi, (2011).

Google Scholar

[12] The American Ceramic Society, Progress in Nanotechnology Processing, New Jersey, (2010).

Google Scholar

[13] D. Wu , J. Zhang, J.C. Huang, H. Bei, and T.G. Nieh, Grain-boundary strengthening in nanocrystalline chromium and the Hall–Petch coefficient of body-centered cubic metals, Scripta Materialia 68 (2013) 118 – 121.

DOI: 10.1016/j.scriptamat.2012.09.025

Google Scholar

[14] Y. Xie and H.M. Hawthorne, A model for compressive coating stresses in the scratch adhesion test, Surface and Coatings Technology 141 (2001) 15 – 25.

DOI: 10.1016/s0257-8972(01)01130-6

Google Scholar

[15] C.G. Morris, Academic Press Dictionary of Science and Technology, London, (1962).

Google Scholar

[16] P. Hidnert, Thermal expansion of cemented tungsten carbide, Journal of Research of the National Bureau of Standards 18 (1937) 47 – 52.

DOI: 10.6028/jres.018.025

Google Scholar

[17] Information on http: /periodictable. com/Properties/A/ThermalExpansion. an. html.

Google Scholar

[18] M.F. Ashby and D.R.H. Jones , Engineering Materials 1, an Introduction to Their Properties & Applications, second ed., Cambridge, (1996).

Google Scholar

[19] T.D. Nguyen, S.K. Kim, and D.B. Lee, High-temperature oxidation of nano-multilayered TiAlCrSiN thin films in air, Surface & Coatings Technology 204 (2009) 697 – 704.

DOI: 10.1016/j.surfcoat.2009.09.008

Google Scholar

[20] E. Lassner and W. – D. Schubert, Tungsten Properties, Chemistry, Technology of the Element, Alloys, and Chemical Compounds, New York, (1999).

DOI: 10.1007/978-1-4615-4907-9

Google Scholar